Decomposition of stable free radicals as "self-regulation" in controlled radical polymerization

Macromolecules

Volumn 31, Issue 16, 1998, Pages 5223-5228

  Steenbock, M ^a   Klapper, M ^a   Mullen K ^a   Bauer, C ^a   Hubrich, M ^a  

^a MAX PLANCK INSTITUTE FOR POLYMER RESEARCH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITIVES; DECOMPOSITION; INITIATORS (CHEMICAL); MONOMERS; POLYMETHYL METHACRYLATES; POLYSTYRENES; THERMODYNAMIC STABILITY;

SELF-REGULATING PROCESS; SPIROTRIAZOLINYL;

FREE RADICAL POLYMERIZATION;

EID: 0032135921     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma980425u     Document Type: Article

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28. A theoretical simulation, performed by A. H. E. Müller (University of Mainz, Germany) using the program "Predici" (CiT GmbH, v. 4.7) further supported the concept of a self-regulating process in controlled radical polymerization. For the polymerization of MMA in the presence of spirotriazolinyl 7, typical conversions of lower than 10% were predicted before the reaction stops. In contrast, a well-controlled polymerization was predicted when a slow decomposition of the triazolinyl counter radical 4 was taken into account. These and other theoretical results will be discussed in detail in a later publication.