Friedel-crafts acylation on porous divinyl benzene polymer particles: A reaction kinetic process studied by mid- and near-infrared spectroscopy

Applied Spectroscopy

Volumn 52, Issue 9, 1998, Pages 1230-1239

  Christy, Alfred A ^a,d   Nyhus, Anne K ^b   Grung, Bjørn ^a   Kvalheim, O M ^a   Hagen, Steinar ^c   Schanche, Jon S ^c  

^a UNIVERSITY OF BERGEN   (Norway)

^b NORWEGIAN UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Norway)

^c Amersham Biosciences   (United States)

^d UNIVERSITY OF AGDER   (Norway)

Author keywords

Acylation; Kinetics and reaction mechanism; Mid IR; Near IR; Poly(divinylbenzene)

Indexed keywords

ABSORPTION SPECTROSCOPY; ACYLATION; CARBOXYLIC ACIDS; CHEMICAL BONDS; FRIEDEL-CRAFTS REACTION; INFRARED SPECTROSCOPY; MONOMERS; PARTICLES (PARTICULATE MATTER); POROUS MATERIALS; REACTION KINETICS; SYNTHESIS (CHEMICAL); TOLUENE;

ETHYLHEXANOIC ACID; POLYDIVINYLBENZENE;

VINYL RESINS;

EID: 0032158201     PISSN: 00037028     EISSN: None     Source Type: Journal    
DOI: 10.1366/0003702981945057     Document Type: Article

References (20)

1. J. M. Millar, D. D. Smith, W. E. Marr, and T. R. E. Kressmann, J. Chem. Soc. 218 (1963).
2. J. Seidl, J. Malinsky, K. Dusek, and W. Heitz, Adv. Polym. Sci. 5, 113 (1967).
3. K. A. Kun and R. Kunin, J. Polym. Sci., Part A1. 6, 2689 (1968).
4. J. Hilgen, G. L. DeJong, and W. L. Sederel, J. Appl. Pol. Sci. 19, 2647 (1975).
5. H. Jacobelli, M. Bartholin, and A. Guyot, Angew. Macromol. Chem. 80, 31 (1979).
6. G. A. Olah, Friedel-Crafts and Related Reactions (Wiley, New York, 1963), pp. 1003-1152.
7. H. O. House, Modern Synthetic Reactions (Benjamin, New York, 1972), pp.787-788.
8. J. K. Groves, Chem. Soc. Rev. 1, 73 (1972).
9. A. A. Christy, R. A. Velapoldi, O. M. Kvalheim, N. Telnæs. and T. V. Karstang, Chemomet. Int. Lab. Sys. 2, 199 (1987).
10. A. A. Christy, R. A. Velapoldi and J. E. Tvedt, Rev. Sci. Inst. 59, 423 (1988).
11. A. A. Christy and O. M. Kvalheim. Vib. Spectrosc. 1, 19 (1995).
12. H. W. Siesler, Macromol. Symp. Near-Infrared Spectrosc. Polym. 52, 113 (1991).
13. Y. Le Bigot, M. Delmas, and A. Gaset, Synth. Comm. 13, 177 (1983).
14. J. Ugelstad, P. C. Mørk, K. Herder Kaggerud, T. Ellingsen, and A. Berge, Adv. Colloid Interface Sci. 13, 101 (1980).
15. J. Ugelstad, A. Berge, T. Ellingsen, R. Schmid, T. N. Nilsen, P. C. Mørk, P. Stenstad, E. Homes, and Ø. Olsvik, Prog. Pol. Sci. 17, 87 (1992).
16. Pattern Recognition Systems (High Technology Centre, Bergen, Norway).
17. G. Herzberg, Infrared and Raman Spectra (D. van Nostrand, New York, 1945), pp. 363-367.
18. B. Osborne, T. Fearn, and P. H. Hindle, Practical NIR Spectroscopy (Longman Scientific & Technical, Essex, 1993), 2nd ed.
19. W. Kaye, Spectrochim. Acta 6, 257 (1954).
20. A. Guyot, in Synthesis and Separations Using Functional Polymers, D. C. Sherrington and P. Hodge, Eds. (John Wiley, London, (1988), pp. 1-42.