Influence of iron oxide inclusion shape on Co(II/III)EDTA reactive transport through spatially heterogeneous sediment

Water Resources Research

Volumn 34, Issue 10, 1998, Pages 2501-2514

  Szecsody, James E ^a   Chilakapati, Ashok ^a   Zachara, John M ^a   Garvin, Amanda L ^a  

^a PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HETEROGENEOUS MEDIUM; IRON OXIDE; MODELING; SOLUTE TRANSPORT;

IRON; REACTION KINETICS; SURFACE REACTIONS; UNCERTAINTY ANALYSIS;

AVERAGED MODELS; ENSEMBLE AVERAGES; EQUIVALENT MODEL; HETEROGENEOUS SEDIMENTS; HETEROGENEOUS SYSTEMS; OXIDE INCLUSION; REACTIVE TRANSPORT; VARIABLE LENGTH;

IRON OXIDES;

EID: 0031684899     PISSN: 00431397     EISSN: None     Source Type: Journal    
DOI: 10.1029/98WR02405     Document Type: Article

References (52)

1. Ainsworth, C., J. Pilon, P. Gassman, and W. van der Sluys, Cobalt, cadmium, and lead sorption to hydrous iron oxide: Residence time effect, J. Soil Sci. Soc. Am., 58, 1615-1623, 1994.
2. Baik, M., and K. Lee, Transport of radioactive solutes in the presence of chelating agents, Ann. Nucl. Energy, 21(2), 81-96, 1994.
3. Bellin, A., A. Rinaldo, W. Bosma, S. van der Zee, and Y. Rubin, Linear equilibrium adsorbing solute transport in physically and chemically heterogeneous porous formations, Water Resour. Res., 29(12), 4019-4030, 1993.
4. Berglund, S., and V. Cvetkovic, Contaminant displacement in aquifers: Coupled effects of flow heterogeneity and nonlinear sorption, Water Resour. Res., 32(1), 23-32, 1996.
5. Blatt, H., G. Middleton, and R. Murray, Origin of Sedimentary Rocks, Prentice-Hall, Englewood Cliffs, N. J., 1972.
6. Bosma, W., and S. E. A. T. M. van der Zee, Transport of reacting solute in a one-dimensional chemically heterogeneous porous medium, Water Resour. Res., 29(1), 117-131, 1993.
7. Bosma, W., S. Bellin, S. van der Zee, and A. Rinaldo, Linear equilibrium adsorbing solute transport in physically and chemically heterogeneous porous formations, Water Resour. Res., 29(12), 4031-4043, 1993.
8. Bosma, W. J. P., S. E. A. T. M. van der Zee, and C. J. van Duijn, Plume development of a nonlinearly adsorbing solute in heterogenous porous formations, Water Resour. Res., 32(6), 1569-1584, 1996.
9. Brooks, S., D. Taylor, and P. Jardine, Reactive transport of EDTA-complexed cobalt in the presence of ferrihydrite, Geochim. Cosmochim. Acta, 60, 1899-1908, 1996.
10. Bryce, A. L., W. A. Kornicker, and A. W. Elzerman, Nickel adsorption to hydrous ferric oxide in the presence of EDTA: Effects of component addition sequence, Environ. Sci. Technol., 28(13), 2353-2359, 1994.
11. Burr, D., E. Sudicky, and R. Naff, Nonreactive and reactive solute transport in three-dimensional heterogeneous porous media: Mean displacement, plume spreading, and uncertainty, Water Resour. Res., 30(3), 791-815, 1994.
12. Charbeneau, R. J., Multicomponent exchange and subsurface solute transport: Characteristics, coherence, and the Riemann problem, Water Resour. Res., 24(1), 57-64, 1988.
13. Chen, W., and R. Wagenet, Solute transport in porous media with sorption-site heterogeneity, Environ. Sci. Technol., 29(11), 2725-2734, 1995.
14. Chilakapati, A., RAFT: A simulator for reactive flow and transport of groundwater contaminants, PNL-10636/VC-602, Pac. Northwest Lab., Richland, Wash., 1995.
15. Chilakapati, A., T. Ginn, and J. Szecsody, An analysis of complex reaction networks in groundwater modeling, Water Resour. Res., 34(7), 1767-1780, 1998.
16. Cushman, J., B. Hu, and F. Deng, Nonlocal reactive transport with physical and chemical heterogeneity: Localization errors, Water Resour. Res., 31(9), 2219-2237, 1995.
17. Cvetkovic, D., and A. Shapiro, Mass arrival of sorptive solute in heterogeneous porous media, Water Resour. Res., 26(9), 2057-2067, 1990.
18. Friedly, J., and J. Rubin, Solute transport with multiple equilibrium-controlled or kinetically controlled chemical reactions, Water Resour. Res., 28(6), 1935-1953, 1992.
19. