Commercial steam reforming catalysts to improve biomass gasification with steam-oxygen mixtures. 2. Catalytic tar removal

Industrial and Engineering Chemistry Research

Volumn 37, Issue 7, 1998, Pages 2668-2680

  Aznar, Maria P ^a   Caballero, Miguel A ^a   Gil, Javier ^a   Martín, Juan A ^a   Corella, José ^b  

^a UNIVERSITY OF ZARAGOZA   (Spain)

^b UNIVERSIDAD COMPLUTENSE DE MADRID   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; AROMATIC COMPOUNDS; BIOMASS; CATALYST ACTIVITY; GASIFICATION; NATURAL GAS; NICKEL COMPOUNDS; OXYGEN; REACTION KINETICS; REFORMING REACTIONS; STEAM; TAR;

HOT GAS CLEANUP; NAPHTHAS; STEAM REFORMING CATALYSTS;

CATALYSTS;

GAS SEPARATION; REMOVAL; STEAM;

EID: 0032105553     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie9706727     Document Type: Article

References (22)

1. Abatzoglou, N.; Evans, R.; Milne, T. A. Biomass Gasifier Tars: Their Nature, Formation and Conversion. IEA/NREL Report, 1998; draft version.
2. Aldén, H.; Hagstrom, P.; Hallgreen, A.; Waldheim, L. HighTemperature Catalytic Gas Cleaning for Pressurized Gasification Processes. In Developments in Thermochemical Biomass Conversion; Bridgwater, A. V., Boocock, D. G. B., Eds.; Blackie Academic & Professional: London, England, 1997; Vol. 2, pp 1131-1143.
3. Aznar, M. P.; Delgado, J.; Corella, J.; Lahoz, J.; Aragues. J. L. Fuel and Useful Gas by Steam Gasification of Biomass in Fluidized Bed with Downstream Methane and Tar Steam Reforming: New Results. In Biomass for Energy, Industry and Environment; Grassi, G., Collina, A., Zibetta, H., Eds.; 6th EC Conference; Elsevier Applied Science: London, 1992; pp 707-713.
4. Aznar, M. P.; Corella, J.; Delgado, J.; Lahoz, J. Improved Steam Gasification of Lignocellulosic Residues in a Fluidized Bed with Commercial Steam Reforming Catalysts. Ind. Eng. Chem. Res. 1993, 32, 1-10.
5. th EC Conference in Vienna, Austria); Chartier, P. H., Beenackers, A. A. C. M., Eds.; Pergamon Press: London, 1995; Vol. 2, pp 1520-1527.
6. Aznar, M. P.; Gil, J.; Martín, J. A.; Franćes, E.; Olivares, A.; Caballero, M. A.; Pérez, P.; Corella, J. Recent Advances in an AFB Biomass Gasification Pilot Plant with Catalytic Reactors in a Downstream Slip Flow. In New Catalysts for Clean Environment; Maijanen, A., Hase, A., Eds.; Technical Research Centre of Finland (VTT): Espoo, Finland, 1996; pp 169-176.
7. Aznar, M. P.; Corella, J.; Gil, J.; Martin, J. A. Biomass Gasification with Steam and Oxygen Mixtures at Pilot Scale and with Catalytic Gas Upgrading. In Developments in Thermochemical Biomass Conversion; Bridgwater, A. V., Boocock, D. G. B., Eds.; Blackie Academic & Professional: London, England, 1997; Vol. 2, pp 1194-1208.
8. Basini, L.; Piovesan, L. Reduction on Synthesis Gas costs by decrease of steam/carbon and oxygen/carbon ratios in the feedstock. Ind. Eng. Chem. Res. 1998, 37, 258-266.
9. Brage, C.; Sjöström, K; Yu, Q.; Chen, G.; Liliedhal, T.; Rosén, C. Application of solid-phase adsorption (SPS) to monitoring evaluation of biomass tar from different types of gasifiers. In Biomass Gasification and Pyrolysis; Kaltschmit, M., Bridgwater, A. V., Eds.; CPL Press: Aug 1997; pp 218-227.
