Chemistry of unsaturated zone gases sampled in open boreholes at the crest of Yucca Mountain, Nevada: Data and basic concepts of chemical and physical processes in the mountain

Water Resources Research

Volumn 34, Issue 6, 1998, Pages 1507-1529

  Thorstenson, Donald C ^a   Weeks, Edwin P ^a   Haas, Herbert ^b   Busenberg, Eurybiades ^c   Plummer, L Niel ^c   Peters, Charles A ^c  

^a DENVER FEDERAL CENTER   (United States)

^b DESERT RESEARCH INSTITUTE   (United States)

^c U S GEOLOGICAL SURVEY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BOREHOLES; CARBON DIOXIDE; GROUNDWATER; HYDROGEOLOGY; TRAVEL TIME;

BASIC CONCEPTS; CANYON FLOW; HYDROGEOLOGIC UNIT; NATURAL SYSTEMS; PHYSICAL PROCESS; SHALLOW FLOW; UNSATURATED ZONE; YUCCA MOUNTAIN , NEVADA;

LANDFORMS;

EID: 0031801142     PISSN: 00431397     EISSN: None     Source Type: Journal    
DOI: 10.1029/98WR00267     Document Type: Article

References (58)

1. Anderson, L. A., Water permeability and related rock properties measured on core samples from the Yucca Mountain USW GU-3/G-3 and USW G-4 boreholes, Nevada Test Site, Nevada, U.S. Geol. Surv. Open File Rep., 92-201, 1994.
2. Benson, L. V., and P. W. McKinley, Chemical composition of ground water in the Yucca Mountain area, Nevada, 1971-84, U.S. Geol. Surv. Open File Rep., 85-484, 1985.
3. Blout, D. O., D. P. Hammermeister, C. L. Loskot, and M. P. Chornack, Geohydrologic data collected from shallow neutron-access bore-holes and resultant-preliminary geohydrologic evaluations, Yucca Mountain area, Nye County, Nevada, U.S. Geol. Surv. Open File Rep., 92-657, 1994.
4. 2): Use as an age dating tool and hydrologic tracer in shallow ground-water systems, U.S. Geol. Surv. Water-Resour. Invest. Rep. 91-4034, pp. 542-547, 1991.
5. 2) as hydrologic tracers and age-dating tools: Example-the alluvium and terrace system of Central Oklahoma, Water Resour. Res., 28, 2257-2283, 1992.
6. Busenberg, E., E. P. Weeks, L. N. Plummer, and Roy C. Bartholomay, Age dating ground water by use of chlorofluorocarbons in the unsaturated zone, Snake River Plain Aquifer, Idaho National Engineering Laboratory, Idaho, U.S. Geol. Surv. Water Resour. Invest. Rep. 93-4054, 1993.
7. Carslaw, H. S., and J. C. Jaeger, Conduction of Heat in Solids, p. 59, Oxford Univ. Press, Oxford, 1959.
8. Cerling, T. E., The stable isotopic composition of modern soil carbonate and its relationship to climate, Earth Planet. Sci. Lett., 71, 229-240, 1984.
9. 2, Geochim. Cosmochim. Acta, 59, 2485-2489, 1995.
10. Day, W. C., C. P. Potter, D. S. Sweetkind, R. P. Dickerson, and C. A. San Juan, Bedrock geologic map of the central block of Yucca Mountain, Nye County, Nevada, U.S. Geol. Surv. Misc. Inv. Ser., Map I-2601, 1998.
11. 2, Radiocarbon, 22, 909-918, 1980.
12. Frizzell, V. A., Jr., and J. Shulters, Geologic map of the Nevada Test Site, Southern Nevada, U.S. Geol. Surv. Misc. Invest. Ser., Map I-2046, 1990.
13. 2 measurements on soil atmosphere sampled in the subsurface unsaturated zone in the western Great Plains of the U.S., Radiocarbon, 25, 301-314, 1983.
