Colligative properties of polyelectrolyte solutions

Fluid Phase Equilibria

Volumn 145, Issue 1, 1998, Pages 15-41

  Nagvekar, Manoj ^a   Tihminlioglu, Funda ^b   Danner, Ronald P ^b  

^a SGT INC   (United States)

^b The Pennsylvania State University   (United States)

Author keywords

Counterion activity coefficient; Excess Gibbs free energy; Osmotic coefficient; Polyelectrolyte solutions

Indexed keywords

COMPOSITION; GIBBS FREE ENERGY; IONS; MATHEMATICAL MODELS; MOLECULAR DYNAMICS; OSMOSIS; PHYSICAL PROPERTIES; POLYELECTROLYTES;

COLLIGATIVE PROPERTIES; COUNTERION ACTIVITY COEFFICIENT; EXCESS GIBBS FREE ENERGY; OSMOTIC COEFFICIENT; POLYELECTROLYTE SOLUTIONS;

SOLUTIONS;

EID: 0032021638     PISSN: 03783812     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0378-3812(97)00304-x     Document Type: Article

References (48)

1. C.-C. Chen, H.I. Britt, J.F. Boston, L.B. Evans, Local composition model for excess Gibbs energy of electrolyte systems: Part I. Single solvent single completely dissociated electrolyte, AIChE J. 28 (1982) 588.
2. A.B. Scranton, B. Rangarajan, J. Klier, Biomedical applications of polyelectrolytes, Adv. Polym. Sci. 122 (1995) 1.
3. A. Rembaum, E. Sélégny, Polyelectrolytes and their Applications, Reidel, Dordrecht, Holland, 1974.
4. F. Oosawa, N. Imani, I. Kajawa, J. Polym. Sci. 13 (1954) 93.
5. M. Mandel, Encyclopedia Polym. Sci. 11 (1988) 739.
6. M. Mandel, in: M. Hara (Ed.), Polyelectrolytes, Marcel Dekker, New York, 1993.
7. S. Forster, M. Schmidt, Polyelectrolyte in solution, Adv. Polym. Sci. 120 (1995) 53.
8. G.S. Manning, Limiting laws and counterion condensation in polyelectrolyte solutions: I. Colligative properties, J. Chem. Phys. 51 (1969) 924.
9. G.S. Manning, Limiting laws and counterion condensation in polyelectrolyte solutions: II. Self-diffusion of small ions, J. Chem. Phys. 51 (1969) 934.
10. G.S. Manning, Limiting laws and counterion condensation in polyelectrolyte solutions: III. An analysis based on the mayer ionic solution theory, J. Chem. Phys. 51 (1969) 3249.
11. G.S. Manning, Polyelectrolytes, Annu. Rev. Phys. Chem. 23 (1972) 117.
12. M. Nagvekar, R.P. Danner, An excess Gibbs free energy model for polyelectrolyte solutions, Fluid Phase Equilib. 53 (1989) 219.
13. R.M. Armstrong, U.P. Strauss, Encyclopedia Polym. Sci. Technol. 10 (1969) 781.
14. T. Alfrey Jr., P.W. Berg, H. Morawetz, The counterion distribution in solutions of rod-shaped polyelectrolyte, J. Polym. Sci. 7 (1951) 543.
15. R.M. Fuoss, A. Katchalsky, S. Lifson, The potential of an infinite rod-like molecule and the distribution of counterions, Proc. Natl. Acad. Sci. 37 (1951) 579.
16. F. Oosawa, Polyelectrolytes, Marcel Dekker, New York, NY, 1971.
17. M. Mandel, Polyelectrolytes solutions without added salt: concentration effects and condensation, Eur. Polym. J. 19 (1983) 911.
18. N. Imai, T. Onishi, Analytical solution to Poisson-Boltzmann equation for two-dimensional many-center problem, J. Chem. Phys. 30 (1959) 1115.
19. A.D. MacGillivray, J.J. Winkleman Jr., On an asymptotic solution of the Poisson-Boltzmann equation - the moderately charged cylinder, J. Chem. Phys. 45 (1966) 2184.
20. A.D. MacGillivray, Upper bounds on solutions of the Poisson-Boltzmann equation near the limit of infinite dilution, J. Chem. Phys. 56 (1972) 80.
21. A.D. MacGillivray, Analytic description of the condensation phenomenon near the limit of infinite dilution based on the Poisson-Boltzmann equation, J. Chem. Phys. 56 (1972) 83.
22. G.S. Manning, Limiting laws for equilibrium and transport properties of polyelectrolyte solutions, in: E. Sélégny (Ed.), Polyelectrolytes, Reidel, Dordrecht, Holland, 1974.
