Ozonolysis at vegetation surfaces: A source of acetone, 4-oxopentanal, 6-methyl-5-hepten-2-one, and geranyl acetone in the troposphere

Atmospheric Environment

Volumn 32, Issue 11, 1998, Pages 1893-1902

  Fruekilde, P ^a   Hjorth, J ^a   Jensen, N R ^a   Kotzias, D ^a   Larsen, B ^a  

^a JOINT RESEARCH CENTRE   (Italy)

Author keywords

Epicuticular wax; Heterogenous reactions; NO3; O3; OH; Products; Rate; Sesquiterpenes; Squalene

Indexed keywords

GERANYL ACETONE; OZONOLYSIS; SESQUITERPENES; SQUALENE;

ACETONE; ATMOSPHERIC CHEMISTRY; NITROGEN OXIDES; OZONE; PARTICULATE EMISSIONS;

TROPOSPHERE;

ACETONE; CARBONYL DERIVATIVE; LIPID; OZONE; SESQUITERPENE; SQUALENE; TERPENOID;

OZONE; OZONOLYSIS; TROPOSPHERE; VEGETATION;

ARTICLE; BIOSYNTHESIS; CHEMICAL REACTION KINETICS; HUMAN; NONHUMAN; PLANT LEAF; PRIORITY JOURNAL; TREE; TROPOSPHERE;

MEDITERRANEAN;

CITRUS SINENSIS; ILEX; PINUS PINEA; QUERCUS; QUERCUS ILEX; QUERCUS SUBER;

EID: 0032101842     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1352-2310(97)00485-8     Document Type: Article

References (35)

