Crown Ethers, Double-Decker, and Sandwich Complexes: Cation-Mediated Formation of Metallatopomer Coronates

Angewandte Chemie - International Edition

Volumn 37, Issue 1-2, 1998, Pages 172-175

  Saalfrank, Rolf W ^a   Löw, Norbert ^a   Kareth, Sabine ^a   Seitz, Verena ^a   Hampel, Frank ^a   Stalke, Dietmar ^b   Teichert, Markus ^b  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

^b NONE

Author keywords

Copper; Crown compounds; Sandwich complexes; Supramolecular chemistry

Indexed keywords

EID: 0031906586     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3773(19980202)37:1/2<172::aid-anie172>3.0.co;2-0     Document Type: Article

References (51)

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31. V. L. Pecoraro, A. J. Stemmler, B. R. Gibney, J. J. Bodwin, H. Wang, J. W. Kampf, A. Barwinski, Prog. Inorg. Chem. 1997, 45, 83-177; A. J. Stemmler, J. W. Kampf, V. L. Pecoraro, Angew. Chem. 1996, 108, 3011-3013; Angew. Chem. Int. Ed. Engl. 1996, 35, 2841-2843; A. J. Stemmler, A. Barwinski, M. J. Baldwin, V. Young, V. L. Pecoraro, J. Am. Chem. Soc. 1996, 118, 11962-11963; B. R. Gibney, D. P. Kessissoglou, J. W. Kampf, V. L. Pecoraro, Inorg. Chem. 1994, 33, 4840-4849; M. S. Lah, B. R. Gibney, D. L. Tierney, J. E. Penner-Hahn, V. L. Pecoraro, J. Am. Chem. Soc. 1993, 115, 5857-5858; I. Haiduc, R. B. King in Large Ring Molecules (Ed.: J. A. Semlyen). Wiley, New York, 1996, p. 525ff; W. Hayes, J. F. Stoddart, in Large Ring Molecules (Ed.: J. A. Semlyen), Wiley, New York, 1996, p. 433ff; A. J. Blake, R. O. Gould, C. M. Grand, P. E. Y. Milne, D. Reed, R. E. P. Winpenny, Angew. Chem. 1994, 106, 208-210; Angew. Chem. Int. Ed. Engl. 1994, 33, 195-197; A. J. Blake, R. O. Gould, P. E. Y. Milne, R. E. P. Winpenny, J. Chem. Soc. Chem. Commun. 1991, 1453-1454; G. M. Gray, C. H. Duffey, Organometallics 1995, 14, 245-250; A. Caneschi, A. Cormia, S. J. Lippard, Angew. Chem. 1995, 107, 511-513; Angew. Chem. Int. Ed. Engl. 1995, 34, 467-469.
32. V. L. Pecoraro, A. J. Stemmler, B. R. Gibney, J. J. Bodwin, H. Wang, J. W. Kampf, A. Barwinski, Prog. Inorg. Chem. 1997, 45, 83-177; A. J. Stemmler, J. W. Kampf, V. L. Pecoraro, Angew. Chem. 1996, 108, 3011-3013; Angew. Chem. Int. Ed. Engl. 1996, 35, 2841-2843; A. J. Stemmler, A. Barwinski, M. J. Baldwin, V. Young, V. L. Pecoraro, J. Am. Chem. Soc. 1996, 118, 11962-11963; B. R. Gibney, D. P. Kessissoglou, J. W. Kampf, V. L. Pecoraro, Inorg. Chem. 1994, 33, 4840-4849; M. S. Lah, B. R. Gibney, D. L. Tierney, J. E. Penner-Hahn, V. L. Pecoraro, J. Am. Chem. Soc. 1993, 115, 5857-5858; I. Haiduc, R. B. King in Large Ring Molecules (Ed.: J. A. Semlyen). Wiley, New York, 1996, p. 525ff; W. Hayes, J. F. Stoddart, in Large Ring Molecules (Ed.: J. A. Semlyen), Wiley, New York, 1996, p. 433ff; A. J. Blake, R. O. Gould, C. M. Grand, P. E. Y. Milne, D. Reed, R. E. P. Winpenny, Angew. Chem. 1994, 106, 208-210; Angew. Chem. Int. Ed. Engl. 1994, 33, 195-197; A. J. Blake, R. O. Gould, P. E. Y. Milne, R. E. P. Winpenny, J. Chem. Soc. Chem. Commun. 