Segmental dynamics of bulk and silica-adsorbed poly(methyl acrylate)-d3 by deuterium NMR: The effect of molecular weight

Macromolecules

Volumn 31, Issue 13, 1998, Pages 4135-4142

  Lin, Wuu Yung ^a   Blum, Frank D ^a  

^a MISSOURI UNIVERSITY OF SCIENCE AND TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; DRYING; MOLECULAR WEIGHT; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHASE INTERFACES; SILICA; SOLVENTS; TOLUENE;

POLYMETHYL ACRYLATE;

POLYACRYLATES;

EID: 0032096208     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma971725z     Document Type: Article

References (27)

1. Fleer, G. J.; Scheutjens, J. M. H. M. Adv. Colloid Interface Sci. 1982, 16, 341.
2. Takahashi, A.; Kawaguchi, M. Adv. Polym. Sci. 1982, 46, 1.
3. Napper, D. H. Polymeric Stability of Colloidal Dispersions; Academic Press: New York, 1983.
4. Blum, F. D. Ann. Rep. NMR Spectrosc. 1994, 28, 277.
5. Blum, F. D. Colloids Surf. 1990, 45, 361.
6. Facchini, L.; Legrand, A. P. Macromolecules 1984, 17, 2405.
7. Barnet, K. G.; Cosgrove, T.; Vincent, B.; Sissons, D. S.; Cohen-Stuart, M. Macromolecules 1981, 14, 1018.
8. Robb, I. D.; Smith, R. Polymer 1977, 18, 500.
9. Orts, W. J.; van Zanten, J. H.; Wu, W.-L.; Satija, S. K. Phys. Rev. Lett. 1993, 71, 867.
10. Keddie, J. L.; Jones, R. A. L.; Cory, R. A. Europhys. Lett. 1994, 27, 59.
11. Sauer, B. B.; Walsh, D. J. Macromolecules 1994, 27, 432.
12. Israelachvili, J. N.; Tirrel, M.; Klein, J.; Almog, Y. Macromolecules 1984, 17, 204.
13. Lin, W. Y.; Blum, F. Macromolecules 1997, 30, 5331.
14. Reiter, G. Europhys. Lett. 1993, 23, 579.
15. Reiter, G. Macromolecules 1994, 27, 3046.
16. Fleer, G. J.; Cohen-Stuart, M. A.; Scheutjens, J. M. H. M.; Cosgrove, T. Vincent, B. Polymers at Interfaces; Chapman & Hall: London, 1993.
17. De Gennes, P. G. Scaling Concept in Polymer Physics; Cornell University Press: Ithaca, NY, 1979.
18. Spiess, H. W. Colloid Polym. Sci. 1983, 261, 193.
19. Schneider, D. J.; Freed, J. H. In Spin Labeling: Theory and Applications; Berliner, L., Ed.; Academic Press: New York, 1976; Vol. 8.
20. Jagannathan, S.; Blum, F. D.; Polnaszek, C. F. J. Chem. Inf. Comput. Sci. 1987, 27, 167.
21. Abragam, A. Principle of Nuclear Magnetism; Oxford University Press: Oxford, England, 1961.
22. Beckham, H. W.; Spiess, H. W. In NMR Basic Principles and Progress-Solid State NMR III: Organic Matter; Diehl, P., Fluck, E., Grunther, H., Kosfeld, R., Seelig, J., Eds.; Springer-Verlag: Berlin, 1994; pp 163-209.
23. 2H spectrum can be successfully simulated by assuming that the polymer segments simultaneously undergo slow and fast motions. This is also consistent with recent 3-D spectra of poly(ethyl methacrylate) which showed the presence of small plus larger angle fluctuations. See: Kuebler, S. C.; Heuer, A.; Spiess, H. W. Macromolecules 1996, 29, 7079.
24. Hirschinger, J.; Miura, H.; Gardner, K. H.; English, A. D. Macromolecules 1990, 23, 2153.
25. Miura, H.; Hirschinger, J.; English, A. D. Macromolecules 1990, 23, 2169.
26. Schmidt-Rohr, K.; Spiess, H. W. Multidemensional Solid-State NMR and Polymers; Academic Press: London, 1994.
27. Heatley, F. Prog. NMR Spectrosc. 1979, 13, 47.