Comparison of the effects of ultrasound and mechanical agitation on a reacting solid-liquid system

Chemical Engineering Science

Volumn 53, Issue 1, 1998, Pages 131-148

  Hagenson, Leigh C ^a   Doraiswamy, L K ^a  

^a Iowa State University of Science and Technology   (United States)

Author keywords

Diffusion reaction; Kinetic modeling; Non catalytic; Solid liquid; Sonochemistry

Indexed keywords

BUBBLES (IN FLUIDS); CAVITATION; DEGRADATION; DIFFUSION; FREE RADICALS; MASS TRANSFER; MIXING; SHOCK WAVES; ULTRASONIC EFFECTS;

SONOCHEMISTRY;

REACTION KINETICS;

AGITATOR; MASS TRANSFER; REACTION; ULTRASONIC TECHNIQUE;

EID: 0031908114     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-2509(97)00193-0     Document Type: Article

References (35)

1. Berlan, J., Trabelsi, F., Delmas, H., Wilhelm, A. M. and Petrignani, J. F. (1994) Oxidative degradation of phenol in aqueous media using ultrasound. Ultrasonics Sonochem. 1, S97-S102.
2. Broeckaert, L., Caulier, T., Fabre, O., Maerschalk, C., Reisse, J., Vandercammen, J., Yang, D. H., Lepoint, T. and Mullie, F. (1992) Quantitative homogeneous sonochemistry: scope and limitations. Current Trends in Sonochemistry, ed. G. J. Price, pp. 8-25. Royal Society of Chemistry, Cambridge.
3. Contamine, F., Faid, F., Wilhelm, A. M., Berlan, J. and Delmas, H. (1994) Chemical reactions under ultrasound: discrimination of chemical and physical effects. Chem. Engng Sci. 49, 5865-5873.
4. Cum, G., Gallo, R. and Spadaro, A. (1988) Effect of static pressure on the ultrasonic activation of chemical reactions. Selective oxidation at benzylic carbon in the liquid phase. J. Chem. Soc. Perkin Trans. II 375-383.
5. de Souza-Barboza, J. C., Luche, J. L. and Petrier, C. (1987) Ultrasound in organic synthesis 11. Retention of optical activity in barbier reactions from S( + ) 2-octyl halides. Mechanistic consequences. Tetrahedron Lett. 28, 2013-2016.
6. Dickens, M. J. and Luche, J. L. (1991) Further evidence for the effect of ultrasonic waves on electron transfer processes - the case of the Kornblum-Russell reaction. Tetrahedron Lett. 32, 4709-4712.
7. Doriaswamy, L. K. and Sharma, M. M. (1984) Heterogeneous Reactions: Analysis, Examples, and Reactor Design, Vol. 2: Fluid-Fluid-Solid Reactions, pp. 449-479. Wiley, New York.
8. Entezari, M. H. and Kruus, P. (1994) Effect of frequency on sonochemical reactions I: oxidation of iodide. Ultrasonics Sonochem. 1, S75-S79.
9. Fuentes, A., Marinas, J. M. and Sinisterra, J. V. (1987) Catalyzed synthesis of chalcones under interfacial solid-liquid conditions with ultrasound. Tetrahedron Lett. 28, 4541-4544.
10. Hagenson, L. C., Naik, S. D. and Doraiswamy, L. K. (1994) Rate enhancements in a solid-liquid reaction using PTC, microphase, ultrasound and combinations thereof. Chem. Engng Sci 49, 4787-4800.
11. Hanafusa, T., Ichihara, J. and Ashida, T. (1987) Useful synthesis of α-aminonitriles by means of alumina and ultrasound. Chem. Lett. 687-690.
12. Hart, E. J. and Henglein, A. (1985) Free radical and free atom reactions in the sonolysis of aqueous iodide and formate solutions. J. Phys. Chem. 89, 4342-4347.