1991, 1453-1454; G. M. Gray, C. H. Duffey, Organometallics 1995, 14, 245-250; A. Caneschi, A. Cormia, S. J. Lippard, Angew. Chem. 1995, 107, 511-513; Angew. Chem. Int. Ed. Engl. 1995, 34, 467-469.
33. V. L. Pecoraro, A. J. Stemmler, B. R. Gibney, J. J. Bodwin, H. Wang, J. W. Kampf, A. Barwinski, Prog. Inorg. Chem. 1997, 45, 83-177; A. J. Stemmler, J. W. Kampf, V. L. Pecoraro, Angew. Chem. 1996, 108, 3011-3013; Angew. Chem. Int. Ed. Engl. 1996, 35, 2841-2843; A. J. Stemmler, A. Barwinski, M. J. Baldwin, V. Young, V. L. Pecoraro, J. Am. Chem. Soc. 1996, 118, 11962-11963; B. R. Gibney, D. P. Kessissoglou, J. W. Kampf, V. L. Pecoraro, Inorg. Chem. 1994, 33, 4840-4849; M. S. Lah, B. R. Gibney, D. L. Tierney, J. E. Penner-Hahn, V. L. Pecoraro, J. Am. Chem. Soc. 1993, 115, 5857-5858; I. Haiduc, R. B. King in Large Ring Molecules (Ed.: J. A. Semlyen). Wiley, New York, 1996, p. 525ff; W. Hayes, J. F. Stoddart, in Large Ring Molecules (Ed.: J. A. Semlyen), Wiley, New York, 1996, p. 433ff; A. J. Blake, R. O. Gould, C. M. Grand, P. E. Y. Milne, D. Reed, R. E. P. Winpenny, Angew. Chem. 1994, 106, 208-210; Angew. Chem. Int. Ed. Engl. 1994, 33, 195-197; A. J. Blake, R. O. Gould, P. E. Y. Milne, R. E. P. Winpenny, J. Chem. Soc. Chem. Commun. 1991, 1453-1454; G. M. Gray, C. H. Duffey, Organometallics 1995, 14, 245-250; A. Caneschi, A. Cormia, S. J. Lippard, Angew. Chem. 1995, 107, 511-513; Angew. Chem. Int. Ed. Engl. 1995, 34, 467-469.
34. V. L. Pecoraro, A. J. Stemmler, B. R. Gibney, J. J. Bodwin, H. Wang, J. W. Kampf, A. Barwinski, Prog. Inorg. Chem. 1997, 45, 83-177; A. J. Stemmler, J. W. Kampf, V. L. Pecoraro, Angew. Chem. 1996, 108, 3011-3013; Angew. Chem. Int. Ed. Engl. 1996, 35, 2841-2843; A. J. Stemmler, A. Barwinski, M. J. Baldwin, V. Young, V. L. Pecoraro, J. Am. Chem. Soc. 1996, 118, 11962-11963; B. R. Gibney, D. P. Kessissoglou, J. W. Kampf, V. L. Pecoraro, Inorg. Chem. 1994, 33, 4840-4849; M. S. Lah, B. R. Gibney, D. L. Tierney, J. E. Penner-Hahn, V. L. Pecoraro, J. Am. Chem. Soc. 1993, 115, 5857-5858; I. Haiduc, R. B. King in Large Ring Molecules (Ed.: J. A. Semlyen). Wiley, New York, 1996, p. 525ff; W. Hayes, J. F. Stoddart, in Large Ring Molecules (Ed.: J. A. Semlyen), Wiley, New York, 1996, p. 433ff; A. J. Blake, R. O. Gould, C. M. Grand, P. E. Y. Milne, D. Reed, R. E. P. Winpenny, Angew. Chem. 1994, 106, 208-210; Angew. Chem. Int. Ed. Engl. 1994, 33, 195-197; A. J. Blake, R. O. Gould, P. E. Y. Milne, R. E. P. Winpenny, J. Chem. Soc. Chem. Commun. 1991, 1453-1454; G. M. Gray, C. H. Duffey, Organometallics 1995, 14, 245-250; A. Caneschi, A. Cormia, S. J. Lippard, Angew. Chem. 1995, 107, 511-513; Angew. Chem. Int. Ed. Engl. 1995, 34, 467-469.
