Precise measurement of the activity/composition relations of H2O-N2 and H2O-CO2 fluids at 500°C, 500 bars

Geochimica et Cosmochimica Acta

Volumn 62, Issue 5, 1998, Pages 815-829

  Anovitz, Lawrence M ^a   Blencoe, James G ^a   Joyce, David B ^a   Horita, Juske ^a  

^a OAK RIDGE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVITY/COMPOSITION RELATIONS; EQUATION OF STATE; FLUID; THERMODYNAMICS;

EID: 0031694388     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7037(98)00027-1     Document Type: Article

References (74)

1. Abdulagatov I. M., Bazaev A. R., and Ramazanova A. E. (1993) P-V-T-x measurements of aqueous mixtures at supercritical condi-tions. Int. J. Thermophys. 14, 231-250.
2. Ackerman F. J. and Koskinas G. J. (1972) Permeation of hydrogen and deuterium through palladium-silver alloys. J. Chem. Eng. Data 17, 51-55.
3. 2 in water from room temperature to 640 K. Ber. Bunsenges. Phys. Chem. 92, 935-940.
4. Alvarez J. and Fernândez-Prini R. (1991) A semiempirical procedure to describe the thermodynamics of dissolution of non-polar gases in water. Fluid Phase Equilibria 66, 309-326.
5. Baiker A. and Maciejewski M. (1984) Formation and thermal stability of copper and nickel nitrides. J. Chem. Soc., Faraday Trans. 80, 2331-2341.
6. Basaev A. R., Skripka V. G., and Namiot A. Yu. (1974) The volume properties of mixtures of water vapor with methane and nitrogen at elevated temperatures and pressures. Zh. Fiz. Khim. 48, 2392. (See also VINITI deposited document 1631-74, June 17, 1974.)
7. Bhattacharyya S. K. and Anovitz L. M. (1993) Measurement of the Gibbs free energies of some metal oxide reactions. GSA Abstr. Prog. 25, A94.
8. Bigeleisen J., Perlman M. L., and Prosser H. C. (1952) Conversion of hydrogenic materials to hydrogen for isotopic analysis. Anal. Chem. 24, 1356-1357.
9. 2O hydrogen buffer at 500°C, 500 bars. GSA Abstr. Prog. 28, A159.
10. Brown B. R. (1964) Nitrides. In Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry (éd. A. A. Eldridge et al.), Vol. 8, Suppl. I, Part I, 150-239. Wiley.
11. Chase M. W., Jr., Davies C. A., Downey J. R., Jr., Frurip D. J., McDonald R. A., and Syverud A. N. (1985) JANAF Thermochemical Tables, 3rd éd.; J. Phys. Chem. Réf. Data 14, Supp. 1. Amer. Chem. Soc.
12. Chou I.-M. (1987) Oxygen buffer and hydrogen sensor techniques at elevated pressures and temperatures. In Hydrothermal Experimental Techniques, Chap. 3, pp. 61-99. Wiley-Interscience.
13. 2O fluids at 2 kbar and 600°C. GSA Abstr. Prog. 22, A342.
14. 2O activities in supercritical fluids. Eos 75, 135.
15. Chou I.-M. and Moecher D. P. (1989) A new method for control and measurement of N2 and NH3 fugacities in hydrothermal experiments. GSA Abstr. Prog. 21, A155.
16. Choudhary C. B., Maiti H. S., and Subbarao E. C. (1980) Defect structure and transport properties. In Solid Electrolytes and Their Applications (ed. E. C. Subbarao), pp. 1-80. Plenum Press.
17. 2 mixtures. J. Phys. Chem. 95, 9034-9036.
18. Cox J. D., Wagman D. D., and Medvedev V. A. (1989) CODATA Key Values for Thermodynamics. Hemisphere Publ. Corp.
19. 2O system: I. Pure systems from 0 to 1000°C and 0 to 8000 bar. Geochim. Cosmochim. Acta 56, 2605-2617.
20. 2O system: II. Mixtures from 50 to 1000°C and 0 to 1000 bar. Geochim. Cosmochim. Acta 56, 2619-2631.
21. Fenghour A., Wakeman W. A., Ferguson D., Scott A. C., and Watson J. T. R. (1993) Densities of (water + nitrogen) in the temperature range 533 K to 703 K and at pressures up to 31 MPa. J. Chem. Therm. 25, 1151-1159.