1. Atkinson, R., Aschmann, S. M. and Pitts, J. N. (1986) Rate constants for the gas phase reactions of the OH radical with a series of monoterpenes at 294 ± 1 K. International Journal of Chemical Kinetics 18, 287-299.
2. 3 with a series of monoterpenes and related compounds at 296 ± 2 K. International Journal of Chemical Kinetics 22, 871-887.
3. Brussol, C., Calogirou, A., Konidari, C. and Kotzias, D. (1996) Sampling and analysis of carbonyls formed during the photooxidation of selected monoterpenes in ambient air. Resenius Environmental Bulletin 5, 534-538.
4. Calogirou, A., Larsen, B. R., Brussol, C., Duane, M. and Kotzias, D. (1996) Decomposition of terpenes by ozone during sampling on Tenax. Analytical Chemistry 68, 1499-1506.
5. Calogirou, A., Duane, M., Kotzias, D., Lahaniati, M. and Larsen, B. R. (1997) Polyphenylenesulfide, noxon®, an ozone scavenger for the analysis of oxygenated terpenes in air. Atmospheric Environment 31, 2741-2751.
6. Ciccioli, P., Brancaleoni, E., Frattoni, M., Cecinato, A. and Brachetti, A. (1993a) Ubiquitous occurrence of semi-volatile carbonyl compounds in tropospheric samples and their possible sources. Atmospheric Environment 27A, 1891-1901.
7. Ciccioli, P., Brancaleoni, E., Cecinato, A., Sparapani, R. and Frattoni, M. (1993b) Identification and determination of biogenic and anthropogenic volatile organic compounds in forest areas of Northern and Southern Europe and a remote site of the Himalaya region by high-resolution gas chromatography-mass spectrometry. Journal of Chromatography 643, 55-69.
8. Ciccioli, P., Cecinato, A., Brancaleoni, E., Frattoni, M., Bruner, F. and Maione, M. (1996) Occurrence of oxygenated volatile organic compounds (VOC) in Antarctica. International Journal of Environmental Analytical Chemistry 62, 245-253.
9. Cutler, D. F., Alvin, K. F. and Price, C. E. (1982) The Plant Cuticle. Academic Press, New York.
10. DeMore, W. B., Sander, S. P., Golden, D. M., Hampson, R. F., Kurylo, M. J., Howard, C. J., Ravishankara, A. R., Kolb, C. E. and Molina, M. J. (1994) Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling. Jet Propulsion Laboratory Publication 94-26, NASA, California, U.S.A.
11. Fehsenfeld, F., Calvert, J., Fall, R., Golden, P., Guenther, A., Hewitt, C., Lamb, B., Liu, S., Trainer, M., Westberg, H. and Zimmreman, P. (1993) Emissions of volatile organic compounds from vegetation and the implications for atmospheric chemistry. Global Biogeochemical Cycles 6, 389-430.
12. Finlayson-Pitts, B. J. and Pitts, J. N. (1986) Atmospheric Chemistry: Fundamentals and Experimental Techniques. Wiley, New York.
13. Glasius, M., Calogirou, A., Jensen, N. R., Hjorth, J. and Nielsen, C. J. (1997) Kinetic study of gas phase reactions of pinonaldehyde and structurally related compounds. International Journal of Chemical Kinetics (in press).
14. 10 carbonyls. International Journal of Environmental Analytical Chemistry 61, 47-64.
15. 9 carbonyls in air. International Journal of Environmental Analytical Chemistry 61, 343-360.
16. Grosjean, E., Grosjean, D. and Seinfeld, J. H. (1996) Gasphase reaction of ozone with trans-2-hexenal, trans-2-hexenyl acetate, ethylvinyl ketone, and 6-methyl-5-hepten-2-one. International Journal of Chemical Kinetics 28, 373-382.
17. Guenther, A., Hewitt, C. N., Erickson, D., Fall, R., Geron, C., Graedel, T., Harley, P., Klinger, L., Lerdau, M., Mckay, W. A., Pierce, T., Scholes, B., Steinbrecher, R., Tallamraju, R., Taylor, J. and Zimmerman, P. (1995) A global model of natural volatile organic compound emissions. Journal of Geophysical Research 100(D5), 8873-8892.
18. Guenther, A., Zimmerman, P., Klinger, L., Greenberg, J., Ennis, C., Davis, K., Pollock, W., Westberg, H., Allwine, G. and Geron, C. (1996) Estimates of regional natural volatile organic compound fluxes from enclosure and ambient measurements. Journal of Geophysical Research 101(D1), 1345-1351.
19. Helmig, D., Pllock, W., Greenberg, J. and Zimmerman, P. (1996) Gas chromatography mass spectrometry analysis of volatile organic trace gases at Mauna Loa Observatory, Hawaii. Journal of Geophysical Research 101(D9), 14,697-14,710.
20. Jacob, D. and Wofsy, S. (1988) Photochemistry of biogenic emissions over the Amazon forest. Journal of Geophysical Research 93, 1477-1486.
21. 3 and dimethylsulphide in air. Atmospheric Environment 25A, 1897-1904.
22. Jensen, N. R., Calogirou, A., Hjorth, J.,. Kotzias, D. and Nielson, C. (1997) Gas phase reactions of selected terpene oxidation products (in preparation).
23. Lamb, B., Gray, D., Westberg, H. and Pierce, T. (1993) A biogenic hydrocarbon emission inventory in the USA using a simple forest canopy model. Atmospheric Environment 27A, 1673-1690.
24. Newman, A. A., ed. (1972) Chemistry of Terpenes and Terpenoids. Academic Press, London and New York.
25. König, G., Brunda, M., Puxbaum, H., Hewitt, C. and Duckham, C. (1995) Relative contribution of oxygenated hydrocarbons to the total biogenic VOC emission of selected Mid-European agricultural and natural plant species. Atmospheric Environment 29A, 861-874.
26. Prinn, R., Cunnold, D., Simmonds, P., Alyea, F., Boldi, R., Crawford, A., Fraser, P., Gutzler, D., Hartley, D., Rosen, R. and Rasmussen, R. (1992) Global average concentration and trend for hydroxyl radicals deduced from ALE/GAGE trichloroethane (methyl chloroform) data for 1978-1990. Journal of Geophysical Research 97 (D2), 2445-2461.
27. 5 at high temperatures. Journal of American Chemical Society 80, 1841-1853.
28. Seufert, G. (1997) BEMA project on biogenic emissions in the Mediterranean area - overview and some aspects of relevance to air chemistry. In The Oxidating Capacity of the Troposphere. Proceedings of the 7th European Symposium Physico-Chemical Behaviour of Atmospheric Pollutants, eds B. Larsen, B. Versino and G. Angeletti. Office for Official Publications of the European Communities, Luxembourg, (EUR 17482 EN).
29. Sharpless, K. B., Amberg, W., Bennani, Y. L., Crispino, G. A., Hartung, J., Jeong, H.-S., Kwong, H.-L., Morikawa, K., Wang, Z.-M., Xu, D. and Zhang, Z.-L. (1992) The osmiumcatalysed asymmetric dihydroxylation: a new ligand class and process improvement. Journal of Organic Chemistry 57, 2768-2771.
30. 3. Environmental Science and Technology 31, 896-904.
31. 3 at 296 ± 2 K. Environmental Science and Technology 30, 1781-1785.
32. Taylor, W. D., Allston, T. D., Moscato, M. J., Fazekas, G. B., Kozlowski, R. and Takacs, G. A. (1980) Atmospheric photodissociation lifetimes for nitromethane, methylnitrite and methylnitrate. International Journal of Chemical Kinetics 12, 231-240.
33. Trainer, M., Williams, E., Parrish, D., Buhr, M., Allwine, E., Westberg, H., Fehsenfeld, F. and Liu, S. (1987) Models and observations of the impact of natural hydrocarbons on rural ozone. Nature 329, 705-707.
34. Wolinsky, J. and Barker, W. (1960) The synthesis of 1-acetyl-4-isopropenyl-l-cyclopentene. Journal of American Chemical Society 82, 636-638.
35. Yeo, H. C. H. and Shibamoto, T. (1992) Formation of formaldehyde and melonaldehyde by photooxidation of squalene. Lipids 27, 50-53.