Synthesis and surface energy measurement of semi-fluorinated, low-energy surfaces

Macromolecules

Volumn 31, Issue 13, 1998, Pages 4272-4276

  Perutz, S ^a,b   Wang, J ^a,c   Kramer, E J ^a,d   Ober, C K ^a   Ellis, K ^a  

^a Cornell University   (United States)

^b HEWLETT PACKARD COMPANY   (United States)

^c Corning Inc ^*  (United States)

^d UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; ELASTOMERS; FLUORINE; HYDROLYSIS; HYSTERESIS; INTERFACIAL ENERGY;

SEMIFLUORINATED GROUPS (SFG);

POLYSILANES;

EID: 0032096279     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9700993     Document Type: Article

References (20)

1. Mahler, W.; Guillon, D.; Skoulios, A. Mol. Cryst. Lig. Cryst. Lett. 1985, 2, 111.
2. Viney, C.; Russell, T. P.; Depero, L. E.; Twieg, R. J. Mol. Cryst. Liq. Cryst. 1989, 168, 63. Viney, C.; Twieg, R. J.; Russell, T. P.; Depero, L. E. Liq. Cryst. 1989, 5, 1783. Russell, T. P.; Rabolt, J. F.; Twieg, R. J.; Siemens, R. L. Macromolecules 1986, 19, 1135.
3. Viney, C.; Russell, T. P.; Depero, L. E.; Twieg, R. J. Mol. Cryst. Liq. Cryst. 1989, 168, 63. Viney, C.; Twieg, R. J.; Russell, T. P.; Depero, L. E. Liq. Cryst. 1989, 5, 1783. Russell, T. P.; Rabolt, J. F.; Twieg, R. J.; Siemens, R. L. Macromolecules 1986, 19, 1135.
4. Viney, C.; Russell, T. P.; Depero, L. E.; Twieg, R. J. Mol. Cryst. Liq. Cryst. 1989, 168, 63. Viney, C.; Twieg, R. J.; Russell, T. P.; Depero, L. E. Liq. Cryst. 1989, 5, 1783. Russell, T. P.; Rabolt, J. F.; Twieg, R. J.; Siemens, R. L. Macromolecules 1986, 19, 1135.
5. Hopken, J.; Moller, M.; Lee, M. S.; Percec, V. Makromol. Chem. 1992, 193, 275-284. Percee, V.; Schlueter, D.; Ungar, G. Macromolecules 1997, 30, 645-648. Beyou, E.; Bennetau, B.; Dunoguès, J.; Babin, P.; Teyssié, D.; Boileau, S.; Corpart, J.-M. Polym. Int. 1995, 38, 237-244.
6. Hopken, J.; Moller, M.; Lee, M. S.; Percec, V. Makromol. Chem. 1992, 193, 275-284. Percee, V.; Schlueter, D.; Ungar, G. Macromolecules 1997, 30, 645-648. Beyou, E.; Bennetau, B.; Dunoguès, J.; Babin, P.; Teyssié, D.; Boileau, S.; Corpart, J.-M. Polym. Int. 1995, 38, 237-244.
7. Hopken, J.; Moller, M.; Lee, M. S.; Percec, V. Makromol. Chem. 1992, 193, 275-284. Percee, V.; Schlueter, D.; Ungar, G. Macromolecules 1997, 30, 645-648. Beyou, E.; Bennetau, B.; Dunoguès, J.; Babin, P.; Teyssié, D.; Boileau, S.; Corpart, J.-M. Polym. Int. 1995, 38, 237-244.
8. Davidson, T.; Griffin, A. C.; Wilson, L. M.; Windle, A. H. Macromolecules 1995, 28, 354-357. Hoyle, C. E.; Kang, D.; Jariwala, C.; Griffin, A. C. Polymer 1993, 34, 3070-3075.
9. Davidson, T.; Griffin, A. C.; Wilson, L. M.; Windle, A. H. Macromolecules 1995, 28, 354-357. Hoyle, C. E.; Kang, D.; Jariwala, C.; Griffin, A. C. Polymer 1993, 34, 3070-3075.
10. Ober, C. K.; Wang, J. G.; Mao, G. P. Macromol. Symp. 1997, 118, 701-706.
11. Wang, J.; Mao, G.; Ober, C. K.; Kramer, E. J. Macromolecules 1997, 30, 1904.
12. Johnson, K. L.; Kendall, K.; Roberts, A. D. Proc. R. Soc. London, A 1971, 324, 301.
13. Silberzan, P.; Perutz, S.; Kramer, E. J.; Chaudhury, M. K. Langmuir 1994, 10, 2466.
14. Perutz, S.; Kramer, E. J.; Baney, J.; Hui, C.-Y. Macromolecules 1997, 30, 7964.
15. Patel, S. K.; Malone, S.; Cohen, C.; Gilmor, J. R.; Colby, R. H. Macromolecules 1992, 25, 5241.
16. Chaudhury, M. K.; Whitesides, G. M. Langmuir 1991, 7, 1013.
17. Chaudhury, M. K. Mater. Sci. Eng. 1996, 19, 30.
18. Error for all XPS composition measurements was ±0.1%. The remaining composition of the samples (without H) with 4.8% F was 47.2% C, 23.0% Si, and 25.0% O. No Cl was observable. On the basis of the 4.8% F and the stoichiometry of the attached SFG group and the unmodified PDMS, the theoretical composition should be 4.8% F, 49.5% C, 22.5% Si, and 23.5% O. The increased O and decreased C observed relative to the computed composition probably results from silanol end groups created by the HCl treatment that have not reacted with the SFG groups.
19. Chaudhury, M. K.; Owen, M. J. J. Phys. Chem. 1993, 97, 5722-6.
20. Israelachvili, J. N. Surf. Sci. Rep. 1992, 14, 112.