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1H NMR spectroscopy showed that after one day most of the starting dichlorosilane 12 had been converted into a mixture of the two diastereomers of the coupling product Cl(Ar)(Mes)Si-Si(Mes)(Ar)Cl. The results of investigations addressing the mechanism of the reaction of these and other 1,2-dichlorodisilanes with magnesium will be published elsewhere.
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