Selective kinetic deactivation model for methanol synthesis from simultaneous reaction of CO2 and CO with H2 on a commercial copper/zinc oxide catalyst

Canadian Journal of Chemical Engineering

Volumn 76, Issue 4, 1998, Pages 753-761

  Rahimpour, Mohammad Reza ^a   Fathikalajahi, Jamshid ^a   Jahanmiri, Abdolhosein ^a  

^a SHIRAZ UNIVERSITY   (Iran)

Author keywords

Catalyst

Indexed keywords

CARBON DIOXIDE; CARBON MONOXIDE; CATALYST SELECTIVITY; COPPER; MATHEMATICAL MODELS; METHANOL; REACTION KINETICS; SYNTHESIS (CHEMICAL); ZINC OXIDE;

SELECTIVE CATALYST DEACTIVATION;

CATALYST DEACTIVATION;

CATALYST;

EID: 0032148196     PISSN: 00084034     EISSN: None     Source Type: Journal    
DOI: 10.1002/cjce.5450760410     Document Type: Article

References (37)

1. Arandes, J. M., A. Romero and J. Bilbao, "Dimerization of Acetaldehyde to Crotonaldehyde over Silica-Alumina Bed Operating in Reaction-Regeneration Cycles", Ind. Engng. Chem. Process Des. Dev. 24, 828-831 (1985).
2. Bakshi, K. R. and G. R. Gavalas, "Effects on Non-separable Kinetics in Alcohol Dehydration over Poisoned Silica-Alumina", A.I.Ch.E. J. 21, 494-500 (1975).
3. Berty, J. M., "Reactor for the Vapor Phase Catalytic Studies", Chem. Eng. Prog. 70, 78-84 (1974).
4. Burch, R. and S. E. Golunski, "The Role of Hydrogen in Methanol Synthesis over Copper Catalysts", Catal. Lett. 5, 55-60 (1990).
5. Campbell, D. R. and B. W. Wojciechowski, "Selectivity of Aging Catalysts in Static, Moving and Fluidized Bed Reactors", Can. J. Chem. Eng. 47, 413-417 (1970).
6. Chinchen, G. C. and K. C. Waugh, "The Activity and State of the Copper Surface in Methanol Synthesis Catalysts", Appl. Catal. 25, 101-107 (1986).
7. Chinchen, G. C., C. M. Hay, H. D. Vandervall and K. C. Waugh, "The Measurement of Copper Surface Areas by Reactive Frontal Chromotography", J. Catal. 103, 79-86 (1987b).
8. 14 Labelled Reactants", Appl. Catal. 30, 333-338 (1987a).
9. Chinchen, G. C., P. J. Denny, J. R. Jenning, M. S. Spencer and K. C. Waugh, "Synthesis of Methanol- Part 1. Catalysts and Kinetics", Appl. Catal. 36, 1-65 (1988).
10. Corella, J. and M. Menendez, "The Modeling of the Kinetics of Deactivation of Nonfunctional Catalyst with an Acid Strength Distribution in their Non-homogeneous Surface. Application to the Deactivation of Commercial Catalysts in the FCC Process", Chem. Eng. Sci. 41, 1817-1826 (1986).
11. Corella, J., R. Bilbao, J. A. Molina and A. Artigas, "Variation with Time of the Mechanism, Observable order, and Activation Energy of the Catalyst Deactivation by Coke in FCC Process", Ind. Eng. Chem. Process Des. Dev. 24, 625-636 (1985).
12. Corella, J., F. G. Morales, M. Provost, A. Espinosa and J. Serrano, "The Selective Deactivation Kinetic Model Applied to the Kinetics of the Catalytic Cracking (FCC Process), In Recent Advances in Chemical Engineering", Edited by D. N. Saraf and Kunzru, McGraw-Hill, New Dehli, India 192-210 (1989).
13. Corella, J. and J. M. Asua, "Kinetic of Deactivation of a Solid Catalyst in a Nonsimple Reaction Isobutene Oxidation in Gaseous Phases by a Parallel Reaction Network", Ind. Eng. Chem. Process Dev. 21, 551-558 (1982).
14. 2 over Copper-based Amorphous Catalysts", Chem. Eng. Sci. 49, 209-221 (1994).
15. 3 methanol-synthesis catalyst", J. Chem. Soc. Faraday Trans. I 85, 3537-3560 (1989).