22. Fenghour A., Wakeman W. A., and Watson J. T. R. (1996) Densities of (water + carbon dioxide) in the temperature range 415 K to 700 K and at pressures up to 35 MPa. J. Chem. Therm. 28, 433-446.
23. Flowers G. C. (1979) Correction of Holloway's (1977) adaptation of the modified Redlich-Kwong equation of state for calculation of the fugacities of molecular species in supercritical fluids of geologic interest. Contrib. Mineral. Petrol. 69, 315-318.
24. Franck E. U. and Tödheide K. Z. (1959) Thermische Eigen Schäften überkritischer Mischungen von Kohlendioxyd und Wasser bis zu 750°C und 2000 Atm. Z. Physik. Chem. 22, 232-245.
25. Gallagher J. S., Levelt Sengers J. M. H., Abdulagatov I. M., Watson J. T. R., and Fenghour A. (1993) Thermodynamic properties of homogeneous mixtures of nitrogen and water from 440 to 1000 K, up to 100 MPa and 0.8 mole fraction N2. Natl. Inst. Standards and Technology Tech. Note 1404.
26. Gehrig M. (1980) Phasengleichgewichte und p VT- Daten ternärer Mischungen aus Wasser, Kohlendioxid und Natriumchlorid bis 3 kbar and 550°C. Hochschulverlag.
27. Greenwood H. J. (1969) The compressibility of gaseous mixtures of carbon dioxide and water between 0 and 500 bars and 450° and 800° centigrade. Amer. J. Sci. 267A, 191-208.
28. 2 between 450° and 800°C and 0 to 500 bars. Amer. J. Sci. 273, 561-571.
29. Gunter W. E., Myers J., and Girsperger S. (1987) Hydrogen: metal membranes. In Hydrothermal Experimental Techniques, Chap. 4, pp. 100-120. Wiley-Interscience.
30. Haar L., Gallagher J. S., and Kell G. S. (1984) NBS/NRC Steam Tables. Hemisphere Publ. Corp.
31. Hallam M. and Eugster H. P. (1976) Ammonium silicate stability relations. Contrib. Mineral. Petrol. 57, 227-244.
32. 3, with comments on selected oxygen buffer reactions. Amer. Mineral. 75, 781-790.
33. Holleck G. L. (1970) Diffusion and solubility of hydrogen in palladium and palladium-silver alloys. J. Phys. Chem. 74, 503-511.
34. Holloway J. R. (1977) Fugacity and activity of molecular species in supercritical fluids. In Thermodynamics in Geology (ed. D. G. Fraser), pp. 161-181. Reidel.
35. 2O fluids for use in hydrothermal experimentation. I. Experimental method and equilibration calculations in the C-O-H-N system. Amer. Mineral. 59, 587-597.
36. Huebner J. S. (1971) Buffering techniques for hydrostatic systems at elevated pressures. In Research Techniques for High Pressure and High Temperature (éd. G. C. Ulmer), pp. 123-177. Springer-Verlag.
37. 2-NaCl fluids: an experimental and thermodynamic evaluation at elevated pressures and temperatures. Amer. Mineral. 66, 1135-1153.
38. Jacobsen R. T., Stewart R. B., and Jahangirl M. (1986)Thermodynamic properties of nitrogen from the freezing line to 2000 K at pressures to 1000 MPa. J. Phys. Chem. Réf. Data 15, 735-909.
39. Japas M. L. and Franck E. U. (1985) High pressure phase equilibria and PVT-data of the water-nitrogen system to 673 K and 250 MPa. Ber. Bunsenges. Phys. Chem. 89, 793-800.
40. Joyce D. B. (1990) Some experimental and theoretical investigations into the thermodynamic properties of fluids and melts. Ph.D. dissertation, Arizona State Univ.
41. 2) at temperatures from 673 K to 973 K at the pressure 50 MPa. J. Chem. Therm. 26, 765-777.
42. 2-NaCl fluids at high pressures and temperatures. Geochim. Cosmochim. Acta 57, 733-746.
43. 2-containing fluids in high-pressure experiments. European J. Mineral. 1, 135-137.
44. 2 mixtures at elevated pressures and temperatures. Amer. J. Sci. 281, 735-767.
45. 2. Geochemistry 3, 246-256.
46. Komarneni S., Freeborn P., and Smith C. A. (1979) Simple cold-weld sealing of noble-metal tubes. Amer. Mineral. 64, 650-651.
