Lipolytic synthesis of optically active 1,2-dibutyryl-sn-glycerol. Identification of diglyceride by solvent-dependent specific rotation

JAOCS, Journal of the American Oil Chemists' Society

Volumn 75, Issue 8, 1998, Pages 1061-1062

  O'Connor, Charmian J ^a   Lai, Douglas T ^a   Barton, Richard H ^a  

^a UNIVERSITY OF AUCKLAND   (New Zealand)

Author keywords

1,2 dibutyryl sn glycerol; Acyl transfer reactions; Lipid hydrolysis; Optical rotation; Pregastric lipase; Racemization; Stereoselective hydrolysis

Indexed keywords

EID: 0032140954     PISSN: 0003021X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11746-998-0288-0     Document Type: Article

References (8)

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3. Barton, R.H., C.J. O'Connor, and K.W. Turner, Characteristics of Tributyroylglycerol Hydrolysis Mediated by a Partially Purified Lamb Pregastric Lipase, J. Dairy Sci. 79:27-32 (1996).
4. 13C Nuclear Magnetic Resonance Characterization of the Reaction Products of Lamb Pregastric Lipase-Catalyzed Hydrolysis of Tributyrylglycerol, J. Am. Oil. Chem. Soc:967-976 (1998).
5. Sowden, J.C., and H.O.L. Fischer, Optically Active α,β-Diglycerides, Ibid. 63:3244-3248 (1941).
6. Baer, E., and V. Mahadevan, Synthesis of L-α-Lecithins Containing Shorter Chain Fatty Acids. Water-Soluble Glycerophosphatides. I, Ibid. 81:2494-2498 (1959).
7. Padley, F.B., F.D. Gunstone, and J.L. Harwood, Occurrence and Characteristics of Oils and Fats, in The Lipid Handbook, 2nd edn., Chapman and Hall, London, 1994, pp. 47-223.
8. O'Connor, C.J., R.H. Barton, P.A.G. Butler, A.D. MacKenzie, R.D. Manuel, and D.T. Lai, Ruminant Pregastric Lipases: Experimental Evidence of Their Potential as Industrial Catalysts in Food Technology, Coll. Surf. B: Biointerfaces 7:189-205 (1996).