Diffusivities of n-Alkanes in Silicalite by Steady-State Single-Crystal Membrane Technique

AIChE Journal

Volumn 44, Issue 3, 1998, Pages 681-694

  Talu, Orhan ^a   Sun, Matthew S ^a   Shah, D B ^a  

^a Cleveland State University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; CRYSTALLOGRAPHY; DIFFUSION IN SOLIDS; MATHEMATICAL MODELS; PARAFFINS; SILICATE MINERALS; SINGLE CRYSTALS;

SILICALITE; SINGLE CRYSTAL MEMBRANE;

ADSORPTION;

EID: 0032025717     PISSN: 00011541     EISSN: None     Source Type: Journal    
DOI: 10.1002/aic.690440316     Document Type: Article

References (67)

1. Abdul-Rehman, H. B., M. A. Hasanain, and K. F. Loughlin, "Quaternary, Ternary, Binary and Pure Component Sorption on Zeolites: 1. Light Alkanes on Linde S-115 Silicalite at Moderate to High Pressures," Ind. Eng. Chem. Res., 29, 1525 (1990).
2. Baertsch, C. D., H. H. Funke, J. L. Falconer, and R. D. Noble, "Permeation of Aromatic Hydrocarbon Vapors through Silicalite - Zeolite Membranes," J. Phys. Chem., 100, 7676 (1996).
3. Bourdin, V., A. Germnus, P. Grenier, and J. Kärger, "Application of the Thermal Frequency Response Method and of PFGNMR to Study Water Diffusion in Zeolite NaX," Adsorption, 2, 205 (1996).
4. Bülow, M., P. Struve, and W. Mietk, "Experimental Evidence of the Influence of Sorption-Heat Release Process on the Sorption Kinetics of Benzene in NaX Zeolite Crystals," J. Chem. Soc., Faraday Trans., 80(1), 813 (1984).
5. Bülow, M., H. Schlodder, L. V. C. Rees, and R. E. Richards, "Molecular Mobility of Hydrocarbon ZSM/Silicalite System Studied by Sorption Uptake and FR Methods," Proc. Int. Conf. on Zeolites, Amsterdam, Netherlands, p. 579 (1989).
6. Caro, J., M. Bülow, W. Schirmer, J. Kärger, W. Heink, and H. Pfeifer, "Microdynamics of Methane, Ethane, and Propane in ZSM-5 Type Zeolites," J. Chem. Soc., Farad. Trans., 81, 2541 (1985).
7. Caro, J., M. Noack, J. Richter-Mendau, F. Marlow, D. Petersohn, M. Griepentrog, and J. Kornatowski, "Selective Sorption Uptake Kinetics of n-Hexane on ZSM-5 - A New Method for Measuring Anisotropie Diffusivities," J. Phys. Chem., 97, 13685 (1993).
8. Callow, C. R. A., C. M. Freeman, B. Vessal, S. M. Tomlinson, and M. Leslie, "Molecular Dynamics Studies of Hydrocarbon Diffusion in Zeolites," J. Chem. Soc., Faraday. Trans., 87, 1947 (1991).
9. Chen, N. Y., T. F. Degnam, Jr., and C. M. Smith, "Molecular Transport and Reaction in Zeolites: Design and Application of Shape Selective Catalysts," VCH (1994).
10. Chiang, A. S. T., A. G. Dixon, and Y. H. Ma, "The Determination of Zeolite Crystal Diffusivity by GC: II. Experimental," Chem. Eng. Sci., 39, 1461 (1984).
11. 1H Nuclear Magnetic Resonance Investigation of the Diffusion of Light n-Alkanes in Zeolite ZSM-5," J. Chem. Soc., Farad. Trans., 87, 1935 (1991).
12. Demontis, P., G. B. Suffritti, E. S. Fois, and S. Quartieri, "Molecular Dynamics Study on Zeolites. 6. Temperature Dependence of Diffusion of Methane in Silicalite," J. Phys. Chem., 96, 1482 (1992).
