Kinetics of Trifluorovinyl Ether Cyclopolymerization via Raman Spectroscopy

Polymer International

Volumn 46, Issue 4, 1998, Pages 320-324

  Cheatham, C Michael ^a   Lee, Soo No ^b   Laane, Jaan ^b   Babb, David A ^a   Smith Jr , Dennis W ^a,c  

^a DOW CHEMICAL COMPANY   (United States)

^b TEXAS A AND M UNIVERSITY   (United States)

^c CLEMSON UNIVERSITY   (United States)

Author keywords

Perfluorocyclobutane polymers; Polymerization kinetics; Raman spectroscopy; Trifluorovinyl ether cyclopolymerization

Indexed keywords

ACTIVATION ENERGY; CURING; FLUORINE CONTAINING POLYMERS; GELATION; MATHEMATICAL MODELS; POLYMERIZATION; RAMAN SPECTROSCOPY; REACTION KINETICS; VINYL RESINS;

CYCLOPOLYMERIZATION; FLUOROVINYL ETHER; PERFLUOROCYCLOBUTANE;

POLYETHERS;

EID: 0032142385     PISSN: 09598103     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1097-0126(199808)46:4<320::aid-pi23>3.3.co;2-p     Document Type: Article

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21. c = 2/f) by statistical analysis (see: Flory, P. J., J. Am. Chem. Soc., 63 (1941) 3083, 3091, 3096) and by Carothers (see: Carothers, W. H., Trans. Faraday Soc., 32 (1936) 39), respectively.
22. -1 in 15 min at 180° C, consistent with our kinetics. (R. Sammler, The Dow Chemical Company, to be published elsewhere.)