Role of chromium and vanadium in the atmospheric oxidation of sulfur(IV)

Atmospheric Environment

Volumn 32, Issue 4, 1998, Pages 797-800

  Brandt, Christian ^a   Elding, Lars I ^a  

^a LUND UNIVERSITY   (Sweden)

Author keywords

Catalysis; Kinetics; Mechanism; Transition metals; Tropospheric aqueous phase

Indexed keywords

ATMOSPHERIC OXIDATION; SPECTROPHOTOMETRIC KINETICS; TROPOSPHERIC AQUEOUS PHASE;

CATALYSIS; CHROMIUM; OXIDATION; PH EFFECTS; REACTION KINETICS; REDOX REACTIONS; SOLUTIONS; SPECTROPHOTOMETRY; SULFUR; VANADIUM;

ATMOSPHERIC CHEMISTRY;

CHROMIUM; SULFUR; SULFUROUS ACID; VANADIUM;

ATMOSPHERIC CHEMISTRY; CHROMIUM; OXIDATION; SULPHUR; VANADIUM;

AIR POLLUTION; AQUEOUS SOLUTION; ARTICLE; ATMOSPHERE; KINETICS; OXIDATION; OXIDATION REDUCTION REACTION; PH; PRIORITY JOURNAL; SPECTROPHOTOMETRY;

EID: 0032005323     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1352-2310(97)00331-2     Document Type: Article

References (35)