35. V. L. Pecoraro, A. J. Stemmler, B. R. Gibney, J. J. Bodwin, H. Wang, J. W. Kampf, A. Barwinski, Prog. Inorg. Chem. 1997, 45, 83-177; A. J. Stemmler, J. W. Kampf, V. L. Pecoraro, Angew. Chem. 1996, 108, 3011-3013; Angew. Chem. Int. Ed. Engl. 1996, 35, 2841-2843; A. J. Stemmler, A. Barwinski, M. J. Baldwin, V. Young, V. L. Pecoraro, J. Am. Chem. Soc. 1996, 118, 11962-11963; B. R. Gibney, D. P. Kessissoglou, J. W. Kampf, V. L. Pecoraro, Inorg. Chem. 1994, 33, 4840-4849; M. S. Lah, B. R. Gibney, D. L. Tierney, J. E. Penner-Hahn, V. L. Pecoraro, J. Am. Chem. Soc. 1993, 115, 5857-5858; I. Haiduc, R. B. King in Large Ring Molecules (Ed.: J. A. Semlyen). Wiley, New York, 1996, p. 525ff; W. Hayes, J. F. Stoddart, in Large Ring Molecules (Ed.: J. A. Semlyen), Wiley, New York, 1996, p. 433ff; A. J. Blake, R. O. Gould, C. M. Grand, P. E. Y. Milne, D. Reed, R. E. P. Winpenny, Angew. Chem. 1994, 106, 208-210; Angew. Chem. Int. Ed. Engl. 1994, 33, 195-197; A. J. Blake, R. O. Gould, P. E. Y. Milne, R. E. P. Winpenny, J. Chem. Soc. Chem. Commun. 1991, 1453-1454; G. M. Gray, C. H. Duffey, Organometallics 1995, 14, 245-250; A. Caneschi, A. Cormia, S. J. Lippard, Angew. Chem. 1995, 107, 511-513; Angew. Chem. Int. Ed. Engl. 1995, 34, 467-469.
36. V. L. Pecoraro, A. J. Stemmler, B. R. Gibney, J. J. Bodwin, H. Wang, J. W. Kampf, A. Barwinski, Prog. Inorg. Chem. 1997, 45, 83-177; A. J. Stemmler, J. W. Kampf, V. L. Pecoraro, Angew. Chem. 1996, 108, 3011-3013; Angew. Chem. Int. Ed. Engl. 1996, 35, 2841-2843; A. J. Stemmler, A. Barwinski, M. J. Baldwin, V. Young, V. L. Pecoraro, J. Am. Chem. Soc. 1996, 118, 11962-11963; B. R. Gibney, D. P. Kessissoglou, J. W. Kampf, V. L. Pecoraro, Inorg. Chem. 1994, 33, 4840-4849; M. S. Lah, B. R. Gibney, D. L. Tierney, J. E. Penner-Hahn, V. L. Pecoraro, J. Am. Chem. Soc. 1993, 115, 5857-5858; I. Haiduc, R. B. King in Large Ring Molecules (Ed.: J. A. Semlyen). Wiley, New York, 1996, p. 525ff; W. Hayes, J. F. Stoddart, in Large Ring Molecules (Ed.: J. A. Semlyen), Wiley, New York, 1996, p. 433ff; A. J. Blake, R. O. Gould, C. M. Grand, P. E. Y. Milne, D. Reed, R. E. P. Winpenny, Angew. Chem. 1994, 106, 208-210; Angew. Chem. Int. Ed. Engl. 1994, 33, 195-197; A. J. Blake, R. O. Gould, P. E. Y. Milne, R. E. P. Winpenny, J. Chem. Soc. Chem. Commun. 1991, 1453-1454; G. M. Gray, C. H. Duffey, Organometallics 1995, 14, 245-250; A. Caneschi, A. Cormia, S. J. Lippard, Angew. Chem. 1995, 107, 511-513; Angew. Chem. Int. Ed. Engl. 1995, 34, 467-469.
