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For general overview on polyolefins by metallocene catalyst, see Brintzinger, H. H.; Fischer, D.; Mulhaupt, R.; Rieger, B.; Waymouth, R. W. Angew Chem., Int. Ed. Engl. 1995, 34, 1143. Kaminsky, W. Macromol. Chem. Phys. 1996, 197(12), 3907-3945. Hamielec, A. E.; Soares, J. B. P. Prog. Polym. Sci. 1996, 21(4), 651-706. Soga, K. Macromol. Symp. 1996, 10, 281-288. Montagna, A. A. Chemtech 1995, 44. Galimberty, M.; et al. Macromol. Symp. 1995, 89, 259.
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n 870, 0.057 mol) with 95% vinylidene terminal double bonds was then added showly to the aforementioned solution, and the mixture was refluxed for 6 h under nitrogen. The reaction mixture was then filtered, and the filtrate was evaporated on rotary evaporator to obtain the product.
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note
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-3 mol) of diethylenetriamine (DETA) was added. The solution was stirred at room temperature for 72 h. The product was diluted with 50 mL of heptane and filtered. The solvent was removed initially by nitrogen stripping and then by high vacuum.
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85034478643
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Patil, A.O.1
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