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Volumn 31, Issue 13, 1998, Pages 4382-4386

Construction of dendritic assemblies: A tailored approach to isomeric metallomacromolecules by means of bis(2,2′:6′,2″-terpyridine)ruthenium(II) connectivity

Author keywords

[No Author keywords available]

Indexed keywords

CYCLIC VOLTAMMETRY; MOLECULAR STRUCTURE; REDOX REACTIONS; RUTHENIUM COMPOUNDS;

EID: 0032100027     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma980280r     Document Type: Article
Times cited : (56)

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    • ESI-MS experiments were performed in MeOH with an accuracy of mass determination ±0.1%.
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    • MALDI-TOF experiments were conducted with a 340 nm laser, linear mode, 2,5-dihydroxylbenzoic acid matrix with an accuracy of mass determination of ±0.2%.
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    • 4NTFB) in anhydrous MeCN] were carefully deoxygenated by bubbling dry nitrogen for at least 10 min. Since the potential was followed through a pseudoreference silver electrode, a second set of voltammograms was obtained after adding a small amount of ferrocene to the solution. The reversible electrochemical signal of the ferrocene/ferrocenium couple did not interfere with the electrochemistry of any of the compounds under study and therefore allowed its use as a reference against which the potentials reported in this work were measured.
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    • Molecular simulations of the metallodendrimers 1 and 2 show that whereas the internal terpyridines of 1 are surrounded by the hyperbranched hydrocarbon environment, the other three terpyridines (the external terpyridine of 1 and both terpyridines of 2) are characterized by a relatively similar solvent-exposed environment.


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