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Volumn 31, Issue 15, 1998, Pages 4687-4694

Anionic polymerization of 1,3-cyclohexadiene with alkyllithium/amine systems. Characteristics of n-butyllithium/N,N,N′,N′-tetramethylethylenediamine system for living anionic polymerization

Author keywords

[No Author keywords available]

Indexed keywords

BENZENE; CHEMICAL REACTIONS; MAGNETIC FIELD EFFECTS; MICROSTRUCTURE; MOLECULAR WEIGHT DISTRIBUTION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLICS; POLYMERS; SYNTHESIS (CHEMICAL);

EID: 0032118265     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9718661     Document Type: Article
Times cited : (97)

References (35)
  • 14
    • 3743100518 scopus 로고    scopus 로고
    • WO9428038 (JP93-141281), 1995; 689867, CAPLUS
    • Natori, I. PCT Int. Appl., p 134, WO9428038 (JP93-141281), 1995; 689867, CAPLUS.
    • PCT Int. Appl. , pp. 134
    • Natori, I.1
  • 15
    • 3743106077 scopus 로고
    • note
    • After our finding of the anionic polymerization of 1,3-cyclohexadiene initiated with the white crystal from n-BuLi and TMEDA, the X-ray structure of this white crystal was reported by Nichols and Williard. Nichols, M. A.; Williard, P. G. J. Am. Chem. Soc. 1993, 115, 1568.
    • (1993) J. Am. Chem. Soc. , vol.115 , pp. 1568
  • 25
    • 85088280835 scopus 로고    scopus 로고
    • note
    • 7Li NMR spectra. This is not due to t-BuOLi which is one of the possible impurities as confirmed by comparison with t-BuOLi separately prepared.
  • 26
    • 3743132999 scopus 로고    scopus 로고
    • note
    • Since 1,3-cyclohexadiene did not polymerize when n-BuLi was the initiator, t-BuLi was used. See Table 5, nos. 1 and 19.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.