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Throughout this paper the trivial name cavitand will be used for the rigidified tetrameric resorcinarene framework of the adsorbates. The official IUPAC name is 7,11,15,28-tetrakis(XX)-1,21,23,25-tetra-(YY)-2,20:3,19-dimetheno-1H,21H,23H, 25H-bis[1,3]dioxacino(5,4i:5′,4′i′]-benzo[1,2d:5,4d′] bis[1,3]benzodioxocin, in which XX refers to the aromatic rings substituents and YY to the methylene bridge substituents.
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11644284064
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note
-
Measurements with toluene were also carried out but did not g ive reliable signals for any of the adsorbate monolayers. The intensity o f the signals was high, suggesting strong interaction with the adsorbates, However, they contiuously changed and the layers showed results obtained with toluene are not reported in this paper.
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21
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11644315106
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note
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After purification by flash column chromatography, trace amounts of trialklated product were also isolated.
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30
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0002754017
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11644263659
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note
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The solutions were not buffered because, after some initial measurements carried out with aqueous solutions of guests, no dependence of the acidity of the solutions on the interactions with receptors 1-4 could be detected.
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32
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0028793510
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It is beyond the scope of this paper to discuss the principles of SPR; for detailed studies, see: Mittler-Neher, S.; Spinke, J.; Liley, M.; Nelles, G.; Weisser, M.; Back, R.; Wenz, G.; Knoll, W. Biosens. Bioelectron. 1995, 10, 903.
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33
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11644267852
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note
-
For the comparison of the results obtained on the receptor layer, other reference layers could have been used. Different types of reference layers, for example hydroxyl-terminated and perfluorinated alkanethiol monolayers, are currently being studied to try to determine in which case the interactions with the guests are minimal.
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34
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0003843314
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From: Atlas of Spectral Data and Physical Constants for Organic Compounds; Grasselli, J. G., Ed.; CRC Press: Cleveland, OH, 1973. Key: 1, insoluble in water, 2, slightly soluble; 3, soluble.
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11644273549
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note
-
Concentretion dependence experiments were not carried out w ith adsorbates 2-4 because there was no reason to believe that these receptor layers would behave in a fundamentally different way from adsorbate 1.
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-
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38
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11644296500
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note
-
At higher guest concentractions than those depicted in Figure 5, receptor curve and reference curve continue to diverge.
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40
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0026153423
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