Oxidative cleavage of propene on Ir(111): Double-bond scission during the formation of acetate

Surface Science

Volumn 398, Issue 1-2, 1998, Pages 11-27

  Karseboom, S G ^a   Davis, I E ^a   Mullins, C B ^a  

^a The University of Texas at Austin   (United States)

Author keywords

Alkenes; Catalysis; Chemisorption; Electron energy loss spectroscopy; Iridium; Low index single crystal surfaces; Oxidation; Thermal desorption spectroscopy

Indexed keywords

ACETIC ACID; CATALYSIS; CHEMISORPTION; CRYSTAL ORIENTATION; ELECTRON ENERGY LOSS SPECTROSCOPY; GAS ADSORPTION; OXIDATION; OXYGEN; PROPYLENE; SINGLE CRYSTALS; SURFACE STRUCTURE; TEMPERATURE PROGRAMMED DESORPTION;

LOW INDEX SINGLE CRYSTALS;

IRIDIUM;

EID: 0032003065     PISSN: 00396028     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0039-6028(98)80007-1     Document Type: Article

References (32)

1. S.O. Karseboom, J.E. Davis, C.B. Mullins, Surf. Sci. 383 (1997) 173.
2. N.W. Cant, W.K. Hall, J. Catal. 16 (1970) 220.
3. N.W. Cant, W.K. Hall, J. Catal. 27 (1972) 70.
4. T. Dozono, D.W. Thomas, H. Wise, J. Chem. Soc., Faraday Trans. I 69 (1973) 620.
5. J.T. Roberts, R.J. Madix, W.W. Crew, J. Catal. 141 (1993) 300.
6. N.W. Cant, W.K. Hall, J. Catal. 52 (1978) 81.
7. R.P. Nielsen, J.H. La Rochelle, US Patent 4 356 312, 1982.
8. J.E. Davis, S.G. Karseboom, P.D. Nolan, C.B. Mullins, J. Chem. Phys. 105 (1996) 8362.
9. F.W. McLafferty, D.B. Stauffer (Eds.), The Wiley/NBS Registry of Mass Spectra Data, vol. 1, Wiley, New York, 1988.
10. J.E. Davis, P.D. Nolan, S.G. Karseboom, C.B. Mullins, J. Chem. Phys. 107 (1997) 943.
11. Ts.S. Marinova, K.L. Kostov, Surf. Sci. 185 (1987) 203.
12. J.C.L. Cornish, N.R. Avery, Surf. Sci. 235 (1990) 209.
13. N.R. Avery, Chem Phys. Lett. 96 (1983) 371.
14. C. Puglia, A. Nilsson, B. Hernnas, O. Karis, P. Bennich, N. Martensson, Surf. Sci. 342 (1995) 119.
15. Ts.S. Marinova, D.V. Chakarov, Surf. Sci. 217 (1989) 65.
16. R.C. Lord, P. Venkateswarlu, J. Opt. Soc. Am. 43 (1953) 1079.
17. B. Silvi, P. Labarbe, J.P. Perchard, Spectrochim. Acta. 29 (1973) 263.
18. C.R. Ayre, R.J. Madix, Surf. Sci. 303 (1994) 279.
19. 2O were modeled after analogous non-deuterated compounds.
20. Extrel Corporation Quadrupole Mass Spectrometer Mass Filter Assembly Manual.
21. X. Xu, C.M. Friend, J. Am. Chem. Soc. 113 (1991) 6779.
22. Correlating bond strength with vibrational frequency for adsorbed species is not strictly rigorous due to (i) the anharmonicity of vibrational potential energy wells, and (ii) the potential coupling of vibrational modes within the molecule. However, a number of studies (such as those summarized in H. Ibach, D.L. Mills, Electron Energy Loss Spectroscopy and Surface Vibrations, Academic Press, New York, 1982) suggest that such correlations are qualitatively valid in many cases.
23. -1 features.
24. B.H. Sakakini, I.A. Ransley, C.F. Oduoza, J.C. Vickerman, M.A. Chesters, Surf. Sci. 271 (1992) 227.
25. N.R. Avery, N. Sheppard, Proc. R. Soc. London Ser. A 405(1986) 1.
26. A.J. Capote, R.J. Madix, Surf. Sci. 214 (1989) 276.
27. 2/isobutylene prepared surfaces were virtually identical at and above 230 K, although at lower temperatures π-bound isobutylene was observed on the former surface while a mixture of di-σ-bound isobutylene and π-bound isobutylene was observed on the latter.
28. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th ed., Wiley, New York, 1986.
29. 2 would not preclude the conversion of some fraction of 3 directly into acetone, but would preclude all of 3 from being directly converted into acetone.
30. P. Uvdal, B.C. Wiegand, J.G. Serafin, C.M. Friend, J. Chem. Phys. 97 (1992) 8727.
31. F. Solymosi, G. Klivenyi, J. Phys. Chem. 99 (1995) 8950.
32. C.W.J. Bol, C.M. Friend, J. Am. Chem. Soc. 117 (1995) 11572.