14. Hammermeister, D. P., D. O. Blout, and J. C. McDaniel, Drilling and coring methods that minimize the disturbance of cuttings, core, and rock formation in the unsaturated zone, Yucca Mountain, Nevada, in Proceedings of the National Water Well Association Conference on Characterization and Monitoring of the Vadose (Unsaturated) Zone, November 18-21, Denver, Colorado, pp. 507-541, Natl. Water Well Assoc., Dublin, Ohio, 1985.
15. Heid, J. G., J. J. McMahon, R. F. Nielson, and S. T. Yuster, Study of the permeability of rocks to homogenous fluids, in Drilling and Production Practice, pp. 230-244, Am. Pet. Inst., New York, 1950.
16. Katz, D. L., Cornell, D., Kobayashi, R., Poettman, F. H., Vary, J. A., Elenbaas, J. R., and C. F. Weinaug, Handbook of Natural Gas Engineering, McGraw-Hill, New York, 1959.
17. LeCain, G. D., Air-injection testing in vertical boreholes in welded and nonwelded tuff, Yucca Mountain, Nevada, U.S. Geol. Surv. Water Resour. Invest. Rep., 96-4262, 1997.
18. Loskot, C. L., Geohydrologic data from test hole USW UZ-6s, Yucca Mountain, Nye County, Nevada, U.S. Geol. Surv. Open File Rep., 93-60, 1993.
19. Marrero, T. R., and E. A. Mason, Gaseous diffusion coefficients, J. Phys. Chem. Ref. Data, 1, 3-118, 1972.
20. McConnaughey, T. A., J. F. Whelan, K. P. Wickland, and R. J. Moscati, Isotopic studies of Yucca Mountain soil fluids and carbonate pedogenesis, in High Level Radioactive Waste Management, Proceedings of the Fifth Annual International Conference, Las Vegas, Nevada, pp. 2584-2589, Am. Nucl. Soc., Lagrange Park, Ill., 1994.
21. Millington, R. J., 1959, Gas diffusion in porous media, Science, 130, 100-102, 1959.
22. Moench, A. F., Double-porosity model for a fissured ground-water reservoir with fracture skin, Water Resour. Res., 20(7), 831-846, 1984.
23. Montazer, P., and W. E. Wilson, Conceptual hydrologic model of flow in the unsaturated zone, Yucca Mountain, Nevada, U.S. Geol. Surv. Water Resour. Invest. 84-4345, 1984.
24. Montazer, P., and W. E. Wilson, Hydrogeology of the unsaturated zone, Yucca Mountain, Nevada, in Proceedings of the National Water Well Association Conference on Characterization and Monitoring of the Vadose (Unsaturated) Zone, November 18-21, Denver, Colorado, pp. 396-412, Natl. Water Well Assoc., Dublin, Ohio, 1985.
25. Montazer, P., E. P. Weeks, F. Thamir, S. N. Yard, and P. B. Hofrichter, Monitoring the vadose zone in fractured tuff, Yucca Mountain, Nevada, in Proceedings of the National Water Well Association Conference on Characterization and Monitoring of the Vadose (Unsaturated) Zone, November 18-21, Denver, Colorado, pp. 439-469, Natl. Water Well Assoc., Dublin, Ohio, 1985.
26. Montazer, P., E. P. Weeks, F. Thamir, S. N. Yard, and P. B. Hofrichter, Monitoring the vadose zone in fractured tuff, Ground Water Monit. Rev., 8(2), 72-88, 1988.
27. Ogard, A. E., and J. R. Kerrisk, Groundwater chemistry along flow paths between a proposed repository site and the accessible environment, Rep. LA-10188-MS, Los Alamos Natl. Lab., Los Alamos, N. M., 1984.
28. Peters, C. A., I. C. Yang, J. D. Higgins, and P. A. Burger, A preliminary study of the chemistry of pore water extracted from tuff by one-dimensional compression, in Water Rock Interaction, edited by Y. K. Kharaka and A. S. Maest, pp. 741-745, A. A. Balkema, Brookfield, Vt., 1992.
