Asymmetric anionic polymerization of (2-fluorophenyl) (4-fluorophenyl) (2-pyridyl) methyl methacrylate leading to a helical polymer

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 36, Issue 12, 1998, Pages 2013-2019

  Wu, Jian ^a,b   Nakano, Tamaki ^a   Okamoto, Yoshio ^a  

^a NAGOYA UNIVERSITY   (Japan)

^b ZHEJIANG UNIVERSITY   (China)

Author keywords

(2 fluorophenyl)(4 fluorophenyl)(2 pyridyl)methyl methacrylate; Anionic polymerization; Asymmetric polymerization; Helix; Optically active polymer

Indexed keywords

ANIONIC POLYMERIZATION; ESTERS; MOLECULES; POLYMETHYL METHACRYLATES; SYNTHESIS (CHEMICAL);

ASYMMETRIC POLYMERIZATION; CHIRAL LITHIUM COMPLEXES; HELIX; ISOTACTICITY; METHANOLYSIS; METHYL METHACRYLATE; OPTICALLY ACTIVE POLYMER;

MONOMERS;

EID: 0032162572     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0518(19980915)36:12<2013::AID-POLA6>3.0.CO;2-Y     Document Type: Article

References (17)

1. A trivial name is 2,4′-difluoro-α-(2-pyridyl)benzhydryl methacrylate.
2. Y. Okamoto and T. Nakano, Chem. Rev., 94, 349 (1994).
3. (a) Y. Okamoto, CHEMTECH, 144 (1987);
4. (b) Y. Okamoto and E. Yashima, in Macromolecular Design of Polymeric Materials, K. Hatada, T. Kitayama, and O. Vogl, Eds., Marcel Dekker, Inc., New York, 1997, p. 731.
5. Y. Okamoto, E. Yashima, M. Ishikura, and K. Hatada, Polym. J., 19, 1183 (1987).
6. (a) Y. Okamoto, M. Ishikura, K. Hatada, and H. Yuki, Polym. J., 15, 851 (1983);
7. (b) E. Yashima, Y. Okamoto, and K. Hatada, Macromolecules, 21, 854 (1988);
8. (c) Y. Okamoto, T. Nakano, T. Asakura, H. Mohri, and K. Hatada, J. Polym. Sci., Polym. Sci. Ed., 29, 287 (1991).
9. T. Nakano, Y. Okamoto, and K. Hatada, J. Am. Chem. Soc., 114, 1318 (1992).
10. Y. Okamoto, M. Kawashima, and K. Hatada, J. Chromatogr., 363, 173 (1986).
11. E. Yashima, Y. Okamoto, and K. Hatada, Polym. J., 19, 897 (1987).
12. Y. Okamoto, H. Mohri, and K. Hatada, Polym. J., 21, 439 (1989).
13. Y. Okamoto and T. Nakano, in Progress in Pacific Polymer Science, K. P. Ghiggino, Ed., Springer-Verlag, Berlin, Heidelberg, 1994, vol. 3, p. 111.
14. T. Nakano, A. Matsuda, M. Mori, and Y. Okamoto, Polym. J., 28, 330 (1996).
15. Y. Okamoto, E. Yashima, and K. Hatada, J. Polym. Sci., Part C: Polym. Lett., 25, 297 (1987).
16. Y. Okamoto, M. Nishikawa, T. Nakano, E. Yashima, and K. Hatada, Macromolecules, 28, 5135 (1995).
17. Y. Okamoto, T. Nakano, Y. Shikisai, and M. Mori, Macromol. Symp., 89, 479 (1995).