23. R. Varoqui, Equilibrium and transport properties of polyelectrolyte solutions, in: K.C. Frisch, D. Klempner, A.V. Patsis (Eds.), Polyelectrolytes, Technomic Pub., Westport, CT, 1976.
24. U.P. Strauss, Y.P. Leung, Volume changes as a criterion for site binding of counterions by polyelectrolytes, J. Am. Chem. Soc. 87 (1965) 1476.
25. A.J. Begala, U.P. Strauss, Dilatometric studies of counterion binding by polycarboxylates, J. Phys. Chem. 76 (1972) 254.
26. R. Zana, C. Tondre, M. Rinaudo, M. Milas, Etude ultrasonore de la fixation sur site des ions alcalins sur des carboxymethylcelluloses de densite de charge variable, J. Chim. Phys. Phys. Chim. Biol. 68 (1971) 1258.
27. S.R. Koene, T. Nicolai, M. Mandel, Scaling relations for aqueous polyelectrolyte-salt solutions: 3. Osmotic pressure as a function of molar mass and ionic strength in the semi-dilute regime, Macromolecules 16 (1983) 231.
28. L. Wang, V.A. Bloomfield, Osmotic pressure of polyelectrolytes without added salt, Macromolecules 23 (1990) 804.
29. L. Wang, V.A. Bloomfield, Osmotic pressure of semi-dilute solutions of flexible, globular, and stiff chain polyelectrolytes with added salt, Macromolecules 23 (1990) 194.
30. I. Noda, N. Kato, T. Kitano, M. Nagasawa, Thermodynamic properties, Macromolecules 14 (1981) 668.
31. P.G. de Gennes, Scaling Concepts in Polymer Physics, Cornell University Press, Ithaca, NY, 1980.
32. P.G. de Gennes, P. Pincus, R.M. Velasco, F.J. Brochard, J. Phys. 37 (1976) 1461.
33. T. Odijk, Possible scaling relations for semi-dilute polyelectrolytes solutions, Macromolecules 12 (1979) 688.
34. T. Odijk, Polyelectrolytes near the rod limit, J. Polym. Sci., Polym. Phys. Ed. 15 (1977) 477.
35. J.M. Steven, K. Kremer, Structure of salt-free linear polyelectrolytes, Phy. Rev. Lett. 71 (1993) 14.
36. A. Katchalsky, J. Polym. Sci. 12 (1959) 688.
37. J. Cruz, H. Renon, A new thermodynamic representation of binary electrolyte solutions non-ideality in the whole range of concentrations, AIChE J. 24 (1978) 817.
38. F.X. Ball, W. Furst, H. Renon, An NRTL model for representation and prediction of deviation from ideality in electrolyte solutions compared to the models of Chen (1982) and Pitzer (1973), AIChE J. 31 (1985) 392.
39. H. Renon, J.M. Prausnitz, Local compositions in thermodynamic excess functions for liquid mixtures, AIChE J. 14 (1968) 135.
40. C.-C. Chen, L.B. Evans, A local composition model for the excess Gibbs energy of aqueous electrolyte systems, AIChE J. 32 (1986) 444.
41. M. Nagvekar, An Excess Gibbs Free Energy Model for Polyelectrolyte Solutions, Ph.D. Dissertation, Penn State University, 1990.
42. C. Christensen, B. Sander, A. Fredenslund, P. Rasmussen, Towards the extension of UNIFAC to mixtures with electrolytes, Fluid Phase Equilib. 13 (1983) 297.
43. Y. Liu, A.H. Harvey, J.M. Prausnitz, Thermodynamics of concentrated electrolyte solutions, Chem. Eng. Commun. 77 (1989) 43.
44. M. Reddy, J.A. Marinsky, A further investigation of the osmotic properties of hydrogen and sodium polystyrenesulfonates, J. Phys. Chem. 74 (1970) 3884.
45. M. Reddy, J.A. Marinsky, A. Sarkar, Osmotic properties of divalent metal polystyrenesulfonates in aqueous solution, J. Phys. Chem. 74 (1970) 3891.
46. D. Kozak, J. Kristan, D. Dolar, Osmotic coefficient of polyelectrolyte solutions: I. Polystyrenesulphonates with monovalent counterions, 1971, Z. Phys. Chem. (Frankfurt am Main) 76 (1971) 85.
47. A. Katchalsky, Z. Alexandrowicz, O. Kedem, in: B.E. Conway, R.G. Barradas (Eds.), Chemical Physics of Ionic Solutions, Wiley, New York, NY, 1966.
48. D.O. Jordan, T. Kuruscev, M.L. Martin, Comparative physical chemical study of isotactic and atactic poly (styrene sulfonic acid) solutions: Part 1. Electrochemical measurements using cells with and without liquid junctions, Trans. Faraday Soc. 65 (1969) 598.