Rare earth element speciation in geothermal fluids from Yellowstone National Park, Wyoming, USA

Geochimica et Cosmochimica Acta

Volumn 62, Issue 4, 1998, Pages 657-663

  Lewis, A J ^a,c   Komninou, A ^a   Yardley, B W D ^a   Palmer, M R ^b  

^a UNIVERSITY OF LEEDS   (United Kingdom)

^b UNIVERSITY OF BRISTOL   (United Kingdom)

^c UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

GEOTHERMAL FLUID; REE; SPECIATION;

USA;

EID: 0031827119     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7037(97)00367-0     Document Type: Article

References (44)

1. Allan W. P., Schiff S., Pierson D., English M., Ecclestone M, and Adams P. (1987) Colour Lake, Axel Heiberg Island, NWT, a naturally acid, High Arctic Lake-data report. Cent. N. Stud. Res., McGill University, Montreal, Quebec. Misc. Paper 2.
2. Baes C. F. and Mesmer R. E. (1976) The Hydrolysis of Cations. Wiley.
3. 2. J. Petrol. 29, 445-522.
4. Berman R. G. (1990) Mixing properties of Ca-Mg-Fe-Mn garnets. Amer. Mineral. 75, 328-344.
5. Brookins D. G. (1988) Eh-pH Diagrams for Geochemistry. Springer-Verlag.
6. Brookins D. G. (1989) Aqueous geochemistry of rare earth elements. In Geochemistry and Mineralogy of Rare Earth Elements (ed. B. R. Lipin and G. A. McKay), pp. 201-225. MSA.
7. Cantrell K. J. and Byrne R. H. (1987) Rare earth element complexation by carbonate and oxalate ions. Geochim. Cosmochim. Acta 51, 597-605.
8. Chernosky J. V. Jr., Berman R. G., and Bryndzia L. T. (1988) Stability, phase relations, and thermodynamic properties of chlorite and serpentine group minerals. In Hydrous Phyllosilicates (ed. S. W. Bailey), pp. 295-346. MSA.
9. de Baar H. J. W., German C. R., Elderfield H., and van Gaans P. (1988) Rare earth element distributions in anoxic waters of the Cariaco Trench. Geochim. Cosmochim. Acta 52, 1203-1219.
10. Fein J. B., Hemley J. J., d'Angelo W. M., Komninou A., and Sverjensky D. A. (1992) Experimental study of iron chloride complexing in hydrothermal fluids. Geochim. Cosmochim. Acta 56, 3179-3190.
11. Fournier R. O. (1989) Geochemistry and dynamics of the Yellowstone National Park Hydrothermal system. Annu. Rev. Earth Planet. Sci. 16, 13-51.
12. Fournier R. O., Thompson J. M., and Hutchinson R. A. (1986) Fluctuations in composition of Cistern Spring, Norris Geyser Basin, Wyoming-variable boiling and mixing 1962-1985. Ext. Abst. Fifth Intl. Symp. Water-Rock Interaction, 206-209 (abstr.).
13. Haas J. R., Shock E. L., and Sassani D. C. (1995) Rare earth elements in hydrothermal systems: Estimates of standard partial molal thermodynamic properties of aqueous complexes of the rare earth elements at high pressures and temperatures. Geochim. Cosmochim. Acta 59, 4329-4350.
14. Helgeson H. C. (1969) Thermodynamics of hydrothermal systems at elevated temperatures and pressures. Amer. J. Sci. 267, 729-804.
15. Helgeson H. C., Delaney J. M., Nesbitt H. W., and Bird D. K. (1978) Summary and critique of the thermodynamic properties of rock-forming minerals. Amer. J. Sci. 278A, 1-229.
16. Johannesson K. H. and Lyons W. B. (1995) Rare earth element geochemistry of Colour Lake, and acidic freshwater lake on Axel Heiberg Island, Northwest Territories, Canada. Chem. Geol. 119, 209-233.
17. Langmuir D. (1978) Uranium solution-mineral equilibria at low temperatures with applications to sedimentary ore deposits. Geochim. Cosmochim. Acta 42, 547-570.
18. Lee H. L. and Byrne R. H. (1992) Examination of comparative rare earth element complexation behavior using linear free-energy relationships. Geochim. Cosmochim. Acta 56, 1127-1137.
19. Lewis A. J. (1995) The behaviour of trace elements and boron isotopes in the Yellowstone hydrothermal system. Ph.D. thesis, Univ. Bristol.
20. Lewis A. J., Palmer M. R., Kemp A. J., and Sturchio N. C. (1995) REE behaviour in the Yellowstone geothermal system. Ext. Abst. 8th Int. Symp. Water-Rock Interaction, 91-94.
21. Lewis A. J., Palmer M. R., Sturchio N. C., and Kemp A. J. (1997) The rare earth element geochemistry of acid-sulphate and acid-sulphatechloride geothermal systems from Yellowstone National Park. Geochim. Cosmochim Acta 61, 695-706.
22. Mäder U. K. and Berman R. G. (1992) Amphibole thermobarometry: A thermodynamic approach. Curr. Res. Part E, 393-400.
23. Mariano A. N. (1989) Economic Geology of Rare Earth minerals. In Geochemistry and Mineralogy of Rare Earth Elements (ed. B. R. Lipin and G. A. McKay), pp. 309-337. MSA.