10. Caballero, M. A.; Aznar, M. P.; Gil, J.; Francés, E.; Corella, J. Commercial steam reforming catalysts to improve biomass gasification with steam-oxygen mixtures. Part I. Hot gas upgrading by the catalytic reactor. Ind. Eng. Chem. Res. 1997, 36, 5227-5239.
11. Corella, J. (University Complutense of Madrid, Spain). Final Report to the EU-DGXII (Brussels) on Project No. AIR2-CT931536, 1996.
12. Corella, J.; Narváez, I.; Orío, A. Criteria for selection of dolomites and catalysts for tar elimination from gasification gas; kinetic constants. In New catalysts for clean environment; Maijanen, A., Hase, A., Eds.; VIT Symposium 163; Julkaisija and Utgivare Publisher: Espoo, Finland, 1996a; pp 177-184.
13. Corella, J.; Narváez, I.; Orio, A. Fresh tar (from biomass gasification) destruction with downstream catalysts: Comparison of their intrinsic activity with a realistic kinetic model. In Power Production from Biomass II; Sipila, K, Korhonen, M., Eds.; VTT Symposium 164; VTT Publishers: Espoo, Finland, 1996b; 269-275.
14. Corella, J.; Orio, A.; Aznar, M. P. Biomass Gasification with Air in Fluidized bed: Hot Gas Clean up and Upgrading with commercial Steam Reforming Catalysts. Ind. Eng. Chem. Res. 1998, submitted for publication.
15. Delgado, J.; Aznar, M. P.; Corella, J. Biomass gasification with steam in fluidized bed: effectiveness of CaO, MgO and CaO-MgO for hot raw gas cleaning. Ind. Eng. Chem. Res. 1997, 36 (5), 1535-1543.
16. Evans, R. J.; Milne, T. A. Chemistry of Tar formation in the Thermochemical Conversion of Biomass. In Develpments in Thermochemical Biomass Conversion; Bridgwater, A. V., Boocock, D. G., Eds.; Blackie Academic: London, U.K., 1997; Vol. 2, pp 803-816.
17. Gil, J.; Aznar, M. P.; Caballero, M. A.; Frances, E.; Corella, J. Biomass Gasification in fluidized bed at pilot scale with steamoxygen mixtures. Product distribution for very different operating conditions. Energy Fuels 1997, 11 (6), 1109-1118.
18. Milne, T. A.; Evans, R. J.; Abatzoglou, N. Biomass Gasifier Tars: Their Nature, Formation and Tolerance Limits in Energy Conversion Devices. In Making a Business from Biomass (Proceedings of the 3rd Biomass Conference of the Americas); Overend, R. P., Chornet, E., Eds.; Pergamon Press: Oxford, U.K., 1997; pp 729-738; Vol. 1.
19. Narváez, I.; Orio, A.; Aznar M. P.; Corella, J. Biomass gasification with air in an atmospheric bubbling fluidized bed. Effect of six operational variables on the quality of the produced raw gas. Ind. Eng. Chem. Res. 1996, 35, 2110-2120.
20. Narváez, I.; Corella, J.; Orío, A. Fresh tar (from a biomass gasifier) elimination over a commercial steam reforming catalyst. Kinetics and effect of different variables of operation. Ind. Eng. Chem. Res. 1997, 36 (2), 317-327.
21. Orio, A.; Corella, J.; Narváez, I. Performance of different dolomites on hot raw gas cleaning from biomass gasification with air. Ind. Eng. Chem. Res. 1997, 36 (9), 3800-3808.
22. Senent, F. Error Theory and Statistics (Book for students); edited by Faculties of Chemistry, Universities of Valladolid (196270) and of Valencia (1970-to date), Spain.