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4c,d explained the preferential formation of adducts in the anti configuration on the basis that the syn configuration requires a higher degree of desolvation than the anti configuration. As the solvent is excluded from the cleft between the two cyclohexyl rings, the solvent-accessible surface area is greater, the volume occupied in solution is smaller, and the solvent reorganization is of less importance for the anti configuration.
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To be published.
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the excimer is a dimer associated in an electronically excited state and dissociated in its ground state having a distance between the centers of its double bonds greater than 10 A°. Hence the distinction between excimers formed from preassociations termed "static excimers" with respect to the former termed "dynamic excimers"
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