13. Eic, M., and D. M. Ruthven, "Intracrystalline Diffusion of Linear Paraffins and Benzene in Silicalite Studied by the ZLC Method," Proc. Int. Conf. on Zeolites, Elsevier, Amsterdam, p. 897 (1989).
14. Funke, H. H., M. G. Kovalchick, J. L. Falconer, and R. D. Noble, "Separation of Hydrocarbon Isomer Vapors with Silicalite Zeolite," Ind. Eng. Chem. Res., 35, 1575 (1996).
15. Gibbs, J. W., Collected Works, Yale Univ. Press, New Haven, CT (1928).
16. Goodbody, S. J., K. Watanabe, D. M. Gowan, J. P. R. B. Walton, and N. Quirke, "Molecular Simulation of Melhane and Butane in Silicalite," J. Chem. Soc., Farad. Trans., 87(13), 1951 (1991).
17. Guo, C.-J., O. Talu, and D. T. Hayhurst, "Phase Transition and Structural Heterogeneity: Benzene Adsorption on Silicalite," AIChE J., 35, 573 (1989).
18. 5 Normal Paraffins in Silicalite," Zeolites, 8, 27 (1988).
19. Heink, W., J. Kärger, and H. Pfeifer, "High-Temperature Pulsed Field Gradient Nuclear Magnetic Resonance Self-diffusion Measurement of n-Alkanes in MFI-type Zeolites," J. Chem. Soc., Farad. Trans., 88(23), 3505 (1992).
20. Hong, U., J. Kärger, R. Kramer, H. Pfeifer, and G. Seiffert, "PFG NMR Study of Diffusion Anisotropy in Oriented ZSM-5 Type Zeolite Crystallites," Zeolites, 11, 816 (1991).
21. Hufton, J. R., and R. P. Danner, "Gas-Solid Diffusion and Equilibrium Parameters by Tracer Pulse Chromatography," Chem. Eng. Sci., 46, 2079 (1991).
22. Hufton, J. R., S. Brandani, and D. M. Ruthven, "Measurement of Intracrystalline Diffusion by Zero Length Column Tracer Exchange," Zeolites and Related Microporous Materials, J. Weitkamp, H. G. Karge, H. Pfeifer, and W. Holderich, eds, Eisevier, Amsterdam, p. 1321 (1994).
23. Jobic, H., M. Bee, J. Caro, M. Bülow, and J. Kärger, "Molecular Self-Diffusion of Methane in Zeolite ZSM-5 by Quasi-Elastic Neutron Scattering and Nuclear Magnetic Resonance Pulsed Field Gradient Technique," J. Chem. Soc., Farad. Trans., 85(1), 4201 (1989).
24. Jobic, H., M. Bee, and J. Caro, "Translational Mobility of n-Butane and n-Hexane in ZSM-5 Measured by Quasi-Elastic Neutron Scattering," Proc. Int. Conf. on Zeolites, Montreal, Canada, p. 121 (1992a).
25. Jobic, H., M. Bee, and G. L. Kearley, "Dynamics of Ethane and Propane in Zeolite ZSM-5 Studied by QENS," Zeolites, 12, 146 (1992b).
26. June, R. L., A. T. Bell, and D. N. Theodorou, "Molecular Dynamics Studies of Butane and Hexane in Silicalite," J. Phys. Chem., 94, 8232 (1990).
27. June, R. L., A. T. Bell, and D. N. Theodorou, "Molecular Dynamics Study of Butane and Hexane in Silicalite," J. Phys. Chem., 96, 1051 (1992).
28. Karge, H. G., and W. Niessen, "A New Method for the Study of Diffusion and Counter Diffusion in Zeolites," Catal. Today, 8, 451 (1991).
