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note
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Due to the lack of a distinct peak in the methane signal, the area under the curve for methane was integrated up to ∼500 K to obtain the product percentages shown in Table 3.
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36
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11744303708
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note
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The relative amounts of hydrocarbon products were calculated from the integrated area of the TPD curves. The integrated areas were then calibrated by determining the mass fragmentation pattern of each gss and taking into account the different ion gauge sensitivities for each of the gases. The ionization gauge sensitivities are as follows: methane, 1.4; ethene, 2.3; ethane, 2.7; propane, 4.3, and were taken from NASA Technical Note, TN D-5285, June 1969 (N69-29331). The results given in Table 3 for methane are the least reliable because the m/e = 16 channel did not show a pronounced peak.
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