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Volumn 102, Issue 8, 1998, Pages 1279-1287

Supramolecularity and photodimerization of isophorone: FTIR and molecular mechanics studies

Author keywords

[No Author keywords available]

Indexed keywords

AGGLOMERATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HYDRATION; MOLECULAR STRUCTURE; PHOTOCHEMICAL REACTIONS;

EID: 0032000488     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9729270     Document Type: Article
Times cited : (10)

References (89)
  • 1
    • 84948747502 scopus 로고
    • The photochemistry of enones
    • Patai, S., Rappoport, J. Wiley: New York, and references therein
    • Schuster, D. I. The photochemistry of enones. In Patai, S., Rappoport, Z. The Chemistry of Enones; J. Wiley: New York, 1989; p 623 and references therein.
    • (1989) Z. The Chemistry of Enones , pp. 623
    • Schuster, D.I.1
  • 3
    • 85034298755 scopus 로고
    • Ph.D. Thesis. University of Utah
    • (b) Jennings, P. W.; Ph.D. Thesis. University of Utah, 1965.
    • (1965)
    • Jennings, P.W.1
  • 5
    • 0013296495 scopus 로고
    • In this work, four dimers were obtained; attribution by GC/MS but no isolation
    • (a) Fox, M. A.; Cardona, R.; Ranade, A. C. J. Org. Chem. 1985, 50, 5016. In this work, four dimers were obtained; attribution by GC/MS but no isolation.
    • (1985) J. Org. Chem. , vol.50 , pp. 5016
    • Fox, M.A.1    Cardona, R.2    Ranade, A.C.3
  • 6
    • 85034277337 scopus 로고
    • Ph.D. Thesis. University of Texas, Austin
    • (b) Cardona-Torres, R. Ph.D. Thesis. University of Texas, Austin 1987.
    • (1987)
    • Cardona-Torres, R.1
  • 10
    • 85034300607 scopus 로고
    • Ph.D. Thesis, University of Western Ontario, London, Canada
    • (b) Rudolph, A. Ph.D. Thesis, University of Western Ontario, London, Canada, 1992.
    • (1992)
    • Rudolph, A.1
  • 13
    • 85034282428 scopus 로고
    • Thèse d'Etat Université Paul Sabatier, Toulouse
    • (c) Sakellariou-Fargues, R. Thèse d'Etat Université Paul Sabatier, Toulouse, 1986.
    • (1986)
    • Sakellariou-Fargues, R.1
  • 14
    • 85034280792 scopus 로고
    • In (a, c) the results concerning organic solvents and micellar solutions corresponded to an irradiation at 300 nm and not 254 nm. When the solvent is cyclohexane HH/HT = 30/70 and not 10/90, as indicated by mistake. In (a) argon was reported by mistake instead of nitrogen (c)
    • Delpech, V.; Fargues-Sakellariou, R.; Rivière, M.; Lattes, A. Bull. Soc. Chim. Fr. 1989, 1, 49. In (a, c) the results concerning organic solvents and micellar solutions corresponded to an irradiation at 300 nm and not 254 nm. When the solvent is cyclohexane HH/HT = 30/70 and not 10/90, as indicated by mistake. In (a) argon was reported by mistake instead of nitrogen (c).
    • (1989) Bull. Soc. Chim. Fr. , vol.1 , pp. 49
    • Delpech, V.1    Fargues-Sakellariou, R.2    Rivière, M.3    Lattes, A.4
  • 28
    • 85034294916 scopus 로고    scopus 로고
    • note
    • 14b
  • 32
    • 85034292676 scopus 로고    scopus 로고
    • QCPE, University of Indiana, Bloomington, IN 47405. Programs MM2(87) and MM3(92)
    • (a) QCPE, University of Indiana, Bloomington, IN 47405. Programs MM2(87) and MM3(92).
  • 41
    • 22144432167 scopus 로고
    • The measurement of derivative IR: (a) Maddams, W. F.; Mead, W. L. Spectrochim. Acta 1982, 38A, 437 (Part I). (b) Hawkes, S.; Maddams, W. F.; Mead, W. L.; Southon, M. J. Spectrochim. Acta 1982, 38A, 445 (Part II). Maddams, W. F.; Southon, M. J. Spectrochim. Acta 1982, 38A, 459 (Part III). Susi, H.; Byler, D. M. Biophys. Biochem. Res. Commun. 1983, 115, 391.
    • (1982) Spectrochim. Acta , vol.38 A , Issue.1 PART , pp. 437
    • Maddams, W.F.1    Mead, W.L.2
  • 42
    • 22144458613 scopus 로고
    • The measurement of derivative IR: (a) Maddams, W. F.; Mead, W. L. Spectrochim. Acta 1982, 38A, 437 (Part I). (b) Hawkes, S.; Maddams, W. F.; Mead, W. L.; Southon, M. J. Spectrochim. Acta 1982, 38A, 445 (Part II). Maddams, W. F.; Southon, M. J. Spectrochim. Acta 1982, 38A, 459 (Part III). Susi, H.; Byler, D. M. Biophys. Biochem. Res. Commun. 1983, 115, 391.
    • (1982) Spectrochim. Acta , vol.38 A , Issue.2 PART , pp. 445
    • Hawkes, S.1    Maddams, W.F.2    Mead, W.L.3    Southon, M.J.4
  • 43
    • 0000952952 scopus 로고
    • The measurement of derivative IR: (a) Maddams, W. F.; Mead, W. L. Spectrochim. Acta 1982, 38A, 437 (Part I). (b) Hawkes, S.; Maddams, W. F.; Mead, W. L.; Southon, M. J. Spectrochim. Acta 1982, 38A, 445 (Part II). Maddams, W. F.; Southon, M. J. Spectrochim. Acta 1982, 38A, 459 (Part III). Susi, H.; Byler, D. M. Biophys. Biochem. Res. Commun. 1983, 115, 391.
