Mass Transfer of Alkanes in Zeolite Packed-Bed Reactors Studied with Positron Emission Profiling (PEP). 1. Experiments

Industrial and Engineering Chemistry Research

Volumn 37, Issue 3, 1998, Pages 815-824

  Andersen, Bruce G ^a   De Gauw, Frank J M M ^a   Noordhoek, Niels J ^a   Van IJzendoorn, Leo J ^a   Van Santen, Rutger A ^a   De Voigt, Martien J A ^a  

^a EINDHOVEN UNIVERSITY OF TECHNOLOGY   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; CHROMATOGRAPHY; DIFFUSION IN SOLIDS; ESTIMATION; ISOMERIZATION; MASS TRANSFER; PACKED BEDS; ZEOLITES;

HYDROISOMERIZATION; POSITRON EMISSION PROFILING (PEP); TRACER PULSE CHROMATOGRAPHY;

PARAFFINS;

MASS TRANSFER; PACKED BED; ZEOLITE;

EID: 0032029569     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie970346r     Document Type: Article

References (34)

1. Bates, S. P.; Van Well, W. J. M.; Van Santen, R. A.; Smit, B. Energetics of n-Alkanes in Zeolites: A Configurational-Bias Monte Carlo Investigation into Pore Size Dependence. J. Am. Chem. Soc. 1996, 118, 6753.
2. Carberry, J. J.; Bretton, R. H. AIChE J. 1958, 4, 367.
3. Choudhary, V. R.; Doraiswamy, L. K. Applications of Gas Chromatography in Catalysis. Ind. Eng. Chem. Process Des. Dev. 1971, 10, 218.
4. Condor, J. L.; Young, C. L. Physicochemical Measurements by Gas-Adsorption Chromography; John Wiley & Sons: Chicester, U.K., 1979.
5. 11C-Labeled n-Hexane for Use in Positron Emission Imaging. J. Mol. Catal. A. 1996, 107, 153.
6. Derouane, E. G.; Nagy, J. B.; Fernandez, C.; Gabelica, Z.; Laurent, E.; Maljean, P. Diffusion of Alkanes in Molecular Sieves: Evidence for Confinement Effects. Appl. Catal. 1988, 40, L1.
7. Eder, F.; Lercher, J. A. On the Role of the Pore Size and Tortusity of Alkanes in Molecular Sieves. J. Phys. Chem. B 1997, 101, 1273.
8. Haast, M. Performance of the EUT Positron Emission Profiling Detector. M. Sc. Thesis, Eindhoven University of Technology, Eindhoven, The Netherlands, 1995.
9. Haynes, H. W., Jr. The Experimental Evaluation of Catalyst Effective Diffusivity. Catal. Rev.-Sci. Eng. 1988, 30, 563.
10. Helfferich, F.; Peterson, D. L. Accurate Chromatographic Method for Sorption Isotherms and Phase Equilibria. Science 1963, 142, 661.
11. Hufton, J. H.; Danner, R. P. Chromatographic Study of Alkanes in Silicalite: Transport Properties. AIChE J. 1993, 39, 962.
12. Hyun, S. H.; Danner, R. P. Adsorption Equilibrium Constants and Intraparticle Diffusivities in Molecular Sieves by Tracer-Pulse Chromatography. AIChE J. 1985, 31, 1077.
13. Jonkers, G.; Vonkeman, K. A.; Van der Waal, S. W. A.; Van Santen, R. A. Surface Catalysis Studied by In Situ Positron Emission. Nature 1992, 355, 63.
14. Karger; J.; Ruthven, D. M. Diffusion in Zeolites and Other Microporous Solids; John Wiley & Sons, New York, 1992.
15. Keibal, V. L.; Kiselev, A. V.; Savinov, I. M.; Khudyakov, V. L.; Shcherbakova, K. D.; Yashin, Y. I. Differential Heats of Adsorption of Sraight-Chain Alkanes at Low Surface Coverages on Different Adsorbents on the Basis of Gas Chromatographic Data. Russ. J. Phys. Chem. 1967, 41, 1203.
