Synthesis and radical ring-opening polymerization of vinylcyclopropanes bearing vinylsilane groups

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 36, Issue 12, 1998, Pages 2037-2042

  Sanda, Fumio ^a   Murata, Junji ^a   Endo, Takeshi ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

Desilylation; Radical polymerization; Vinylcyclopropane; Vinylsilane

Indexed keywords

HYDROCHLORIC ACID; MONOMERS; RING OPENING POLYMERIZATION; SILANES; SYNTHESIS (CHEMICAL);

DESILYLATION; GLYCINE ETHYL ESTER HYDROCHLORIDE; RADICAL RING OPENING POLYMERIZATION; VINYLCYCLOPROPANE; VINYLSILANE;

FREE RADICAL POLYMERIZATION;

EID: 0032162504     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0518(19980915)36:12<2037::AID-POLA9>3.0.CO;2-U     Document Type: Article

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11. a and ΔH values in the addition reactions of 1a-trans and 1b-cis are expected to show similar values with those of 1a-cis and 1b-trans. The carboethoxy group should not sterically affect the reactivity of the vinyl group, because the carboethoxy group exists apart from the vinyl groups.