29. Peters, R. R., E. A. Klavetter, I. J. Hall, S. C. Blair, P. R. Heller, and G. W. Gee, Fracture and matrix hydrologic characteristics of tuffaceous materials from Yucca Mountain, Nye County, Nevada, Sandia Rep. SAND84-1471, Sandia Natl. Lab., Albuquerque, N. M., 1984.
30. Quade, J., T. E. Cerling, and J. R. Bowman, Systematic variations in the carbon and oxygen isotopic composition of pedogenic carbonate along elevation transects in the southern Great Basin, United States, Geol. Soc. Am. Bull., 101, 464-475, 1989.
31. Raich, J. W., and W. H. Schlesinger, The global carbon dioxide flux in soil respiration and its relation to vegetation and climate, Tellus Ser. B, 44, 81-99, 1992.
32. 2 at Trout Creek, Ontario, J. Hydrol., 43, 355-371, 1979.
33. Scott, R. B., and J. Bonk, Preliminary geologic map of Yucca Mountain, Nye County, Nevada, with geologic sections, U.S. Geol. Surv. Open File Rep., 84-494, 1984.
34. Striegl, R. G., Diffusional limits to the consumption of atmospheric methane by soils, Chemosphere, 26, 715-720, 1993.
35. Striegl, R. G., T. A. McConnaughey, D. C. Thorstenson, E. P. Weeks, and J. C. Woodward, Consumption of atmospheric methane by desert soils, Nature, 357, 145-147, 1992.
36. 2 carbon isotope signature of gases from borehole USW UZ-6, Yucca Mountain, Nevada, in Proceedings of Workshop V: Flow and Transport Through Unsaturated Fractured Rock - Related to High-Level Radioactive Waste Disposal, January 7-10, Tucson, Arizona, 1991, edited by D. D. Evans and T. J. Nicholson, U.S. Nucl. Reg. Comm. Conf. Publ., NUREG/ CP-0040, 184-188, 1993.
37. Thorstenson, D. C., and D. W. Pollock, Gas transport in unsaturated zones: Multicomponent systems and the adequacy of Pick's laws, Water Resour. Res., 25, 477-507, 1989.
38. 2 in the subsoil unsaturated zone of the western U.S. Great Plains, Radiocarbon, 25, 315-346, 1983.
39. Thorstenson, D. C., E. P. Weeks, H. Haas, and J. C. Woodward, Physical and chemical characteristics of topographically affected airflow in an open borehole at Yucca Mountain, Nevada, in Proceedings, Nuclear Waste Isolation in the Unsaturated Zone, Focus '89, Las Vegas, Nevada, pp. 256-270, Am. Nucl. Soc., La Grange Park, Ill., 1990.
40. U.S. Department of Energy, Yucca Mountain Site Characterization Project Bibliography, 1992-1993, Rep. DOE/OSTI - 3406, Suppl. 4, Washington, D. C., Aug. 1994.
41. U.S. Department of Energy, Site Characterization Progress Report: Yucca Mountain, Nevada, April 1, 1994-September 30, 1994, Rep. DOE/RW-0463, Off. of Civ. Radioactive Waste Manag., Washington, D. C., 1995.
42. van Bavel, C. H. M., A soil aeration theory based on diffusion: Soil Sci., 72, 33-46, 1951.
43. Vaniman, D. T., and J. F. Whelan, Inferences of paleoenvironment from petrographic, chemical, and stable-isotope studies of calcretes and fracture calcites, in High Level Radioactive Waste Management, Proceedings of the Fifth Annual International Conference, Las Vegas, Nevada, pp. 2730-2737, Am. Nucl. Soc., Lagrange Park, Ill., 1994.
44. Van Konynenberg, R. A., Gaseous release of carbon-14: Why the high level waste regulations should be changed, in High Level Radioactive Waste Management, Proceedings of the Second Annual International Conference, Las Vegas, Nevada, vol. 1, pp. 313-319, Am. Nucl. Soc., Lagrange Park, Ill., 1991.
