A facile synthesis of α-iodo-β-nitroalkenes from alkynes using I2/NO3- or KI/NO3-

Synthetic Communications

Volumn 28, Issue 5, 1998, Pages 833-836

  Yusubov, Mehman S ^a,b   Perederina, Irina A ^a   Filimonov, Victor D ^a   Park, Tae Ho ^c   Chi, Ki Whan ^d  

^a NATIONAL RESEARCH TOMSK POLYTECHNIC UNIVERSITY   (Russian Federation)

^b SIBERIAN STATE MEDICAL UNIVERSITY   (Russian Federation)

^c Korea Research Institute of Chemical Technology   (South Korea)

^d University of Ulsan   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; ALKYNE DERIVATIVE; NITRATE; NITROALKANE; POTASSIUM IODIDE; REAGENT;

ARTICLE; GAS CHROMATOGRAPHY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STEREOISOMERISM; SYNTHESIS;

EID: 0031950644     PISSN: 00397911     EISSN: None     Source Type: Journal    
DOI: 10.1080/00032719808006480     Document Type: Article

References (7)

1. Corey, E.J. and Estreicher, H. J.Am.Chem.Soc. 1978, 100, 6294.
2. Jager, V. and Viehe, H.G. Angew.Chem.Intern.Edit. 1969, 8, 273.
3. Stevens, T.E. and Emmons, W.D. J.Am.Chem.Soc. 1958, 80, 338.
4. 13C NMR confirmed the structures of 2a and 2c.
5. 6 The NOE experiment with 2c for the structual elucidation ended up in vain.
6. Breitmaier, E. and Voelter, W. "Carbon-13 NMR Spectroscopy. High-Resolution Method and Applications in Organic Chemistry and Biochemistry, 3rd Ed." VCH, Weinheim, 1987, pp.115-116, 192-194.
7. 13C NMR 594.8,96.5,127.2,128.0, 128.7,128.9,130.0,130.1,139.6,142.1.