24. Michard A. (1989) Rare earth element systematics in hydrothermal fluids. Geochim. Cosmochim. Acta 53, 745-750.
25. Millero F. J. (1992) Stability constants for the formation of rare earth inorganic complexes as a function of ionic strength. Geochim. Cosmochim. Acta 56, 3123-3132.
26. Saccocia P. J. and Seyfried W. E. J. (1993) A resolution of discrepant thermodynamic properties for chamosite retrieved from experimental and empirical techniques. Amer. Mineral. 78, 607-611.
27. Shock E. L. and Helgeson H. C. (1988) Calculation of the thermodynamic and transport properties of aqueous species at high temperatures: Correlation algorithms for ionic species and equation of state predictions to 5 kb and 1000°C. Geochim. Cosmochim. Acta 52, 2009-2036.
28. Shock E. L. and Helgeson H. C. (1990) Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: Standard partial molal properties of organic species. Geochim. Cosmochim. Acta 54, 915-945.
29. Shock E. L., Helgeson H. C. and Sverjensky D. A. (1989) Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: Standard partial molal properties of inorganic neutral species. Geochim. Cosmochim. Acta 53, 2157-2184.
30. Shock E. L. and Koretsky C. M. (1993) Metal-organic complexes in geochemical processes: Calculation of standard partial molal thermodynamic properties of aqueous acetate complexes at high pressures and temperatures. Geochim. Cosmochim. Acta 57, 4899-4922.
31. Shock E. L. and Koretsky C. M. (1995) Metal-organic complexes in geochemical processes: Calculation of standard partial molal thermodynamic properties of aqueous complexes between metal cations and monovalent organic acid ligands at high pressures and temperatures. Geochim. Cosmochim. Acta 59, 1497-1532.
32. Sverjensky D. A., Hemley J. J., and D'Angelo W. M. (1991) Thermodynamic assessment of hydrothermal alkali feldspar-mica-alumino-silicate equilibria. Geochim. Cosmochim. Acta 55, 989-1004.
33. Tanger J. C. and Helgeson H. C. (1988) Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: Revised equations of state for the standard partial molal properties of ions and electrolytes. Amer. J. Sci. 288, 19-98.
34. Turner D. R., Whitfield M., and Dickson A. G. (1981) The equilibrium speciation of dissolved components in freshwater and seawater at 25°C and 1 atm. pressure. Geochim. Cosmochim. Acta 45, 855-881.
35. White D. E., Fournier R. O., Muffler L. P. J., and Truesdell A. H. (1975) Physical results of research drilling in thermal areas of Yellowstone National Park, Wyoming. USGS Professional Paper 892.
36. White D. E., Hutchinson R. A., and Keith T. E. C. (1988) The geology and remarkable thermal activity of Norris Geyser Basin, Yellowstone National Park, Wyoming. USGS Professional Paper, 1456.
37. Wolery T. J. (1983) EQ3NR: A computer program for geochemical aqueous speciation-solubility calculations, user's guide and documentation. UCRL-53414. Lawrence Livermore National Laboratory, Univ. California.
38. Wolery T. J. and Daveler S. A. (1992) EQ3/6, a software package for geochemical modelling of aqueous systems. UCRL-MA-110772 PT I-IV. Lawrence Livermore National Laboratory, Univ. California.
39. Wolery T. J., Sherwood D. J., Jackson K. J., Delaney J. M., and Puigdimenech I. (1984) EQ3/6: Status and applications: UCRL-91884. Lawrence Livermore National Laboratory, Univ. California.
40. Wood S. A. (1990a) The aqueous geochemistry of the rare-earth elements and yttrium 1. Review of the available low-temperature data for inorganic complexes and the inorganic REE speciation of natural waters. Chem. Geol. 82, 159-186.
41. Wood S. A. (1990b) The aqueous geochemistry of the rare-earth elements and yttrium 2. Theoretical predictions of speciation in hydrothermal solutions to 350°C at saturation water vapor pressure. Chem. Geol. 88, 99-125.
42. Wood S. A. and Williams A. E. (1994) The aqueous geochemistry of the rare-earth elements and yttrium 4. Monazite solubility and REE mobility in exhalative massive sulfide-depositing environments. Chem. Geol. 115, 7-60.
43. Zhu C. and Sverjensky D. A. (1991) Partitioning of F, Cl, and OH between minerals and hydrothermal fluids. Geochim. Cosmochim. Acta 55, 1837-1858.
44. Zhu C. and Sverjensky D. A. (1992) F-Cl-OH partitioning between biotite and apatite. Geochim. Cosmochim. Acta 56, 3435-3468.