The role of shape selectivity and intrinsic selectivity of acidic sites of the catalysts in the skeletal isomerization of n-butenes

Journal of Chemical Technology and Biotechnology

Volumn 71, Issue 1, 1998, Pages 6-14

  Llorens, Francisco J ^a   Gayubo, Ana G ^a   Cepeda, Emilio ^a   Aguayo, Andrés T ^a   Bilbao, Javier ^a  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

Author keywords

Acidity; Chlorinated alumina; Isobutene; Shape selectivity; Skeletal isomerization

Indexed keywords

ALUMINA; BROMINE; CATALYST ACTIVITY; CATALYST SELECTIVITY; CHLORINE; FLUORINE; ISOMERIZATION; PH; POROSITY; REACTION KINETICS; SILICA;

SHAPE SELECTIVITY; SKELETAL ISOMERIZATION;

BUTENES;

ALUMINUM OXIDE; ISOBUTYLENE; SILICON DIOXIDE; ZEOLITE;

ARTICLE; CATALYST; ISOMERISM;

EID: 0031963760     PISSN: 02682575     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1097-4660(199801)71:1<6::AID-JCTB807>3.0.CO;2-D     Document Type: Article

References (34)

1. Panneman, H. J. & Beenackers, A. C. M., Influence of the isobutene/methanol ratio and of the methyl tert-butyl ether content on the reaction rate of the synthesis of methyl tert-butyl ether. Ind. Eng. Chem. Res., 34 (1995) 3817-25.
2. Panneman, H. J. & Beenackers, A. C. M., Synthesis of methyl tert-butyl ether catalyzed by acidic ion-exchange resins. Influence of the proton activity. Ind. Eng. Chem. Res., 34 (1995) 4318-25.
3. Marceglia, G. & Oriani, G., Snamprogetti's associated technologies. Chemical Economy & Engineering Review, 14 (1982) 35-40.
4. Nilsen, B. P., Onuferko, J. H. & Gates, B. C., Silicated aluminas prepared from tetraethoxysilane: catalysts for skeletal isomerization of butenes. Ind. Eng. Chem. Fundam., 25 (1986) 337-43.
5. Stöcker, M., Riis, T. & Hagen, H., Double bond and skeletal isomerization of 1-butene over lanthanum-modified silicated alumina. Acta Chemica Scandinabica, B40 (1986) 200-3.
6. Choudhary, V. R., Fluorine promoted catalysis: activity and surface properties. Ind. Eng. Chem. Prod. Res. Dev., 16 (1977) 12-22.
7. Cheng, Z. X. & Ponec, V., Selective isomerization of butene to iso-butene. J. Catal., 148 (1994) 607-16.
8. Cheng, Z. X. & Ponec, V., Fluorinated alumina as a catalyst for skeletal isomerization of n-butene. Appl. Catal., 118 (1994) 127-38.
9. Sun, H. N. & Gastinger, R. G., Skeletal isomerization of olefins over bromided aluminas. US Patent 6,654,463, Mar. 31, 1987.
10. Myers, H. W., Skeletal isomerization of olefins over halogen-containing zirconia catalyst. US Patent 3,663,453, May 16, 1972.
11. Myers, H. W., Skeletal isomerization of olefins over halogen-containing zirconia catalyst. US Patent 3,730,958, May 1, 1973.
12. Szabo, J., Perrotey, J., Szabo, G., Duchet, J. C. & Cornet, D., Isomerization of n-butenes into isobutene over fluorinated aluminas: influence of experimental conditions upon selectivity. J. Molec. Catal., 67 (1991) 79-90.
13. Szabo, J., Szabo, G., van Gestel, J. & Cornet, D., Isomerization of n-butenes to isobutene catalyzed by fluorinated alumina. Reaction kinetics. Appl. Catal., 96 (1993) 319-30.
14. Tabak, S. A., Krambeck, F. J. & Garwood, W. E., Conversion of propylene and butylene over ZSM-5 catalyst. AIChE J., 32 (1986) 1526-31.