16. Edwards, J. F. and G. L. Schrader, "In Situ Fourier Transform Infrared Study of Methanol Synthesis on Mixed Metal Oxide Catalysts", J. Catal. 94, 175-186 (1985).
17. Fathikalajahi, J., "Break-in Behavior of a Tungsten Oxide on Silica Catalyst during Propylene Disproportionation", Ph.D. Thesis, Blacksburg, VI (1978).
18. 2 Catalyst", J. of Molecular Catalysis, 8, 127-134 (1980).
19. Froment, G. F., "The Modeling of Catalyst Deactivation by Coke Formation, in Catalyst Deactivation", Edited by Bartholomew, C. H. and J. B. Butt, Elsevier, Amsterdam, The Netherlands, 53-85 (1991).
20. Gayubo, A. G., J. M. Arandes, A. T. Aguayo, M. Olazar and J. Bilbao, "Selective Kinetic Deactivation Model for a Triangular Reaction Scheme", Chem. Eng. Sci. 48, 2273-2282 (1993).
21. Ghiotti, G. and F. Boccuzzi, "Chemical and Physical Properties of Copper-based Catalysts for CO Shift Reaction and Methanol Synthesis", Catal. Rev. Sci. Eng. 29, 151-182 (1987).
22. Graaf, G. H., E. J. Stamhuis and A. A. C. M. Beenackers, "Kinetics of Low-pressure Methanol Synthesis", Chem. Eng. Sci. 43, 3185-3195 (1988).
23. Islam, K. A., W. B. Earl, "Deactivation of ICI low Temperature Catalyst in an Industrial Reactor", Can. J. Chem. Eng. 68, 702-704 (1990).
24. Klier, K., V. Chatikavanij, R. G. Herman and G. W. Simmons, "Catalytic Synthesis of Methanol from CO/H2, IV. The Effect of Carbon Dioxide", J. Catal., 74, 343-360 (1982).
25. Kuechen, C., "Reaktionstechnische Untersuchungen zur Simultanen Umsetzung von Kohlenmonoxide und Kohlendioxid mit Wasserstoff", Dissertation, TU Clausthal, (1992).
26. Kuechen, C. and U. Hoffmann, "Investigation of Simultaneous Reaction of Carbon Monoxide and Carbon Dioxide with Hydrogen on a Commercial Copper/Zinc Oxide Catalyst", Chem. Eng. Sci. 48, 3767-3776 (1993).
27. Kung, H. H., "Methanol Synthesis", Catal. Rev. Sci. Eng. 22, 235-259 (1980).
28. Ladebeck, J., "Improve Methanol Synthesis", Hydrocarbon Processing, March, 89-91 (1993).
29. Liu, G., D. Willcox, M. Garland and H. H. Kung, "The Rate of Methanol Production on a Copper-Zinc Oxide Catalyst: The Dependence on the Feed Composition", J. Catal. 90, 139-146 (1985).
30. Marquardt, F. W., "An Algorithm for Least-Squares Estimation of Nonlinear Parameters", J. Soc. Ind. Appl. Math. 11, 431-441 (1963).
31. 3 Catalyst. II. Development of a Phenomenlogical Rate Expression", Appl. Catal. 50, 265-285 (1989).
32. 3 Methanol Synthesis Catalyst", Appl. Catal. 63, 165-179 (1990).
33. Santosh, K., K. Gangwal, J. Fathikalajahi and George B. Wills, "Brak-in Behavior of a Tungsten on Silica Catalyst in Propylene Disproportionation", Ind. Eng. Chem. Prod. Res. Dev. 16, 237-241 (1977).
34. Shiraz Petrochemical Complex of Iran, "Operating Data of Methanol Production Plant", (1997).
35. Skrzypek, J., Lachowska, M. and Moroz, H., 1991, "Kinetics of Methanol Synthesis over Commercial Copper/Zinc Oxide/Alumina Catalysts", Chem. Eng. Sci. 46, 2809-2813 (1991).
36. 2. I. Characterization of Catalysts by TPD", Appl. Catal. 18, 285-293 (1985).
37. Villa, P., P. Forzatti, G. Buzzi-Ferraris, G. Garone and I. Pasquon, "Synthesis of Alcoholes from Carbon Oxides and Hydrogen. 1. Kinetics of the Low-Pressure Methanol Synthesis", Ind. Eng. Chem. Process Des. Dev. 24, 12-19 (1985).