Efficient synthesis of (E)-3-trifluoromethyl-3-aryl(hetaryl)acroleins

Tetrahedron

Volumn 54, Issue 1-2, 1998, Pages 119-128

  Baraznenok, Ivan L ^a   Nenajdenko, Valentine G ^a   Balenkova, Elizabeth S ^a  

^a MOSCOW STATE UNIVERSITY   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

3 TRIFLUOROMETHYL 3 ARYLACROLEIN DERIVATIVE; ACROLEIN DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; DRUG CONFORMATION; DRUG SYNTHESIS; ISOMER; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PRIORITY JOURNAL; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0031986130     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(97)10263-0     Document Type: Article

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18. 14. Yield based on conversion of substrate
19. 15. 1:1 Substrate/reagent ratio were used
20. 16. Two equivalents of reagent were used
21. 17. Yield based on conversion of ketone 1
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23. 19. Product 9a was found decomposed in time of several hours at room temperature and quickly converted into brown tar when heating.