1. Abel, E. (1951) Zur Theorie der Oxydation von Sulfit zu Sulfat durch Sauerstoff Monatsh Chem. 82, 815-834.
2. Berglund, J., Voigt, R., Fronaeus, S. and Elding, L. I. (1994) Kinetics and mechanism for oxidation of dissolved sulfur dioxide by tetracyanodichloro-platinate(IV) in acidic aqueous solution and for formation and O-S linkage isomerization of sulfitotetracyanochloroplatinate(IV). Inorganic Chemistry 33, 3346-3353.
3. Berglund, J. and Elding, L. I. (1995) Manganese-catalysed autoxidation of dissolved sulfur dioxide in the atmospheric aqueous phase. Atmospheric Environment 29, 1379-1391.
4. Boyce, S. D., Hoffmann, M. R., Andrew Hong, P. and Moberly, L. M. (1983) Catalysis of the autoxidation of aqualed sulfur dioxide by homogeneous metalphthalocyanine complexes. Environmental Science Technology 17, 602-611.
5. Brandt, Ch. (1994) Kinetic and mechanistic studies of the iron(III)-catalyzed autoxidation of sulfur(IV) oxides. Ph. D. thesis, University of Witten-Herdecke (Germany).
6. Brandt, Ch. and van Eldik, R. (1995) Transition metalcatalyzed oxidation of sulfur(IV)-oxides. Atmosphericrelevant processes and mechanisms. Chemical Reviews 95, 119-190.
7. Brandt, Ch. and van Eldik, R. (1997) Influence of pH on the iron(III)-catalyzed autoxidation of sulfur(IV) oxides (submitted).
8. Bronikowski, T. (1979) Sulphur dioxide oxidation in aqueous solution containing metal cations. Reaction Kinetics and Catalysis Letters 10, 139-142.
9. Buxton, G. V., McGowan, S., Salmon, G. A., Williams, J. E. and Wood, N. D. (1996) A study of the spectra and reactivity of oxysulphur-radical anions involved in the chain oxidation of S(IV): a pulse-radiolysis study. Atmospheric Environment 30, 2483-2493.
10. Carlyle, D. W. and King, E. L. (1970) The influence of sulfite ion upon the rate of aquation of various complexes of chromium(III) ion. The stability of sulfitochromium(IIl) ion. Inorganic Chemistry 9, 2333-2339.
11. van Eldik, R. and Harris, G. M. (1980) Kinetics and mechanism of the formation, acid-catalyzed decomposition, and intramolecular redox reaction of oxygen-bonded (sulfito)pentaammine cobalt(III) ions in aqueous solution. Inorganic Chemistry 19, 880-886.
12. Galloway, J. N., Eisenreich, S. J. and Scott, B. C. (1980) Toxic substances in atmospheric deposition: a review and assessment. National Atmospheric Deposition Program Report NC-141, University of Virginia, Charlottesville, cited after:
13. Galloway, J. N., Thornton, J. D., Norton, S. A., Volchok, H. L. and McLean, R. A. N. (1982) Trace metals in atmospheric deposition: a review and assessment. Atmospheric Environment 16, 1677-1700.
14. Golodov, V. A. and Kashnikova, L. V. (1988) Oxidation of sulphur dioxide in aqueous solutions. Russian Chemical Reviews 57, 1029-1040.
15. Graedel, T. E., Weschler, C. J. and Mandich, M. L. (1985) Influence of transition metal complexes on atmospheric droplet acidity. Nature 317 (6034), 240-242.
16. Gupta, K. S., Madnawat, P. V. S., Rani, A., Sharma, M., Prasad, D. S. N., Jain, U., Bhargava, P. and Saxena, D. (1991) Kinetics of heterogeneous autoxidation of sulphur dioxide in aerosols, droplets and aqueous suspensions. Environmental considerations. In Topics in Chemistry, Series 1: Chemical Kinetics and Reaction Mechanisms, ed. K. S. Gupta, pp. 117-163. RBSA Publishers, Jaipur, India.
17. Haight, G. P. Jr., Perchonock, E., Emmenegger, F. and Gordon, G. (1965) The mechanism of the oxidation of sulfur(IV) by chromium(VI) in acid solution. Journal of American Chemical Society 87, 3835-3840.
18. Hoffmann, M. R. and Calvert, J. G. (1985) Chemical Transformation Modules for Eulerian Acid Deposition Models. The Aqueous Phase Chemistry, Vol. II. Publication No. EPA-600/3-85/017. U.S. Environmental Protection Agency, Research Triangle Park, North Carolina.
19. Horvath, Z., Lasztity, A., Varga, I., Meszaros, E. and Molnar, A. (1994) Determination of trace metals and speciation of chromium ions in atmospheric precipitation by ICP-AES and GFAAS. Talanta 41, 1165-1168.
20. Lantzy, R. J. and Mackenzie, F. T. (1979) Atmospheric trace metals: Global cycle and assessment of man's impact. Geochimica et Cosmochimica Acta 43, 511-525.
21. Lioy, P. J. and Morandi, M. T. (1980) The seasonal levels and origin of sulfur dioxide and sulfate(2-) ion in New York City (N. Y., USA). Proceedings of Annual Meeting on Air Pollution Control Association. 73rd, Montreal, Quebec (Canada), 22-27 June paper 80-51.3.
22. Matthijsen, J., Builtjes, P. J. H. and Sedlak, D. L. (1995) Cloud model experiments on the effect of iron and copper on tropospheric ozone under marine and continental conditions. Meteorological Atmospheric Physics 57, 43-60.
23. Moritzen, P. A., El-Awaday, A. A. and Harris, G. M. (1985) Kinetics and mechanisms of the formation, acid-catalyzed decomposition, and intramolecular isomerization of oxygen-bonded (sulfito)pentaaquochromium(III) perchlorate. Inorganic Chemistry 24, 313-318.
24. Novic, M., Grgic, I., Poje, M. and Hudnik, V. (1996) Ironcatalyzed oxidation of S(IV) species by oxygen in aqueous solution; Influence of pH on the redox cycling of iron. Atmospheric Environment 30, 4191-4196.
25. Nriagu, J. O. (1989) A global assessment of natural sources of atmospheric trace metals. Nature 338 (6210), 47-49.
26. Owens, M. A. and Herwehe, J. A. (1989) Sensitivity of tropospheric oxidants to global chemical and climate change. Atmospheric Environment 23, 519-532.
27. Penkett, S. A., Jones, B. M. R., Brice, K. A. and Eggleton, A. E. J. (1979) The importance of atmospheric ozone and hydrogen peroxide in oxidizing sulfur dioxide in cloud-and rain water. Atmospheric Environment 13, 123-137.
28. Pettersson, L., Hedman, B., Andersson, I. and Ingri, N. (1983) Multicomponent polyanions. Chemica Scripta 22, 254 -264.
29. Pettersson, L. (1994) Equilibria of polyoxometalates in aqueous solution. In: Polyoxometalates, eds. M. T. Pope and A. Müller pp. 27-40. Kluwer Academic Publishers. The Hague, Netherlands.
30. Seigneur, Ch. and Constantinou, E. (1995) Chemical kinetic mechanism for atmospheric chromium. Environment Science and Technology 29, 222-231.
31. Soldi, T., Riolo, C., Alberti, G., Gallorini, M. and Peloso, G. F. (1996) Environmental vanadium distribution from an industrial settlement. Science and Total Environment 181, 45-50.
32. Walcek, C. J., Yuan, H-.H. and Stockwell, W. R. (1997) The influence of aqueous phase chemical reactions on ozone formation in polluted and nonpolluted clouds. Atmospheric Environment 31, 1221-1237.
33. Wawrzenczyk, M. and Cyfert, M. (1994) Kinetics of sulphite oxidation by Cr(VI) in acid media. Polish Journal of Chemistry 68, 1615-1620.
34. Westley, F. (1982) Oxidation of sulfite ion by oxygen in aqueous solution-a bibliography. National Bureau of Standards (NBS) Special Publication (U.S.) 630, Washington, D. C. 1982.
35. 2 initiated by ionising radiation. Progress in Reaction Kinetics 21, 133-168.