29. Kärger, J., and D. M. Ruthven, "Diffusion in Zeolites: Comparison of Sorption and NMR Diffusivities," J. Chem. Soc., Farad. Trans., 77, 1485 (1981).
30. Kärger, J., and D. M. Ruthven, "On the Comparison Between Macroscopic and NMR Measurements of Intracrystalline Diffusion in Zeolites," Zeolites, 9, 267 (1989).
31. Kärger, J., "Random Walk Through Two-Dimensional Networks: A Simple Means to Correlate the Coefficients of Anisotropie Diffusion in ZSM-5 Type Zeolites," J. Phys. Chem., 95, 5558 (1991).
32. Kärger, J., and D. M. Ruthven, Diffusion in Zeolites and Other Microporous Solids, Wiley, New York (1992).
33. Lewis, J. E., G. R. Gavalas, and M. E. Davis, "Permeation Studies on Oriented Single-Crystal Ferrierite Membranes," AIChE J., 43, 83 (1997).
34. Li, J., and O. Talu, "Structural Effect on Molecular Simulations of Tight-Pore Systems," J. Chem. Soc., Farad. Trans., 89, 1683 (1993).
35. Maginn, E. J., A. T. Bell, and D. N. Theodorou, "Transport Diffusivity of Methane in Silicalite from Equilibrium and Nonequilibrium Simulations," J. Phys. Chem., 97, 4173 (1993).
36. Maginn, E. J., A. T. Bell, and D. N. Theodorou, "Dynamics of Long n-Alkanes in Silicalite: A Hierarchical Simulation Approach," J. Phys. Chem., 100, 7155 (1996).
37. Myers, A. L., and J. M. Prausnitz, "Thermodynamics of Mixed-Gas Adsorption," AIChE J., 11(1), 121 (1965).
38. Nicholas, J. B., F. R. Trouw, J. E. Mertz, L. E. Iton, and A. J. Hopfinger, "Molecular Dynamics Simulation of Propane and Methane in Silicalite," J. Phys. Chem., 97, 4149 (1993).
39. Nowak, A. K., C. J. J. den Ouden, S. D. Pickett, B. Smit, A. K. Cheetham, M. F. M. Post, and J. M. Thomas, "Mobility of Adsorbed Species in Zeolites: Methane, Ethane and Propane Diffusivities," J. Phys. Chem., 95, 848 (1991).
40. Olson, D. H., and R. T. Reischman, "Structure Related Paraffin Sorption in ZSM-5," Zeolites, 17, 434 (1996).
41. Paravar, A. R., and D. T. Hayhurst, "Direct Measurement of Diffusivity for Butane Across a Single Large Silicalite Crystal," Proc. Int. Conf. on Zeolites, Reno, NV, p. 217 (1984).
42. Quig, A., and L. V. C. Rees, "Self-Diffusion of n-Alkanes in Type A Zeolite," J. Chem. Soc., Farad. Trans., 72, 771 (1976).
43. Quresh, W. R., and J. Wei, "One- and Two-Component Diffusion in Zeolites ZSM-5," J. Catal., 126, 126 (1990).
44. Richards, R. E., and L. V. C. Rees, "Sorption and Packing of n-Alkane Molecules in ZSM-5," Langmuir, 3, 335 (1987).
45. Ruthven, D. M., Principles of Adsorption and Adsorption Processes, Wiley, New York (1984).
46. Ruthven, D. M., P. Stapleton, and K. Dahlke, "Application of the ZLC Method to the Measurement of Intracrystalline Counter-Diffusion in Liquid-Zeolite Systems," Proc. Int. Conf. on Zeolites, Montreal, Canada (1992).
47. Rynders, R., M. Rao, and S. Sircar, "Isotope Exchange Technique for Measurement of Gas Adsorption Equilibria and Kinetics," AIChE J., 43, 2456 (1997).