37. V. L. Pecoraro, A. J. Stemmler, B. R. Gibney, J. J. Bodwin, H. Wang, J. W. Kampf, A. Barwinski, Prog. Inorg. Chem. 1997, 45, 83-177; A. J. Stemmler, J. W. Kampf, V. L. Pecoraro, Angew. Chem. 1996, 108, 3011-3013; Angew. Chem. Int. Ed. Engl. 1996, 35, 2841-2843; A. J. Stemmler, A. Barwinski, M. J. Baldwin, V. Young, V. L. Pecoraro, J. Am. Chem. Soc. 1996, 118, 11962-11963; B. R. Gibney, D. P. Kessissoglou, J. W. Kampf, V. L. Pecoraro, Inorg. Chem. 1994, 33, 4840-4849; M. S. Lah, B. R. Gibney, D. L. Tierney, J. E. Penner-Hahn, V. L. Pecoraro, J. Am. Chem. Soc. 1993, 115, 5857-5858; I. Haiduc, R. B. King in Large Ring Molecules (Ed.: J. A. Semlyen). Wiley, New York, 1996, p. 525ff; W. Hayes, J. F. Stoddart, in Large Ring Molecules (Ed.: J. A. Semlyen), Wiley, New York, 1996, p. 433ff; A. J. Blake, R. O. Gould, C. M. Grand, P. E. Y. Milne, D. Reed, R. E. P. Winpenny, Angew. Chem. 1994, 106, 208-210; Angew. Chem. Int. Ed. Engl. 1994, 33, 195-197; A. J. Blake, R. O. Gould, P. E. Y. Milne, R. E. P. Winpenny, J. Chem. Soc. Chem. Commun. 1991, 1453-1454; G. M. Gray, C. H. Duffey, Organometallics 1995, 14, 245-250; A. Caneschi, A. Cormia, S. J. Lippard, Angew. Chem. 1995, 107, 511-513; Angew. Chem. Int. Ed. Engl. 1995, 34, 467-469.
38. V. L. Pecoraro, A. J. Stemmler, B. R. Gibney, J. J. Bodwin, H. Wang, J. W. Kampf, A. Barwinski, Prog. Inorg. Chem. 1997, 45, 83-177; A. J. Stemmler, J. W. Kampf, V. L. Pecoraro, Angew. Chem. 1996, 108, 3011-3013; Angew. Chem. Int. Ed. Engl. 1996, 35, 2841-2843; A. J. Stemmler, A. Barwinski, M. J. Baldwin, V. Young, V. L. Pecoraro, J. Am. Chem. Soc. 1996, 118, 11962-11963; B. R. Gibney, D. P. Kessissoglou, J. W. Kampf, V. L. Pecoraro, Inorg. Chem. 1994, 33, 4840-4849; M. S. Lah, B. R. Gibney, D. L. Tierney, J. E. Penner-Hahn, V. L. Pecoraro, J. Am. Chem. Soc. 1993, 115, 5857-5858; I. Haiduc, R. B. King in Large Ring Molecules (Ed.: J. A. Semlyen). Wiley, New York, 1996, p. 525ff; W. Hayes, J. F. Stoddart, in Large Ring Molecules (Ed.: J. A. Semlyen), Wiley, New York, 1996, p. 433ff; A. J. Blake, R. O. Gould, C. M. Grand, P. E. Y. Milne, D. Reed, R. E. P. Winpenny, Angew. Chem. 1994, 106, 208-210; Angew. Chem. Int. Ed. Engl. 1994, 33, 195-197; A. J. Blake, R. O. Gould, P. E. Y. Milne, R. E. P. Winpenny, J. Chem. Soc. Chem. Commun. 1991, 1453-1454; G. M. Gray, C. H. Duffey, Organometallics 1995, 14, 245-250; A. Caneschi, A. Cormia, S. J. Lippard, Angew. Chem. 1995, 107, 511-513; Angew. Chem. Int. Ed. Engl. 1995, 34, 467-469.
