Evidence for direct γ-NiOOH ↔ β-Ni(OH)2 transitions during electrochemical cycling of the nickel hydroxide electrode

Journal of the Electrochemical Society

Volumn 145, Issue 5, 1998, Pages 1434-1441

  Sac Epee N ^a   Palacin M R ^a,c   Delahaye Vidal, A ^a   Chabre, Y ^b,c   Tarascon J M ^a,c  

^a UNIVERSITÉ DE PICARDIE JULES VERNE   (France)

^b UNIV GRENOBLE ALPES   (France)

^c ELECTROCHEMICAL SOCIETY

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRIC DISCHARGES; NICKEL COMPOUNDS; OXIDATION; PHASE SEPARATION; PHASE TRANSITIONS; REDUCTION; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION ANALYSIS;

ELECTROCHEMICAL CYCLING; INTERMITTENT GALVANOSTATIC TECHNIQUE; NICKEL HYDROXIDE; POTENTIODYNAMIC TECHNIQUE;

ELECTROCHEMICAL ELECTRODES;

EID: 0032070284     PISSN: 00134651     EISSN: None     Source Type: Journal    
DOI: 10.1149/1.1838501     Document Type: Article

References (30)

1. H. Bode, K. Dehmelt, and J. Witte, Electrochim. Acta., 11, 1079 (1966).
2. S. Le Bihan, J. Guenot, and M. Figlarz, C. R. Acad. Sci., C270, 2131 (1970).
3. R. S. McEwen, J. Phys. Chem., 75, 1782 (1971).
4. P. Genin, A. Delahaye-Vidai, F. Portemer, K. Tekaia-Elhsissen, and M. Figlarz, Eur. J. Solid State Inorg. Chem., 28, 505 (1991).
5. A. Delahaye-Vidal and M. Figlarz, J. Appl. Electrochem., 17, 589 (1987).
6. W. E. O'Grady, K. I. Pandya, K. E. Swider, and D. A. Corrigan, J. Electrochem. Soc., 143, 1613 (1996).
7. P. Oliva, J. Léonardi, J. F. Laurent, C. Delmas, J. J. Braconnier, M. Figlarz, F. Fievet, and A. de Guibert, J. Power Sources, 8, 229 (1982).
8. C. Delmas, Y. Borthomieu, C. Faure, A. Delahaye-Vidal, and M. Figlarz, Solid State Ionics, 32/33, 104 (1989).
9. J. McBreen, in Modern Aspects of Electrochemistry, R. E. White, J. O'M. Bockris, and B. E. Conway, Editors, p. 46, Plenum Press, London (1990).
10. R. Barnard, G. T. Crickmore, J. A. Lee, and F. L. Tye, J. Appl. Electrochem., 10, 61 (1980).
11. B. Klapste, K. Mickja, J. Mrha, and J. Vondrak, J. Appl. Electrochem., 8, 351 (1982).
12. H. S. Lim and S. A. Verzwyvelt, J. Power Sources, 22, 213 (188).
13. H. Vaidyanathan, J. Power Sources, 22, 221 (1988).
14. A. H. Zimmerman, in Nickel Hydroxide Electrode, D. A. Corrigan and A. H. Zimmerman, Editors, PV 90-4, p. 311, The Electrochemical Society Proceedings Series Pennington, NJ (1990).
15. A. H. Zimmerman, in Proceedings of the 29th IECEC, Vol. 4, p. 63, American Institute of Aeronautics and Astronautics (1994).
16. M. Jain, S. Motupally, and J. W. Weidner, Abstract 37, p. 47, The Electrochemical Society Meeting Abstracts, Vol. 96-2, San Antonio, TX, October 6-11, 1992.
17. N. Sac-Epée, M. R. Palàcin, B. Beaudoin, A. Delahaye-Vidal, T. Jamin, Y. Chabre, and J-M. Tarascon, J. Electrochem. Soc., 144, 3896 (1997).
18. A. H. Thompson, J. Electrochem. Soc., 126, 603 (1979).
19. A. H. Thompson, Rev. Sci. Instrum., 54, 329 (1983).
20. Y. Chabre, NATO ASI Series, B305, 181 (1993).
21. Y. Chabre, J. Electrochem. Soc., 138, 329 (1991).
22. Y. Chabre and J. Pannetier, Prog. Solid State Chem., 23, 1 (1995).
23. R. Barnard, C. Randell, and F. L. Tye, J. Appl. Electrochem., 10, 109 (1980).
24. R. Barnard, C. Randell, and F. L. Tye, J. Appl. Electrochem., 10, 127 (1980).
25. R. Barnard, C. Randell, and F. L. Tye, J. Electronal. Chem., 119, 17 (1981).
26. R. Barnard, C. Randell, and F. L. Tye, J. Appl. Electrochem., 11, 517 (1981).
27. M. S. Kim, T. S. Hwang, and K. B. Kim, J. Electrochem. Soc., 144, 1537 (1997).
28. C. Tessier and C. Delmas, Paper presented 9th International Symposium on Intercalation Compounds, Bordeaux-Arcachon, France, May 1997.
29. P. Bernard, C. Gabrielli, M. Keddam, and H. Tanekouti, Electrochim. Acta, 36, 743 (1991).
30. P. Strobel and C. Mouget, Mater. Res. Bull., 28, 93 (1993).