Kinetic effects induced by cellulose on water-catalyzed reactions. Hydrolysis of 2,4-dinitrophenyl cellulose xanthate and some sugar xanthate ester analogues

Canadian Journal of Chemistry

Volumn 76, Issue 6, 1998, Pages 960-965

  Humeres, Eduardo ^a   Sequinel, Luiz Fernando ^a   Nunes, Mauricéa ^a   Oliveira, Célia M S ^a   Barrie, Patrick J ^b  

^a FEDERAL UNIVERSITY OF SANTA CATARINA   (Brazil)

^b UNIVERSITY COLLEGE LONDON   (United Kingdom)

Author keywords

Cellulose xanthate esters; Hydrolysis; Methyl glucose; Neighbouring OH effect; Water catalysis; Xanthate esters

Indexed keywords

ACETONE; AMINES; CATALYSIS; CELLULOSE; CHEMICAL ACTIVATION; ENTROPY; ESTERS; GLUCOSE; HYDROLYSIS; MIXTURES; OXIDES; WATER;

CELLULOSE XANTHATE ESTER; ENTROPY OF ACTIVATION; HYDROXIDE; METHYL GLUCOSE; NUCLEOPHILE; WATER CATALYZED HYDROLYSIS; XANTHATE ESTER;

REACTION KINETICS;

2,4 DINITROPHENYL CELLULOSE XANTHATE; CELLULOSE; METHYL 4,6 2 BENZYLIDENE ALPHA GLUCOPYRANOSIDE; METHYL GLUCOPYRANOSIDE 6 (2 4 NITROBENZYL XANTHATE); UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION KINETICS; ENTROPY; MOLECULAR INTERACTION; REACTION ANALYSIS; STEREOCHEMISTRY; STRUCTURE ANALYSIS;

EID: 0032100353     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/v98-046     Document Type: Article

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