From Molecular to One-Dimensional Polychalcogenides: Preparation, Structure, and Reactivity of NaNbS6, the First Ternary Alkali Metal Niobium Polychalcogenide Exhibiting Infinite Anionic Chains

Angewandte Chemie - International Edition

Volumn 37, Issue 1-2, 1998, Pages 133-135

  Bensch, Wolfgang ^a   Näther, Christian ^a   Dürichen, Peter ^a  

^a UNIVERSITY OF KIEL   (Germany)

Author keywords

Chain compounds; Chalcogens; Low dimensional materials; Niobium; Reactive melts

Indexed keywords

EID: 0031881551     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980202)37:1/2<133::AID-ANIE133>3.0.CO;2-C     Document Type: Article

References (21)

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13. 6 is stable against air and water.
14. 3). Further details of the crystal structure investigation may be obtained from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshafen (Germany), on quoting the depository number CSD-407708.
15. R. D. Shannon, Acta Crystallogr. Sect A 1976, 32, 751-767.
16. 2 plot.
17. G. Kortüm, Reflectance spectroscopy, Springer, New York, 1969.
18. 2.
19. Additional tempering experiments in glass ampoules produced a yellow solid at the colder end of the ampoule, which was identified as sulfur by X-ray fluorescence analysis (RFA).
20. W. Omloo, F. Jellinek, J. Less Common Met. 1970, 20, 121-129.
21. P. Dürichen, M. Boite, W. Bensch, unpublished results.