48. Segura, C. J., and W. G. Chapman, "Associating Fluids with Four Bonding Sites Against Solid Surfaces: Monte Carlo Simulations," Mol. Phys., 86, 415 (1995).
49. Shah, D. B., and D. M. Ruthven, "Measurement of Zeolites Diffusivities and Equilibrium Isotherm by Chromatography," AIChE J., 23, 804 (1977).
50. Shen, D., and L. V. C. Rees, "Adsorption and Diffusion of n-Butane and 2-Butyne in Silicalite-1," Zeolites, 11, 684 (1991).
51. Shen, D., and L. V. C. Rees, "Study of Fast Diffusion in Zeolites Using a Higher Harmonic Frequency Response Method," J. Chem. Soc., Farad. Trans., 90(19), 3011 (1994).
52. Sircar, S., and A. L. Myers, "Surface Potential Theory of Multi-Layer Adsorption from Gas Mixtures," Chem. Eng. Sci., 28, 489 (1973).
53. Sircar, S., "Excess Properties and Thermodynamics of Multicomponent Adsorption," J. Chem. Soc., Farad. Trans., 81, 1527 (1985).
54. Sircar, S., "Novel Application of Adsorption Technology," Fundamentals of Adsorption, M. Suzuki, ed., Kodansha, Japan, p. 3 (1992).
55. Sircar, S., "Data Representation for Binary and Multicomponent Gas Adsorption Equilibria," Adsorption, 2, 327 (1996).
56. Smit, B., and J. L. Siepmann, "Simulating the Adsorption of Alkanes in Zeolites," Science, 264, 1118 (1994).
57. Sun, M. S., O. Talu, and D. B. Shah, "Diffusion Measurements Through Embedded Zeolite Crystals," AIChE J., 42, 3001 (1996a).
58. 10 Normal Alkanes in Silicalite Crystals," J. Phys. Chem., 100, 17276 (1996b).
59. Talu, O., and I. Zwiebel, "Multicomponent Adsorption Equilibria of Non-Ideal Mixtures," AIChE J., 32(8), 1263 (1986).
60. Talu, O., C.-J. Guo, and D. T. Hayhurst, "Heterogeneous Adsorption Equilibria with Comparable Molecule and Pore Sizes," J. Phys. Chem., 93(21), 7294 (1989).
61. Talu, O., J. Li, R. Kumar, P. Mathias, J. D. Moyer, Jr., and J. M. Schork, "Measurement and Correlation of Oxygen/Nitrogen/ 5A - Zeolite Adsorption Equilibria for Air Separation," Gas Sep. Purif., 10, 149 (1996a).
62. Talu, O., "Equilibrium Measurement Techniques for Screening New Adsorbent Materials," Proc. World Cong. of Chem. Eng., San Diego, CA (1996b).
63. Valenzuela, D. P., and A. L. Myers, Adsorption Equilibrium Data Handbook, Prentice Hall, Englewood Cliffs, NJ (1989).
64. Van-Den-Begin, L. V. C. Rees, J. Caro, and M. Bülow, "Fast Adsorption-Desorption Kinetics of Hydrocarbons in Silicalite-1 by the Single Step Frequency Response Method," Zeolites, 9, 287 (1989).
65. Van Koningsveld, H., F. Tuinstra, H. van Bekkum, and J. C. Jansen, "The Location of p-Xylene in a Single Crystal of Zeolite H-ZSM-5 with a New, Sorbate Induced, Orthorhombic Framework Symmetry," Acta Cryst. B, 45, 423 (1989).
66. Van Ness, H. C., "Adsorption of Gases on Solids," Ind. Eng. Chem. Fundam., 8(3), 464 (1969).
67. Van Well, W. J. M., J. P. Wolthuizen, B. Smit, J. H. C. van Hooff, and R. A. van Santen, "Commensurate Freezing of n-Alkanes in Silicalite," Angew. Chem. Int. Ed. Engl., 34(22), 2543 (1995).