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Pyrene used in most of the previous studies is not suitable because the vibronic structure of fluorescence is affected significantly by the medium polarity and because the excimer emission bands which originate both from the ground-state associated dimers and from microcrystals occur at similar wavelengths and cannot be distinguished easily.
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-1 hydrated NaY at ambient temperature while it was only about 50 μs in dehydrated NaY. Thus the cation-π interaction enhances significantly the decay rate of the triplet state of anthracene (Hashimoto, S.; Miyashita, T. Unpublished result).
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Similar observations of the effect of added water on the intensities of excimer emission were made for pyrene in zeolites previously (refs 13 and 14).
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61
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-1 of the molecules when left in open air.
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