Complexation of borate with polyd(1-(acrylamido)-1-deoxylactitol): Dilute solution viscosity, 11B NMR, and 13C NMR studies

Macromolecules

Volumn 31, Issue 14, 1998, Pages 4486-4492

  Wilson, Mark E ^a   Najdi, Samir ^b   Krochta, John M ^a   Hsieh, You Lo ^a   Kurth, Mark J ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b AL QUDS UNIVERSITY   (Palestine)

Author keywords

[No Author keywords available]

Indexed keywords

BORON COMPOUNDS; FREE RADICAL POLYMERIZATION; IONS; MONOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYSACCHARIDES; RHEOLOGY; SOLUTIONS; VISCOSITY; VISCOSITY MEASUREMENT;

BINDING CONSTANT; BORATE;

COMPLEXATION;

EID: 0032115953     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9802430     Document Type: Article

References (33)

1. Sibayama, M.; Sato, M.; Kimura, Y.; Fujiwara, H.; Nomura, S. Polymer 1988, 29, 336.
2. Sinton, S. W. Macromolecules 1987, 20, 2430.
3. Nickerson, R. F. J. Appl. Polym. Sci. 1971, 15, 111.
4. Pezron, E.; Leibler, L.; Ricard, A.; Lafuma, F.; Audebert, R. Macromolecules 1989, 22, 1169.
5. Yoshimura, K.; Miyazaki, Y.; Sawada, S.; Waki, H. J. Chem Soc., Faraday Trans. 1996, 92 (4), 651.
6. Pizer, R.; Ricatto, P. J. Inorg. Chem. 1994, 33, 2402.
7. (a) van Duin, M.; Peters, J. A.; Kieboom, A. P. G.; van Bekkum, H. Tetrahedron 1984, 40, 2901;
8. (b) 1985, 41, 3411.
9. van den Berg, R.; Peters, J. A.; van Bekkum, H. Carbohydr. Res. 1994, 253, 1.
10. Pezron, E.; Ricard, A.; Leibler, L. J. Polym. Sci., Polym. Phys. Ed. 1990, 28, 2445.
11. Sato, T.; Tsujii, Y.; Fukuda, T.; Miyamoto, T. Macromolecules 1992, 25, 5, 5970.
12. Klein, J. J. Makromol. Chem. 1987, 188, 1217.
13. Klein, J. J. Makromol. Chem. 1989, 190, 2527.
14. (a) Wilson, M. E.; Hu, M.; Kurth, M. J.; Krochta, J. M.; Hsieh, Y. L. J. Appl. Polym. Sci. 1996, 59, 1759.
15. (b) Zhou, W. J.; Wilson, M. E.; Kurth, M. J.; Hsieh, Y-.L.; Krochta, J. M. Macromolecules 1997, 30, 7063.
16. A full account of the synthesis and characterization of PACL and the related poly(1-(methacrylamido)-1-deoxylactitol) is given in the Ph.D. dissertation of Mark E. Wilson, University of California, Davis, 1997.
17. Brevard, G.; and Granger, P. Handbook of High-Resolution Multinuclear NMR; John Wiley: New York, 1981; p 40.
18. Takeda, T.; Oi, T. Bull. Chem. Soc. Jpn. 1994, 67, 1485.
19. Kurokawa, H.; Shibayama, M.; Ishimaru, T. Polymer 1992, 33 (10), 2182.
20. 1.5)L6 where α is the expansion factor of the polymer coil, Φ is a universal constant, M is the molecular weight, and is the unperturbed mean-square end-to-end distance of the polymer chain.
21. Bolewski, V. K.; Rychly, B. Kolloid Z. Polym. 1968, 228, 48.
22. Pezron, E.; Leibler, L.; Ricard, A.; Lafuma, F.; Audebert, R. Macromolecules 1988, 21, 1126.
23. 20 were both shown to be ∼1.4.
24. Henderson, W. G.; How, M. J.; Kennedy, G. R.; Mooney, E. F. Carbohydr. Res. 1973, 28, 1.
25. The energy levels absorbed by interconverting species are blurred by ΔB according to ΔE = h/(2πτ), where τ is the lifetime of each discrete species. In NMR, this translates to a collapse of spectral structure (peak coalescence) when τ < 1/(2πΔδv), where Δδv is the chemical shift difference (in Hz) between the interconverting species. Accordingly, two borate complexes separated by 1 ppm at 96 MHz will appear as two distinct peaks when τ > 1.7 ms but will coalesce to one peak when τ < 1.6 ms. As Δδv decreases, the τ of each respective borate complex must increase in order to retain peak resolution.
26. Anderson, J. L.; Eyring, E. M.; Whittaker, M. P. J. Phys. Chem. 1964, 68, 1128.
27. - peaks appear broader. The broadened peaks in the NMR spectra of PACL-borate are likely due from the high solution viscosity.
28. Chapelle, S.; Verchere, J.-F. Tetrahedron 1988, 44, 4469.
29. Gorin, P. A. J.; Mazurek, M. Can. J. Chem. 1973, 51, 3277.
30. 11B peaks area and concentration, see: (a) Pizer, R. D.; Ricatto, P. J.; Tihal, C. A. Polyhedron 1993, 12, 2137. (b) Dawber, J. G.; Green, S. I. E.; Dawber, J. C.; Garail, S. J. Chem Soc., Faraday Trans, 1 1988, 84, 41.
31. 11B peaks area and concentration, see: (a) Pizer, R. D.; Ricatto, P. J.; Tihal, C. A. Polyhedron 1993, 12, 2137. (b) Dawber, J. G.; Green, S. I. E.; Dawber, J. C.; Garail, S. J. Chem Soc., Faraday Trans, 1 1988, 84, 41.
32. Makkee, M.; Kieboom, A. P. G.; van Bekkum, H. Recl. Trav. Chim. Pays-Bas 1985, 104, 230.
33. 13C NMR of PACL-borate is likely due from the high viscosity of the solution.