15. Hoser, H., Innocenti, A., Riva, A. & Trifiro, F., Catalytic activity of HZSM-5 zeolite in 1-butene conversion. Diffusive reflectance-IR spectroscopic study in a flow system. Appl. Catal., 30 (1987) 11-20.
16. Janssen, M. J. G., Mortier, W. J. van Oorschot, C. W. M. & Makkee, M., Process for catalytic conversion of olefins. International Patent, WO 91/18851, December 12, 1991.
17. Gadja, G. J., Butene isomerization process. US Patent 5,132,484, July 21, 1992.
18. Xu, W.-Q., Yin, Y.-G., Suib, S. L. & O'Young, C.-L., Selective conversion of n-butene to isobutylene at extremely high space velocities on ZSM-23 zeolites. J. Catal., 150 (1994) 34-45.
19. Simon, M. W., Suib, S. L. & O'Young, C.-L., Synthesis and characterization of ZSM-22 zeolites and their catalytic behavior in 1-butene isomerization reactions. J. Catal., 147 (1994) 484-93.
20. 3+ content of B-ZSM-11 and B-ZSM-5 on acidity and chemical and thermal stability. J. Phys. Chem., 96 (1992) 6381-88.
21. 8. J. Catal., 144 (1993) 285-95.
22. Bianchi, D., Simin, M. W., Nam, S. S., Xu, W.-Q., Suib, S. L. & O'Young, C.-L., Kinetic studies of the isomerization of n-butenes over boroaluminosilicate zeolites. J. Catal., 145 (1994) 551-60.
23. Gielgens, L. H., van Kampen, M. G. H., Broek, M. M., van Hardeveld, R. & Ponec, V., Skeletal isomerization of 1-butene on tungstene oxide catalysts., J. Catal., 154 (1995) 201-7.
24. Guisnet, M., Andy, P., Gnep, N. S., Benazzi, E. & Travers, C., Skeletal isomerization of n-butenes. I. Mechanism of n-butene transformation on a nondeactivated H-Ferrierite catalyst. J. Catal., 158 (1996) 551-60.
25. Asensi, M. A., Corma, A. & Martinez, A., Skeletal isomerization of 1-butene on MCM-22 zeolite catalyst. J. Catal., 158 (1996) 561-9.
26. Aguayo, A. T., Arandes, J. M., Romero, A. & Bilbao, J., Optimization of the preparation of a catalyst under deactivation. 1. Control of its kinetic behavior by selecting the preparation conditions. Ind. Eng. Chem. Res., 26 (1987) 2403-8.
27. Aguayo, A. T., Arandes, J. M., Olazar, M. & Bilbao, J., Optimization of the preparation of a catalyst under deactivation. 2. Application to the operation in reaction-regeneration cycles. Ind. Eng. Chem. Res., 28 (1989) 1299-303.
28. Argauer, R. J. & Landolt, G. R., Crystalline zeolite HZSM-5 and method of preparing the same. US Patent 3,702,886, November 14, 1972.
29. Benito, P. L., Aguayo, A. T., Gayubo, A. G. & Bilbao, J., Evolution of the acidic structure of a H-ZSM-5 zeolite with the thermal treatment steps in its preparation. Afinidad, 51 (1994) 375-8.
30. Benito, P. L., Kinetic modelling of the transformation of methanol into gasoline on HZSM5 zeolites. PhD thesis. University of the Basque Country, Bilbao, 1995.
31. Kaiser, S. W., Production of light olefins. US Patent 4,499, 327, February 12, 1985.
32. Aguayo, A. T., Benito, P. L., Gayubo, A. G., Olazar, M. & Bilbao, J., Acidity deterioration and coke deposition in a H-ZSM-5 zeolite in the MTG process. Stud. Surf. Sci. Catal., 88 (1994) 567-72.
33. Aguayo, A. T., Gayubo, A. G., Ereña, J., Olazar, M., Arandes, J. M. & Bilbao, J., Isotherms of chemical adsorption of bases on solid catalysts for acidity measurement. J. Chem. Technol. Biotechnol. 60 (1994) 141-6.
34. Sanchez del Campo, A. E., Gayubo, A. G., Gonzalez, I., Aguayo, A. T. & Bilbao, J., Surface acidity of SAPO-34 silicoaluminophosphate. Afinidad, 53 (1996) 325.