    • (1982) Spectrochim. Acta , vol.38 A , Issue.3 PART , pp. 459
    • Maddams, W.F.1    Southon, M.J.2
  • 44
    • 0021115861 scopus 로고
    • The measurement of derivative IR: (a) Maddams, W. F.; Mead, W. L. Spectrochim. Acta 1982, 38A, 437 (Part I). (b) Hawkes, S.; Maddams, W. F.; Mead, W. L.; Southon, M. J. Spectrochim. Acta 1982, 38A, 445 (Part II). Maddams, W. F.; Southon, M. J. Spectrochim. Acta 1982, 38A, 459 (Part III). Susi, H.; Byler, D. M. Biophys. Biochem. Res. Commun. 1983, 115, 391.
    • (1983) Biophys. Biochem. Res. Commun. , vol.115 , pp. 391
    • Susi, H.1    Byler, D.M.2
  • 56
    • 0022017136 scopus 로고
    • (a) Lehn, J. M. Science 1985, 227, 849.
    • (1985) Science , vol.227 , pp. 849
    • Lehn, J.M.1
  • 62
    • 0002023185 scopus 로고
    • For the ideas of supramolecular systems in photochemistry see for example. (a) Turro, N. J.; Buchachenko, A. L.; Tarasov, V. F. Acc. Chem. Res. 1995, 28, 69. (b) Turro, N. J.; Wu, C. H. J. Am. Chem. Soc. 1995, 117, 11031.
    • (1995) Acc. Chem. Res. , vol.28 , pp. 69
    • Turro, N.J.1    Buchachenko, A.L.2    Tarasov, V.F.3
  • 63
    • 0001605842 scopus 로고
    • For the ideas of supramolecular systems in photochemistry see for example. (a) Turro, N. J.; Buchachenko, A. L.; Tarasov, V. F. Acc. Chem. Res. 1995, 28, 69. (b) Turro, N. J.; Wu, C. H. J. Am. Chem. Soc. 1995, 117, 11031.
    • (1995) J. Am. Chem. Soc. , vol.117 , pp. 11031
    • Turro, N.J.1    Wu, C.H.2
  • 64
    • 85034305371 scopus 로고    scopus 로고
    • note
    • 6a,c not isolated, and therefore does not appear in ref 6c.
  • 69
    • 84948780891 scopus 로고
    • Dimerization and polymerization of enones in the fluid and solid states
    • Patai, S., Rappoport, Z., Eds.; J. Wiley: New York
    • (e) Theocharis, C. R. Dimerization and polymerization of enones in the fluid and solid states. In The Chemistry of Enones; Patai, S., Rappoport, Z., Eds.; J. Wiley: New York, 1989; p 1133.
    • (1989) The Chemistry of Enones , pp. 1133
    • Theocharis, C.R.1
  • 72
    • 85034301054 scopus 로고    scopus 로고
    • note
    • 4c,d explained the preferential formation of adducts in the anti configuration on the basis that the syn configuration requires a higher degree of desolvation than the anti configuration. As the solvent is excluded from the cleft between the two cyclohexyl rings, the solvent-accessible surface area is greater, the volume occupied in solution is smaller, and the solvent reorganization is of less importance for the anti configuration.
  • 85
    • 85034291162 scopus 로고    scopus 로고
    • To be published
    • To be published.
  • 86
    • 0039837271 scopus 로고
    • the excimer is a dimer associated in an electronically excited state and dissociated in its ground state having a distance between the centers of its double bonds greater than 10 A°. Hence the distinction between excimers formed from preassociations termed "static excimers" with respect to the former termed "dynamic excimers"
    • (a) According to the definition of Birks, Birks J. B. Rep. Prog. Phys. 1975, 38, 903, the excimer is a dimer associated in an electronically excited state and dissociated in its ground state having a distance between the centers of its double bonds greater than 10 A°. Hence the distinction between excimers formed from preassociations termed "static excimers" with respect to the former termed "dynamic excimers". (b) Winnik, F. M. Chem. Rev. 1993, 93, 587.
    • (1975) Rep. Prog. Phys. , vol.38 , pp. 903
    • Birks, J.B.1
  • 87
    • 1542688597 scopus 로고
    • (a) According to the definition of Birks, Birks J. B. Rep. Prog. Phys. 1975, 38, 903, the excimer is a dimer associated in an electronically excited state and dissociated in its ground state having a distance between the centers of its double bonds greater than 10 A°. Hence the distinction between excimers formed from preassociations termed "static excimers" with respect to the former termed "dynamic excimers". (b) Winnik, F. M. Chem. Rev. 1993, 93, 587.
    • (1993) Chem. Rev. , vol.93 , pp. 587
    • Winnik, F.M.1
  • 88
    • 0000796464 scopus 로고
    • n (n = 2-5). (a) Saigusa, H.; Sun, S.; Lim, E. C. J. Phys. Chem. 1992, 96, 10099. (b) Saigusa, H.; Lim, E. C. J. Phys. Chem. 1994, 98, 13470.
    • (1992) J. Phys. Chem. , vol.96 , pp. 10099
    • Saigusa, H.1    Sun, S.2    Lim, E.C.3
  • 89
    • 0001258288 scopus 로고
    • n (n = 2-5). (a) Saigusa, H.; Sun, S.; Lim, E. C. J. Phys. Chem. 1992, 96, 10099. (b) Saigusa, H.; Lim, E. C. J. Phys. Chem. 1994, 98, 13470.
    • (1994) J. Phys. Chem. , vol.98 , pp. 13470
    • Saigusa, H.1    Lim, E.C.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.