Diffusive radical entry as the rate-determining step in amphiphilic block polyelectrolyte mediated emulsion polymerization

Macromolecules

Volumn 31, Issue 17, 1998, Pages 5565-5571

  Leemans, Luc ^a,b   Jérôme, Robert ^a   Teyssié, Philippe ^a  

^a UNIVERSITY OF LIÈGE   (Belgium)

^b DSM RESEARCH   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

BLOCK COPOLYMERS; EMULSION POLYMERIZATION; FREE RADICAL POLYMERIZATION; LATEXES; NEGATIVE IONS; POSITIVE IONS; REACTION KINETICS; SURFACE ACTIVE AGENTS;

COUNTERION DIFFUSION;

POLYELECTROLYTES;

EID: 0032136297     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma971162r     Document Type: Article

References (27)

1. Hansen, F. K.; Ugelstad, J. J. Polym. Sci., Polym. Chem. Ed. 1979, 17, 3033.
2. Blackley, D. C. Emulsion Polymerization; Applied Science: London, 1975.
3. Kim, J. U.; Lee, H. H. Macromolecules 1994, 27, 3337.
4. Vanderhoff, J. W. In Vinyl Polymerization; Ham, G., Ed.; Marcel Dekker: New York, 1969; Vol. 7, Part 2.
5. Fitch, R. M.; Tasi, C. H. In Polymer Colloids; Fitch, R. M., Ed.; Plenum: New York, 1971.
6. Penboss, I. A.; Napper, D. H.; Gilbert, R. G. J. Chem. Soc., Faraday Trans. 1 1986, 82, 2247.
7. Yeliseeva, V. I. In Emulsion Polymerization; Piirma, I., Ed.; Academic Press: New York, 1982.
8. Ottewil, R. H. In Emulsion Polymerization; Piirma, I., Ed.; Academic Press: New York, 1982.
9. Penboss, I. A.; Gilbert, R. G.; Napper, D. H. J. Chem. Soc., Faraday Trans, 1 1983, 79, 1257.
10. Maxwell, I. A.; Morrison, B. R.; Napper, D. H.; Gilbert, R. G. Macromolecules 1991, 24, 1629.
11. Leemans, L.; Fayt, R.; Teyssié, Ph. J. Polym. Sci. A 1990, 28, 1255.
12. Leemans, L.; Fayt, R.; Teyssié, Ph.; de Jaeger, N. C. Macromolecules 1991, 24, 5922.
13. Leemans, L.; Fayt, R.; Teyssié, Ph.; Uytterhoeven, H.; De Winter, W. J. Polym. Sci. A 1990, 28, 2187.
14. Teyssié, Ph. J.; Leemans, L. E.; Verdijck, W. A.; de Jaeger, N. C. US Pat. 5,200,456, 1993.
15. Maxwell, I. A.; Morrison, B. R.; Napper, D. H.; Gilbert, R. G. Makromol. Symp. 1990, 31, 1.
16. Uytterhoeven, H. J. Private communication.
17. Crank, J.; Park, G. S. Eds. Diffusion in Polymers; Academic Press: London and New York, 1968.
18. Nordmeier, E. Polymer J. 1994, 26, 539.
19. Morishima, Y.; Higuchi, Y.; Kamachi, M. J. Polym. Sci. 1991, 29, 677.
20. Rios, H. E.; Gamboa, C.; Ternero, G. J. Polym. Sci., Part B: Polym. Phys. 1991, 29, 805.
21. Hao, M.; Harvey, S. C. Macromolecules 1992, 25, 2200.
22. Itaya, T.; Ochiai, H. J. Polym. Sci., Part B: Polym. Phys. 1992, 30, 587.
23. Jakubovic, A. O.; Hills, G. J.; Kitchener, J. A. Trans. Faraday Soc. 1959, 55, 1570.
24. Nomura, M.; Fujita, K. Makromol. Chem. Rapid Commun. 1989, 10, 581.
25. Nomura, M.; Yamada, A.; Fujita, S.; Sugimoto, A.; Ikoma, J.; Fujita, K. J. Polym. Sci., Part A: Polym. Chem. 1991, 29, 987.
26. Alduncin, J. A.; Forcada, J.; Barandiaran, M. J.; Asua, J. M. J. Polym. Sci., Part A: Polym. Chem. 1991, 29, 987.
27. Adams, M. E.; Trau, M.; Gilbert, R. G.; Napper, D. H.; Sangster, D. F. Aust. J. Chem. 1988, 41, 179.