13. Javed, T., Mason, T. J., Phull, S. S., Baker, N. R. and Robertson, A. (1995) Influence of ultrasound on the Diels-Alder cyclization reaction: synthesis of some hydroquinone derivatives and lonapalene, and anti-psoriatic agent. Ultrasonics Sonochem. 2, S3-S4.
14. Jouglet, B., Blanco, L. and Rousseau, G. (1991) New method for the reaction of nitroalkanes with unsaturated esters. Synlett. (Dec.) 907-908.
15. Landini, D. and Rolla, F. A. (1974) Convenient synthesis of primary and secondary dialkyl and aryl sulfides in the presence of phase-transfer catalysts. Synthesis, 565.
16. Levenspiel, O. (1972) Chemical Reaction Engineering, 2nd Edition, pp. 357-377. Wiley, NY.
17. Lie Ken Jie, M. S. F. and Lam, C. K. (1995) Ultrasound-assisted epoxidation reaction of long-chain unsaturated fatty esters. Ultrasonics Sonochem. 2, S11-S14.
18. Lorimer, J. P., Mason, T. J. and Fiddy, K. (1991) Enhancement of chemical reactivity by power ultrasound: an alternative interpretation of the hot spot. Ultrasonics 29, 338-343.
19. Luche, J. L. (1994) Effect of ultrasound on heterogeneous systems. Ultrasonics Sonochem. 1(2), S111-S118.
20. Margulis, M. A. (1985) Sonoluminescence and sonochemical reactions in cavitation fields. a review. Ultrasonics 23, 157-169.
21. Mason, T. J. (1990a) Chemistry With Ultrasound. Elsevier, Amsterdam.
22. Mason, T. J. (1990b) Sonochemistry. Royal Society of Chemistry, Cambridge.
23. Mazet, N. (1992) Modeling of gas solid reactions. 1. Nonporous solids. Int. J. Chem. Engng. 32(2), 271-284.
24. Noltingk, B. E. and Neppiras, E. A. (1950) Cavitation produced by ultrasonics. Proc. Phys. Soc. 63B, 674-685.
25. Phadtare, P. G. and Doraiswamy, L. K. (1965) Mass transfer model for Kolbe-Schmitt carbonation of 2-naphthol. Ind. Engng Chem. Process. Des. Dev. 4, 274.
26. Pradhan, N. C. and Sharma, M. M. (1990) Kinetics of reactions of benzyl chloride/p-chlorobenzyl chloride with sodium sulfide: phase-transfer catalysis and the role of the omega phase. Ind. Engng Chem. Res. 29, 1103-1108.
27. Prasad Naidu, D. V., Rajan, R., Kumar, R., Gandhi, K. S., Arakeri, V. H. and Chandrasekaran, S. (1994) Modeling of a batch sonochemical reactor. Chem. Engng Sci. 49, 877-888.
28. Ratoarinoro, N., Contamine, F., Wilhelm, A. M., Berlan, J. and Delmas, H. (1995) Activation of a solid-liquid chemical reaction by ultrasound. Chem. Engng Sci. 50, 554-558.
29. Ratoarinoro, N., Wilhelm, A. M., Berlan, J. and Delmas, H. (1992) Effects of ultrasound emitter type and power on a heterogeneous reaction. Chem. Engng J. 50, 27-31.
30. Sinisterra, J. V. (1992) Application of ultrasound to biotechnology: an overview. Ultrasonics 30, 180-185.
31. Soudagar, S. R. and Samant, S. D. (1995) Investigation of ultrasound catalyzed oxidation of arylalkanes using aqueous potassium permanganate. Ultrasonics Sonochem. 2, S15-S18.
32. Suslick, K. S. (1988) Ultrasound: Its Chemical, Physical and Biological Effects, VCH Publishers, New York.
33. Suslick, K. S., Doktycz, S. J. and Flint, E. B. (1990) On the origin of sonoluminescence and sonochemistry, Ultrasonics 28, 280-290.
34. Tozzi, A. and Cassandrini, P. (1975) Catalysts for organic sulfide manufacture. Ger. Offen. 2513805; (1976) Chem. Abstr. 84, 4476.
35. Tozzi, A. and Cassandrini, P. (1975) Catalysts for organic sulfide manufacture. Ger. Offen. 2513805; (1976) Chem. Abstr. 84, 4476.