Chirality alteration of racemic thiaheterohelicenes with a labile helix incorporated into alkyl β-D-pyranoside micelles

Enantiomer

Volumn 3, Issue 2, 1998, Pages 175-179

  Nakagawa, Hiroko ^a   Gomi, Kanae ^a   Yamada, Koh Ichi ^a  

^a JOSAI UNIVERSITY   (Japan)

Author keywords

Alkyl D glucoside micelle; Alkyl D maltoside micelle; Chiral discrimination energy; Induced CD; Thiaheterohelicene

Indexed keywords

ALCOHOL DERIVATIVE; CARBOXYLIC ACID DERIVATIVE; PYRANOSIDE;

ARTICLE; CHIRALITY; ENANTIOMER; EQUILIBRIUM CONSTANT; MICELLE; PRIORITY JOURNAL; RACEMIC MIXTURE; TEMPERATURE DEPENDENCE; THERMODYNAMICS;

EID: 0031740596     PISSN: 10242430     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (15)

1. IUPAC name: thieno[3,2-e:4,5-e′]di[1]benzothiophene.
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9. Kano, K. and Ishimura, T. (1995) J. Chem. Soc., Perkin Trans, 2, 1655-1659. Bilirubin in the micelles showed ICD due to a conformational enantiomer with a (S)-helix caused by the formation of intramolecular hydrogen-bonds.
10. -3 [8]. Shinoda, K., Yamaguchi, T. and Hori, R. (1961) Bull. Chem. Soc. Jpn., 34, 237-241.
11. According to the Clar's nomenclature. Clar, E. (1936) Chem. Ber., 69, 607-614.
12. IUPAC name: bisthieno[3′,2′:4,5]benzo[1,2-b:4.3-b′]di[1]-benzothiophene.
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