45. Van Konynenberg, R. A., Behavior of carbon-14 in waste packages for spent fuel in a tuff repository, Waste Manag. J., 14(5), 363-383, 1994.
46. Weast, R. C., D. R. Lide, M. J. Astle, and W. H. Beyer, eds., CRC Handbook of Chemistry and Physics, CRC Press, Boca Raton, Fla., 1990.
47. Weeks, E. P., Field determination of vertical permeability to air in the unsaturated zone, U.S. Geol. Surv. Prof. Pap. 1051, 1978.
48. Weeks, E. P., Barometric fluctuations in wells tapping deep unconfined aquifers, Water Resour. Res., 15, 1167-1176, 1979.
49. Weeks, E. P., Effect of topography on gas flow in unsaturated fractured rock: Concepts and observations, in Flow and Transport Through Unsaturated Fractured Rock, Geophys. Monogr. Ser., vol. 42, edited by D. D. Evans and T. J. Nicholson, pp. 165-170, AGU, Washington, D. C., 1987.
50. Weeks, E. P., Does the wind blow through Yucca Mountain? in Proceedings of Workshop V: Flow and Transport through Unsaturated Fractured Rock - Related to High-Level Radioactive Waste Disposal, January 7-10, Tucson, Arizona, 1991, edited by D. D. Evans and T. J. Nicholson, U.S. Nucl. Reg. Comm., NUREG/CP-0040, 43-53, 1993.
51. Wenzel, L. K., Methods for determining permeability of water-bearing materials, with special reference to discharging-well methods, U.S. Geol. Surv. Water-Supply Pap. 887, 1942.
52. Whelan, J. F., D. T. Vaniman, J. S. Stuckless, and R. J. Moscati, Paleoclimatic and paleohydrologic records from secondary calcite: Yucca Mountain, Nevada, in High Level Radioactive Waste Management, Proceedings of the Fifth Annual International Conference, Las Vegas, Nevada, pp. 2738-2745, Am. Nucl. Soc., Lagrange Park, Ill., 1994.
53. Whitfield, M. S., Vacuum drilling of unsaturated tuff at a potential radioactive waste repository, Yucca Mountain, Nevada, in Proceedings of the National Water Well Association Conference on Characterization and Monitoring of the Vadose (Unsaturated) Zone, November 18-21, Denver, Colorado, pp. 413-423, Natl. Water Well Assoc., Dublin, Ohio, 1985.
54. Whitfield, M. S., W. Thordarson, and D. P. Hammermeister, Drilling and geohydrologic data for test hole USW UZ-1, Yucca Mountain, Nye County, Nevada, U.S. Geol. Surv. Open File Rep., 90-354, 1990.
55. Whitfield, M. S., C. M. Cope, and C. L. Loskot, Borehole and geohydrologic data for test hole USW UZ-6, Yucca Mountain area, Nye County, Nevada, U.S. Geol. Surv. Open File Rep., 92-28, 1993.
56. Winograd, I. J., and F. N. Robertson, Deep oxygenated ground water: Anomaly or common occurrence?, Science, 216, 1227-1230, 1982.
57. Yang, I. C., H. Haas, E. P. Weeks, and D. C. Thorstenson, Analysis of gaseous-phase stable and radioactive isotopes in the unsaturated zone, Yucca Mountain, Nevada, in Proceedings of the National Water Well Association Conference on Characterization and Monitoring of the Vadose (Unsaturated) Zone, pp. 488-506, Natl. Water Well Assoc., Dublin, Ohio, 1985.
58. Yang, I. C., C. A. Peters, and D. C. Thorstenson, Carbon isotopic data from test hole USW UZ-1, Yucca Mountain, Nevada, in High Level Radioactive Waste Management, Proceedings of the Fourth Annual International Conference, Las Vegas, Nevada, vol. 1, pp. 401-405, Am. Nucl. Soc., Lagrange Park, Ill., 1993.