Determination of geosmin and 2-methylisoborneol in water using isotope dilution high resolution mass spectrometry

Water Research

Volumn 32, Issue 2, 1998, Pages 287-294

  Palmentier, J P F P ^a   Taguchi, Vince Y ^a   Jenkins, Steve W D ^a   Wang, David T ^a   Ngo, Kim Phuong ^a   Robinson, Don ^a  

^a ONTARIO MINISTRY OF THE ENVIRONMENT   (Canada)

Author keywords

2 methylisoborneol; Ambersorb; Geosmin; High resolution mass spectrometry; Isotope dilution

Indexed keywords

ADSORBENTS; DESORPTION; GAS CHROMATOGRAPHY; MASS SPECTROMETRY; POTABLE WATER; SURFACE WATERS; WATER FILTRATION;

GEOSMIN; HIGH RESOLUTION MASS SPECTROMETRY; ISOTOPE DILUTION MASS SPECTROMETRY; LOW RESOLUTION MASS SPECTROMETRY; METHYLISOBORNEOL;

WATER SUPPLY;

2 METHYLISOBORNEOL; DICHLOROMETHANE; GEOSMIN;

ARTICLE; CANADA; DESORPTION; FILTRATION; GAS CHROMATOGRAPHY; INTERMETHOD COMPARISON; ISOTOPE DILUTION ASSAY; LAKE; MASS SPECTROMETRY; PRIORITY JOURNAL; WATER ANALYSIS; WATER POLLUTION;

EID: 0032007582     PISSN: 00431354     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0043-1354(97)00280-7     Document Type: Article

References (28)

1. Blok V. C., Slater G. P. and Gilbin E. M. (1983) Comparison of sorption and extraction methods for recovery of trace organics from water. Wat. Sci. Tech. 15, 149-159.
2. Dupuy H. P., Flick G. J. Jr, St. Angelo A. J. and Sumrell G. (1986) Analysis for trace amounts of geosmin in water and fish. J. Am. Oil Chem. Soc. 63, 905-908.
3. Ellis J. and Korth W. (1992) Removal of geosmin and methylisoborneol from drinking water by adsorption on ultrastable Zeolite-Y. Wat. Res. 27, 535-539.
4. Gerber N. N. (1979) Volatile substances from actinomycetes: Their role in the odor pollution of water. CRC Crit. Rev. Microbiol. 7, 191-214.
5. Gerber N. N. (1983) Volatile substances from actinomycetes: Their role in the odor pollution of water. Wat. Sci. Tech. 15, 115-125.
6. Hrudey S. E., Rector D. and Motkosky N. (1992) Characterization of drinking water odour arising from spring thaw for an ice-covered upland river source. Wat. Sci. Tech. 25, 65-72.
7. Huang C., Van Benschoten J. E. and Jensen J. N. (1996) Adsorption kinetics of MIB and geosmin. J. Am. Wat. Works Assoc. 88, 116-128.
8. Hwang C. J., Krasner S. W., McGuire M. J., Moylan M. S. and Dale M. S. (1984) Determination of subnanogram per litre levels of earthy-musty odorants in water by the salted Closed-Loop Stripping method. Environ. Sci. Tech. 18, 535-539.
9. Ito T., Okumura T. and Yamamoto M. (1988) The relationship between concentration and sensory properties of 2-methylisoborneol and geosmin in drinking water. Wat. Sci. Tech. 20, 11-17.
10. Izaguirre G., Hwang C. J., Krasner S. W. and McGuire M. J. (1982) Geosmin and 2-methylisoborneol from cyanobacteria in three water supply systems. Appl. Environ. Microbiol. 43, 708-714.
11. Jenkins S. W. D., Koester C. J., Taguchi V. Y., Wang D. T., Palmentier J.-P. F. P. and Hong K. P. (1995) N-Nitrosodimethylamine in drinking water using a rapid, solid-phase extraction method. Environ. Sci. and Pollut. Res. 2, 207-210.
12. Korth W., Ellis J. and Bowmer K. (1991a) Synthesis of deuterium labelled geosmin and methylisoborneol. J. Lab. Cpds. Radiopharm. 29, 823-828.
13. Korth W., Bowmer K. and Ellis J. (1991b) New standards for the determination of geosmin and methylisoborneol in water by gas chromatography/mass spectrometry. Wat. Res. 25, 319-324.
14. Korth W., Ellis J. and Bowmer K. (1992) The stability of geosmin and MIB and their deuterated analogues in surface waters and organic solvents. Wat. Sci. Tech. 25, 115-122.
15. Krasner S. W., Hwang C. J. and McGuire M. J. (1983) A standard method for quantitation of earthy-musty odorants in water, sediments and algal cultures. Wat. Sci. Tech. 15, 127-138.
16. Lalezary S., Pirbazari M. and McGuire M. J. (1986) Evaluating activated carbons for removing low concentrations of taste-and odor-producing organics. J. Am. Wat. Works Assoc. 79, 76-82.
17. Lalezary-Craig S., Pirbazari M., Dale M. S., Tanaka T. S. McGuire M. J. (1988) Optimizing the removal of geosmin and 2-methylisoborneol by powdered activated carbon. J. Am. Wat. Works Assoc. 80, 73-80.
18. Martin J. F., McCoy C. P., Greenleaf W. and Bennett L. (1987) Analysis of 2-methylisoborneol in water, mud and channel catfish (Ictalurus punctatus) from commercial culture ponds in Mississippi. Can. J. Fish. Aquat. Sci. 44, 909-912.
19. Means E. G. III and McGuire M. J. (1986) An early warning system for taste and odor control. J. Am. Wat. Works Assoc. 78, 77-83.
20. Medsker L. L., Jenkins D. and Thomas J. F. (1968) Odorous compounds in natural waters: An earthy-smelling compound associated with blue-green algae and actinomycetes. Environ. Sci. Tech. 2, 461-464.
21. Medsker L. L., Jenkins D. and Thomas J. F. (1969) Odorous compounds in natural waters: 2-exo-hydroxy-2-methylbornane, the major odorous compound produced by several actinomycetes. Environ. Sci. Tech. 3, 476-477.
22. Ministry of the Environment (MOE) (1988) Estimation of Analytical Method Detection Limits (MDL), ISBN 0-7729-4117-3.
23. Ministry of Environment and Energy (MOEE) (1993) The determination of 2-methylisoborneol (2-MIB) and geosmin in drinking water and in aqueous samples by Closed-Loop Stripping (CLS) technique and gas chromatography-mass spectrometry (GC-MS) LSB Method MSABN-E3310A, Etobicoke, Ontario.
24. Persson P.-E. (1980) Sensory properties and analysis of two muddy odour compounds, geosmin and 2-methylisoborneol, in water and fish. Wat. Res. 14, 1113-1118.
25. Safferman R. S., Rosen A. A., Mashni C. I. and Morris M. E. (1967) Earthy-smelling substance from a blue-green alga. Environ. Sci. Tech. 1, 429-430.
26. Slater G. P. and Blok V. C. (1983a) Volatile compounds of the cyanophyceae - A review. Wat. Sci. Tech. 15, 181-190.
27. Slater G. P. and Blok V. C. (1983b) Isolation and identification of odourous compounds from a lake subject to cyanobacterial blooms. Wat. Sci. Tech. 15, 229-240.
28. Taguchi V. Y., Jenkins S. W. D., Wang D. T., Palmentier J.-P. F. P. and Reiner E. J. (1994) Determination of N-Nitrosodimethylamine by isotope dilution, high resolution mass spectrometry. Can. J. Appl. Spec. 39, 87-93.