39. V. L. Pecoraro, A. J. Stemmler, B. R. Gibney, J. J. Bodwin, H. Wang, J. W. Kampf, A. Barwinski, Prog. Inorg. Chem. 1997, 45, 83-177; A. J. Stemmler, J. W. Kampf, V. L. Pecoraro, Angew. Chem. 1996, 108, 3011-3013; Angew. Chem. Int. Ed. Engl. 1996, 35, 2841-2843; A. J. Stemmler, A. Barwinski, M. J. Baldwin, V. Young, V. L. Pecoraro, J. Am. Chem. Soc. 1996, 118, 11962-11963; B. R. Gibney, D. P. Kessissoglou, J. W. Kampf, V. L. Pecoraro, Inorg. Chem. 1994, 33, 4840-4849; M. S. Lah, B. R. Gibney, D. L. Tierney, J. E. Penner-Hahn, V. L. Pecoraro, J. Am. Chem. Soc. 1993, 115, 5857-5858; I. Haiduc, R. B. King in Large Ring Molecules (Ed.: J. A. Semlyen). Wiley, New York, 1996, p. 525ff; W. Hayes, J. F. Stoddart, in Large Ring Molecules (Ed.: J. A. Semlyen), Wiley, New York, 1996, p. 433ff; A. J. Blake, R. O. Gould, C. M. Grand, P. E. Y. Milne, D. Reed, R. E. P. Winpenny, Angew. Chem. 1994, 106, 208-210; Angew. Chem. Int. Ed. Engl. 1994, 33, 195-197; A. J. Blake, R. O. Gould, P. E. Y. Milne, R. E. P. Winpenny, J. Chem. Soc. Chem. Commun. 1991, 1453-1454; G. M. Gray, C. H. Duffey, Organometallics 1995, 14, 245-250; A. Caneschi, A. Cormia, S. J. Lippard, Angew. Chem. 1995, 107, 511-513; Angew. Chem. Int. Ed. Engl. 1995, 34, 467-469.
40. V. L. Pecoraro, A. J. Stemmler, B. R. Gibney, J. J. Bodwin, H. Wang, J. W. Kampf, A. Barwinski, Prog. Inorg. Chem. 1997, 45, 83-177; A. J. Stemmler, J. W. Kampf, V. L. Pecoraro, Angew. Chem. 1996, 108, 3011-3013; Angew. Chem. Int. Ed. Engl. 1996, 35, 2841-2843; A. J. Stemmler, A. Barwinski, M. J. Baldwin, V. Young, V. L. Pecoraro, J. Am. Chem. Soc. 1996, 118, 11962-11963; B. R. Gibney, D. P. Kessissoglou, J. W. Kampf, V. L. Pecoraro, Inorg. Chem. 1994, 33, 4840-4849; M. S. Lah, B. R. Gibney, D. L. Tierney, J. E. Penner-Hahn, V. L. Pecoraro, J. Am. Chem. Soc. 1993, 115, 5857-5858; I. Haiduc, R. B. King in Large Ring Molecules (Ed.: J. A. Semlyen). Wiley, New York, 1996, p. 525ff; W. Hayes, J. F. Stoddart, in Large Ring Molecules (Ed.: J. A. Semlyen), Wiley, New York, 1996, p. 433ff; A. J. Blake, R. O. Gould, C. M. Grand, P. E. Y. Milne, D. Reed, R. E. P. Winpenny, Angew. Chem. 1994, 106, 208-210; Angew. Chem. Int. Ed. Engl. 1994, 33, 195-197; A. J. Blake, R. O. Gould, P. E. Y. Milne, R. E. P. Winpenny, J. Chem. Soc. Chem. Commun. 1991, 1453-1454; G. M. Gray, C. H. Duffey, Organometallics 1995, 14, 245-250; A. Caneschi, A. Cormia, S. J. Lippard, Angew. Chem. 1995, 107, 511-513; Angew. Chem. Int. Ed. Engl. 1995, 34, 467-469.
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43. [15]
44. [14]
45. 2 by the solvent methanol.
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49. SHELXS-96, program for structure solution: G. M. Sheldrick, Acta Crystallogr. Sect. A 1990, 46, 467.
50. SHELXL-96, program for structure refinement: G. M. Sheldrick, Universität Göttingen, 1996.
51. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication nos. CCDC-100739 (1) and 100744 (2, 3). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: int. code +(44)1223 336-033; e-mail: deposit@ccdc.cam.ac.uk). Red-green stereo presentations of 1-3 are available on the WWW under http://www.organik.uni-erlangen.de/saalfrank/index.html.