16. Kiselev, A. V.; Nikitin, Y. S.; Petrova, R. S.; Shcherbakova, K. D.; Yashin, Y. I. Effect of Pore Size of Silica Gels on the Separation of Hydrocarbons. Anal. Chem. 1964, 36, 1526.
17. Kulkarni, B. D.; Doraiswamy, L. K. Estimation of Effective Transport Properties in Packed Bed Reactors. Catal. Rev.-Sci. Eng. 1980, 22, 431.
18. Lopez Garzon, F. J.; Domingo Garcia, M. The Use of Gas Chromatography to Study the Adsorption from Gaseous Phase at the Infinite Dilution. In Adsorption on New and Modified Inorganic Sorbents; Dabrowski, A.; Tertykh, V. A., Eds.; Elsevier Science: Amsterdam, 1996.
19. rd), 392.
20. Mangnus, A. V. G.; Van IJzendoorn, L. J.; De Goeij, J. J. M.; Cunningham, R. H.; Van Santen, R. A.; De Voigt, M. J. A. A BGO Detector for Positron Emission Profiling in Catalyts. NIM B 1995, 99, 649.
21. McKee, S. L.; Parker, D. J.; Williams, R. A. Visualization of Size-Dependent Particle Segregation in Slurry Mixers Using Positron Emission Tomography. In Frontiers in Industrial Process Tomography; Engineering Foundation: New York, 1995.
22. Noordhoek, N. J.; Van IJzendoorn, L. J.; Anderson, B. G.; De Gauw, F. J.; Van Santen, R. A.; De Voigt, M. J. Mass Transfer of Alkanes in Zeolite Packed-Bed Reactors Studied with Positron Emission Profiling (PEP): Part II: Modeling. Ind. Eng. Chem. Res., 1998, 37, 825-833.
23. Ruthven, D. M. Principles of Adsorption and Adsorption Processes; Wiley-Interscience: New York, 1984.
24. Ruthven, D. M.; Ching, C. B. Modeling of Chromatographic Processes. In Preparative and Production Scale Chromatography; Ganetsos, G., Barker, P. E., Eds.; Marcel Dekker: New York, 1992.
25. Satterfield, C. N.; Margetts, W. G. Diffusion in Sodium Mordenite. AIChE J. 1971, 17, 295.
26. Siegel, S.; Cherry, S. R.; Ricci, A. R.; Shao, Y.; Phelps, M. E. Development of Continuous Detectors for High Resolution Animal PET System. IEEE 1995, 1662.
27. Smith, J. M. Rate Parameters for Catalytic Reactors by Dynamic Techniques. In Catalysis on the Energy Scene; Kaliaguine, S., Mahay, A., Eds.; Elsevier: Amsterdam, 1984.
28. Suzuki, M. Adsorption Engineering; Kodansha: Tokyo, 1990.
29. Suzuki, M.; Smith, J. P. Kinetic Studies by Chromatography. Chem. Eng. Sci. 1971, 26, 221.
30. Van Deemter, J. J.; Zuiderweg, F. J.; Klinkenberg, A. Chem. Eng. Sci. 1956, 5, 271.
31. Van Santen, R. A.; Anderson, B. G.; Cunningham, R. H.; Mangnus, A. V. G.; Van IJzendoorn, L. J.; De Voigt, M. J. A. In Situ Observation of Transient Reaction Phenomena Occurring on Zeolite Catalysts with the Aid of Positron Emission Profiling. Angew. Chem., Int. Ed. Engl. 1996, 35, 2785.
32. Voogd, P.; Van Bekkum, H.; Shavit, D.; Kouwenhoven, H. W. Effect of Zeolite Structure and Morphology on Intracrystalline n-Hexane Diffusion in Pentasil Zeolites Studied by the Zero-Length Column Method. J. Chem. Soc., Faraday Trans. 1991, 87, 3575.
33. Wakao, N.; Kaguei, S. Heat and Mass Transfer in Packed Beds; Gordon and Breach Science: New York, 1982.
34. Yanovskii, M. I.; Berman, A. D. The Use of Chromatography in Catalysis. In Preparative and Production Scale Chromatography; Ganetsos, G., Barker, P. E., Eds.; Marcel Dekker: New York, 1992.