Enantioselective polyol synthesis via the cope rearrangement of chiral aldol products. A synthesis of the C1-C10-fragment of nystatin A1

Tetrahedron Letters

Volumn 39, Issue 1-2, 1998, Pages 9-12

  Schneider, Christoph ^a   Rehfeuter, Markus ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

NYSTATIN; POLYOL;

ANTIFUNGAL ACTIVITY; ARTICLE; CHIRALITY; DRUG SYNTHESIS; ENANTIOMER; GENE REARRANGEMENT; NONHUMAN; SIALYLATION; STEREOCHEMISTRY;

EID: 0031983548     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)10455-5     Document Type: Article

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34. 3): d=36.84, 38.19, 39.80, 40.72 (C-2, C-4, C-6, C-8), 51.75 (OMe), 70.67 (benzyl-C), 73.15, 73.74, 74.38 (C-3, C-5, C-7), 100.6 (acetal-C), 117.5 (C-10), 126.0, 127.6, 128.0, 128.1, 128.4, 128.6, 138.4, 138.6 (phenyl-C), 134.5 (C-9), 171.2 (CO).
35. 3): δ=20.99, 24.71, 33.75, 35.51, 38.38, 42.75, 62.31, 64.36, 68.51, 75.00, 170.8, 171.4. All new compounds were fully characterized by IR, UV, MS, NMR and combustion analysis.