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This is because (i) bulky N-isopropyl groups are expected to be more sterically active than N-propyl groups, and (ii) N-alkyl groups in s-complexes of en derivatives usually tend to occupy equatorial positions with respect to the chelate ring, in u-dipen, however, one such group is forced to occupy an axial position, increasing axial steric hindrance (cf. Ref. 1).
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