Integral sorption in glassy polymers

Chemical Engineering Science

Volumn 53, Issue 4, 1998, Pages 629-638

  Vrentas, J S ^a   Vrentas, C M ^a  

^a The Pennsylvania State University   (United States)

Author keywords

Case II diffusion; Fickian diffusion; Glassy polymers

Indexed keywords

CHEMISORPTION; DESORPTION; DIFFUSION IN SOLIDS;

FICKIAN DIFFUSION;

POLYMERIC GLASS;

EID: 0032005222     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-2509(97)00368-0     Document Type: Article

References (18)

1. Baird, B. R., Hopfenberg, H. B. and Stannett, V. (1971) The effect of molecular weight and orientation on the sorption of n-pentane by glassy polystyrene. Polym. Engng Sci. 11, 274-283.
2. Frisch, H. L. (1980) Sorption and transport in glassy polymers - a review. Polym. Engng Sci. 20, 2-13.
3. Holley, R. H., Hopfenberg, H. B. and Stannett, V. (1970) Anomalous transport of hydrocarbons in polystyrene. Polym. Engng Sci. 10, 376-382.
4. Hopfenberg, H. B., Holley, R. H. and Stannett, V. (1969) The effect of penetrant activity and temperature on the anomalous diffusion of hydrocarbons and solvent crazing in polystyrene Part I: Biaxially oriented polystyrene. Polym. Engng Sci. 9, 242-249.
5. Hui, C.-Y., Wu, K.-C., Lasky, R. C. and Kramer, E. J. (1987a) Case-II diffusion in polymers. I. Transient swelling. J. Appl. Phys. 61, 5129-5136.
6. Hui, C.-Y., Wu, K.-C., Lasky, R. C. and Kramer, E. J. (1987b) Case-II diffusion in polymers. II. Steady-state front motion. J. Appl. Phys. 61, 5137-5149.
7. Jacques, C. H. M., Hopfenberg, H. B. and Stannett, V. (1973) Vapor sorption and liquid interactions with glassy polyblends of polystyrene and poly(2,6-dimethyl-1,4-phenylene oxide). Polym. Engng Sci. 13, 81-87.
8. Jacques, C. H. M., Hopfenberg, H. B. and Stannett, V. (1974) Super case II transport of organic vapour in glassy polymers. In Permeability of Plastic Films and Coatings. pp. 73-86. Plenum Press, New York.
9. Jacques, C. H. M. and Hopfenberg, H. B. (1974) Vapor and liquid equilibria in glassy polyblends of polystyrene and poly(2,6-dimethyl-1,4-phenylene oxide). Part I. Polym. Engng Sci. 14, 441-448.
10. Long, F. A. and Richman, D. (1960) Concentration gradients for diffusion of vapors in glassy polymers and their relation to time dependent diffusion phenomena. J. Am. Chem. Soc. 82, 513-519.
11. Thomas, N. and Windle, A. H. (1978) Case II swelling of PMMA sheet in methanol. J. Membrane Sci. 3, 337-342.
12. Thomas, N. L. and Windle, A. H. (1980) A deformation model for case II diffusion. Polymer 21, 613-619.
13. Thomas, N. L. and Windle, A. H. (1982) A theory of case II diffusion. Polymer 23, 529-542.
14. Vrentas, J. S., Jarzebski, C. M. and Duda, J. L. (1975) A Deborah number for diffusion in polymer-solvent systems. A.I.Ch.E. J. 21, 894-901.
15. Vrentas, J. S. and Duda, J. L. (1977) Diffusion in polymer-solvent systems. III. Construction of Deborah number diagrams. J. Polym. Sci. Polym. Phys. Ed. 15, 441-453.
16. Vrentas, J. S. and Vrentas, C. M. (1991) Sorption in glassy polymers. Macromolecules 24, 2404-2412.
17. Vrentas, J. S. and Vrentas, C. M. (1994) Solvent self-diffusion in glassy polymer-solvent systems. Macromolecules 27, 5570-5576.
18. Vrentas, J. S. and Vrentas, C. M. (1996) Hysteresis effects for sorption in glassy polymers. Macromolecules 29, 4391-4396.