Kinetic studies of isobutane dehydrogenation and isobutene hydrogenation over Pt/Sn-based catalysts

Industrial and Engineering Chemistry Research

Volumn 37, Issue 5, 1998, Pages 1717-1723

  Cortright, Randy D ^a   Levin, Per E ^a   Dumesic, James A ^a  

^a University of Wisconsin Madison   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; COMPOSITION EFFECTS; DEHYDROGENATION; GAS ADSORPTION; HYDROGENATION; OLEFINS; PLATINUM; POTASSIUM; REACTION KINETICS; SILICA; TIN; ZEOLITES;

HORIUTI-POLANYI MECHANISM;

PARAFFINS;

EID: 0032073072     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie970917f     Document Type: Article

References (19)

1. Benesi, HA.; Curtis, RM.; Studer, H. P. Preparation of Highly Dispersed Catalytic Metals. J. Catal. 1968, 10, 328.
2. Brinkmeyer, FM.; Rohr, DF., Jr. Hydrocarbon Conversion Processes. U.S. Patent 4,866,211, 1987.
3. Cortright, RD.; Dumesic, JA. Microcalorimetric, Spectroscopic, and Kinetic Studies of Silica-Supported Pt and Pt/Sn Catalysts for Isobutane Dehydrogenation. J. Catal. 1994, 148, 771.
4. Cortright, RD.; Dumesic, JA. Effects of Potassium on SilicaSupported Pt and Pt/Sn Catalysts for Isobutane Dehydrogenation. J. Catal. 1995a, 157, 576.
5. Cortright, RD.; Dumesic, JA. L-Zeolite-Supported Platinum and Platinum/Tin Catalysts for Isobutane Dehydrogenation. Appl. Catal. A: General 1995b, 129, 101.
6. Cortright, RD.; Goddard, SA.; Rekoske, J. E.; Dumesic, J. A. Kinetic Study of Ethylene Hydrogenation. J. Catal. 1991, 127, 342.
7. Cortright, RD.; Bergene, E.; Levin, P.; Natal-Santiago, M.; Dumesic, JA. Reactions of Isobutane and Isobutene over Silicaand L-Zeolite-Supported Pt/Sn and Pt/Sn/K Catalysts. 11th International Congress on Catalysis, Baltimore, MD; Elsevier: New York, 1996; Vol. 101, 1185.
8. Hill, JM.; Cortright, RD.; Dumesic, J. A. Silica and L-zeolitesupported Pt, Pt/Sn and Pt/Sn/K Catalysts for Isobutane Dehydrogenation. Accepted for publication Appl. Catal.: A, 1997.
9. Horiuti, J.; Miyahara, KHydrogenation of Ethylene on Metallic Catalysts; Report No. NBS-NSRDS 13, U.S. Government Printing Office: Washington, DC, 1968.
10. Imai, T.; Hung, CW. Dehydrogenation Process using a Catalytic Composition. U.S. Patent 4,430,517, 1983.
11. Lok, LK.; Gaidai, NA.; Gudkov, B. S.; Kiperman, S. L.; Kogan, S. B. Investigation of the Kinetics and Mechanism of the Dehydrogenation of Isobutane on Platinum-Tin Catalysts. Kinet. Katal. 1986, 27 (6), 1365.
12. Mears, DETests for Transport Limitations in Experimental Catalytic Reactors. Ind. Eng. Chem. Process Des. Dev. 1971a, 10 (4), 541.
13. Mears, DEDiagnostic Criteria for Heat Transport Limitations in Fixed Bed Reactors. J. Catal. 1971b, 20, 127.
14. Miller, SJDehydrogenation of Isobutane over a zeolitic catalyst. U.S. Patent 4,727,216, 1986.
15. Natal-Santiago, MA.; Podkolzin, SG.; Cortright, R. D.; Dumesic, J. A. Microcalorimetric Studies of Interaction of Ethene, Isobutene, and Isobutane with Silica-Supported Pd, Pt, and Pt/ Sn. Catal. Lett. 1997, 45, 155.
16. Rekoske, JE.; Cortright, RD.; Goddard, S. A.; Sharma, S. B.; Dumesic, J. A. Microkinetic Analysis of Diverse Experimental Data for Ethylene Hydrogenation on Platinum. J. Phys. Chem. 1992, 96, 1880.
17. Resasco, DE.; Haller, GL. Catalytic Dehydrogenation of Lower Alkanes. Catalysis 1994, 11, 379.
18. Stull, DR.; Westrum, EF., Jr.; Sinke, G. C. The Chemical Thermodynamics of Organic Compounds; John Wiley & Sons: New York, 1969.
19. Weinberg, WH.; Sun, YQuantification of primary and tertiary C-H bond cleavage in alkane activation: isobutane dissociation on Pt(110)-(1 × 2). Surf. Sci. Lett. 1992, 277, L39.