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Volumn 63, Issue 24, 1998, Pages 8860-8864

Free radical chlorinations in halogenated solvents: Are there any solvents which are truly noncomplexing?

Author keywords

[No Author keywords available]

Indexed keywords

ALKANE DERIVATIVE; FREE RADICAL; SOLVENT;

EID: 0031791871     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo980991n     Document Type: Article
Times cited : (30)

References (31)
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    • S(3°/1°) = 6([3° RC1]/[1° RC1])
    • S(3°/1°) = 6([3° RC1]/[1° RC1]).
  • 10
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    • For reviews, see: (a) Ingold, K. U.; Lusztyk, J.; Raner, K. D. Acc. Chem. Res. 1990, 23, 219. (b) Tanko, J. M.; Suleman, N. K. in Energetics of Organic Free Radicals; Simões, J. A. M., Greenberg, A., Liebman, J., Eds.; Chapman & Hall: New York, 1996; pp 224-293.
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    • For reviews, see: (a) Ingold, K. U.; Lusztyk, J.; Raner, K. D. Acc. Chem. Res. 1990, 23, 219. (b) Tanko, J. M.; Suleman, N. K. in Energetics of Organic Free Radicals; Simões, J. A. M., Greenberg, A., Liebman, J., Eds.; Chapman & Hall: New York, 1996; pp 224-293.
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    • A common criteria for the assignment of charge-transfer complexes is linearity in the polot of the charge-transfer energy of several complexes with the same acceptor against the vertical ionization potential of the donor, see Bühler, R. E.; Ebert, M. Nature 1967, 214, 1220. Bühler, R. E. Radiat. Res. Rev. 1972, 4, 233.
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    • A common criteria for the assignment of charge-transfer complexes is linearity in the polot of the charge-transfer energy of several complexes with the same acceptor against the vertical ionization potential of the donor, see Bühler, R. E.; Ebert, M. Nature 1967, 214, 1220. Bühler, R. E. Radiat. Res. Rev. 1972, 4, 233.
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    • note
    • 2CHCl (i.e., assuming that (Solv/Cl·) abstracts hydrogen from solvent with a rate constant less than or equal to that for free Cl·), it is apparent that hydrogen abstraction from solvent has only a negligible effect on selectivity in these experiments.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.