47. Lancaster N. M. and Wormald C. J. (1990) Excess molar enthalpies of nine binary steam mixtures: new and corrected values. J. Chem. Eng. Data 35, 11-16.
48. Liley P. E. (1956) Thermodynamic Properties of Steam, Carbon Dioxide, and Steam-Carbon Dioxide Mixtures. Report to the British Admiralty DEMR/EN/32/16/1/56.
49. 2 mixtures: a review of P-V-T-X data and an assessment from a phase-equilibrium point of view. Canadian Mineral. 29, 767-790.
50. Maya L. (1993) Deposition of crystalline binary nitride films of tin, copper and nickel by reactive sputtering. J. Vac. Sci. Technol. A11, 604-608.
51. Maya L., Paranthaman M., Thompson J. R., Thundat T., and Stevenson R. J. (1996) Ferromagnetic nanocomposite films of cobalt in a ceramic matrix by thermal decomposition of cobalt nitride, CoN, precursor. J. Appl. Phys. 79, 7905-7910.
52. Morgan G. B., VI, Chou I.-M., and Pasteris J. D. (1992) Speciation in experimental C-O-H fluids produced by the thermal decomposition of oxalic acid dihydrate. Geochim. Cosmochim. Acta 56, 281-294.
53. 2 buffer. Contrib. Mineral. Petrol. 114, 296-314.
54. Prokhorov V. M. and Tsiklis D. S. (1970) Gas-gas equilibrium in the nitrogen-water system. Russian J. Phys. Chem. 44, 1173-1174.
55. Rettich T. R., Battino R., and Wilhelm E. (1984) Solubility of gases in liquids. XVI. Henry's law coefficients for nitrogen in water at 5 to 50°C. J. Soin. Chem. 13, 335-348.
56. Richards P., Wormald C. J., and Yerlett T. K. (1981) The excess enthalpy of (water+nitrogen) vapour and (water+n-heptane) vapour. J. Chem. Therm. 13, 623-628.
57. 5 Pascals) Pressure and at Higher Temperatures. USGS Bull. 1452.
58. 5 Pascals) Pressure and at Higher Temperatures. USGS Bull. 2131.
59. Rubin L. R. (1966) Permeation of deuterium and hydrogen through palladium and 75 palladium-25 silver at elevated temperatures and pressures. Engelhard Industries Techn. Bull. 7, 55-62.
60. Shaw H. R. (1963) Hydrogen-water vapor mixtures: control of hydrothermal atmospheres by hydrogen osmosis. Science 139, 1220-1222.
61. Shaw H. R. (1967) Hydrogen osmosis in hydrothermal experiments. In Researches in Geochemistry (ed. P. H. Abelson), Vol. 2, pp. 521-541. Wiley.
62. 2O-nonpolar gas type. Geokhimiya 11, 1625-1638. (
63. Translated in Geochem. Intl. 17, 18-29.
64. 2 system (homogeneous solutions). Geochem. Intl. 17, 123-139.
65. Shmulovich K. I., Shmonov V. M., and Zharikov V. A. (1982) The thermodynamics of supercritical fluid systems. In Advances in Physical Geochemistry (ed. S. K. Saxena), Vol. 2, Chap. 5, pp. 173-190. Springer-Verlag.
66. 2O system to 6 kb and 700°C. Amer. J. Sci. 291, 1-54.
67. Tödheide K. and Franck E. U. (1963) Das Zweiphasengebiet und die kritische Kurve im system Kohlendioxyd-Wasser bis zu Drucken von 3500 bar. Z. Phys. Chem. 37, 387-401 (Neue Folge).
68. Tsiklis D. S. and Maslennikova V. Ya. (1965) Bounded mutual solubility of gases in the water-nitrogen system. Dokl. Akad. Nauk SSSR 161, 645-647.
69. 2. Fluid Phase Equil. 88, 115-121.
70. 8). Phys. Chem Minerals 15, 323-328.
71. Wormald C. J. and Colling C. N. (1983) Excess enthalpies for (water+nitrogen) (g) up to 698.2 K and 12.6 MPa. J. Chem. Therm. 15, 727-737.
72. 2 ) (g) at high temperatures and pressures. J. Chem. Therm. 18, 135-147.
73. 2 system at 300 and 400°C up to 1000 bar. Geochem. Intl. 21, 13-20.
74. 2O mixtures, derived from high-pressure mineral equilibrium data. In High-Pressure Researches in Geoscience (ed. W. Schreyer), pp. 493-500. E. Schweizertart'sche Verlagsbuchhandlung.