Mechanisms of thermal degradation of polystyrene, polymethacrylonitrile, and their copolymers on flash pyrolysis

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 36, Issue 13, 1998, Pages 2315-2330

  Yang, M ^a   Shibasaki, Y ^a  

^a SAITAMA UNIVERSITY   (Japan)

Author keywords

Back biting reaction; Boundary effect; Depolymerization; Poly(styrene co methacrylonitrile); Pyrolysis gas chromatography; Thermal degradation mechanism

Indexed keywords

COPOLYMERS; DIMERS; DISSOCIATION; GAS CHROMATOGRAPHY; HYDROGEN BONDS; MOLECULAR STRUCTURE; MONOMERS; POLYACRYLONITRILES; POLYSTYRENES; RATE CONSTANTS;

CURIE-POINT PYROLYZERS; DEPOLYMERIZATION; FLASH PYROLYSIS; POLYMETHACRYLONITRILE; TRIMERS;

PYROLYSIS;

EID: 0032162539     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0518(19980930)36:13<2315::AID-POLA19>3.0.CO;2-D     Document Type: Article

References (38)

1. G. C. Hewitt and B. T. Whitham, Analyst, 86, 643 (1961).
2. K. Ettre and P. F. Vardi, Anal. Chem., 35, 69 (1963).
3. Y. Shibasaki and H. Kambe, Kobunshi Kagaku, 21, 71 (1964).
4. J. Strassburger, G. M. Brauer, M. Tryon, and A. F. Forziati, Anal. Chem., 32, 454 (1960).
5. A. Barlow, R. S. Lehrle, and J. C. Robb, Polymer, 2, 27 (1961).
6. T. Hammond, R. S. Lehrle, and A. Shortland, Polym. Deg. Stab., 50, 169 (1995).
7. T. Okumoto, H. Ito, S. Tsuge, and T. Takeuchi, Makromol. Chem., 151, 285 (1972).
8. B. R. Northmore, Br. Polym. J., 4, 511 (1972).
9. N. Oguri and P. Kim, Int. Lab., 19, 58 (1989).
10. T. Shimono, M. Tanaka, and T. Shono, J. Anal. Appl. Pyro., 1, 77 (1979).
11. N. Oguri, A. Onishi, and T. Hanai, J. High Resolut. Chromatogr., 14, 79 (1991).
12. I. C. McNeill, M. Zulfinger, and T. Kousar, Polym. Deg. Stab., 28, 131 (1990).
13. I. C. McNeill and T. Mahmood, Polym. Deg. Stab., 46, 195 (1994).
14. S. Tsuge, T. Okumoto, and T. Takeuchi, Macromol. Chem., 123, 123 (1969).
15. R. P. Lattimer and W. J. Kroenke, J. Appl. Polym. Sci., 25, 101 (1980).
16. R. P. Lattimer and W. J. Kroenke, J. Appl. Polym. Sci., 27, 1355 (1982).
17. C. A. Fyfe and M. S. McKinnon, Macromolecules, 19, 1909 (1986).
18. J. J. Maurer, D. J. Eustace, and C. T. Ratcliffe, Macromolecules, 20, 196 (1987).
19. Y. Tsuchiya and K. Suni, J. Appl. Polym. Sci., 21, 975 (1977).
20. T. Usami, T. Itoh, H. Ohtani, and S. Tsuge, Macromolecules, 23, 2460 (1990).
21. L. Dean, S. Groves, R. Hancox, G. Lamb, and R. S. Lehrle, Polym. Degrad. Stab., 25, 143 (1989).
22. H. Ohtani, T. Yuyama, S. Tsuge, B. Plage, and R. H. Schulten, Eur. Polym. J., 26, 893 (1990).
23. Y. Shibasaki, Kobunshi Kagaku, 21, 125 (1964).
24. Y. Shibasaki, J. Polym. Sci., A-1, 5, 21 (1967).
25. Y. Shibasaki and M. Yang, J. Thermal Anal., 49, 71 (1997).
26. H. J. Harwood and W. M. Ritchey, ACS Polym. Prepr., 5, No. 1, 229 (1964); J. Polym. Sci., B, 2, 601 (1964).
27. H. J. Harwood and W. M. Ritchey, ACS Polym. Prepr., 5, No. 1, 229 (1964); J. Polym. Sci., B, 2, 601 (1964).
28. M. G. Evans and M. Polanyi, Trans. Faraday Soc., 34, 11 (1938).
29. N. N. Semenov, Some Problems in Chemical Kinetics and Reactivity, Princeton Univ. Press, Princeton, NJ, 1958.
30. Kh. S. Bagdasar'yan, Theory of the Radical Polymerization, Izdatel'stvo Akademii Nauk SSSR, Moskva, 1959.
31. A. Rudin and R. G. Yule, J. Polym. Sci., A-1, 9, 3009 (1971).
32. A. Onishi, JAI News, 6, 1 (1985).
33. T. Tsukame, private communication (1996).
34. Y. Shibasaki, Proc. of 1983 annual meeting on the thermal degradation and stabilization of polymers, The Society of Polymer Science, Japan (Nov. 30, 1983, Tokyo), The Boundary Effect and Bond Dissociation Energies in the Pyrolysis of Copolymers.
35. Y. Shibasaki, Proc. of 21th annual meeting of the Japan Society of Calorimetry and Thermal Analysis (Sept. 26, 1985, Sapporo), Relationship between Rapid Thermal Degradation Mechanism of Polymers at High Temperatures and Bond Dissociation Energies.
36. R. S. Lehrle and E. J. Place, Polym. Degrad. Stab., 56, 216 (1997).
37. R. S. Lehrle and E. J. Place, Polym. Degrad. Stab., 56, 221 (1997).
38. N. Oguri, A. Onishi, S. Uchino, K. Nakahashi, and X. Jin, Mass Spectrosc., 40, 33 and 41 (1992).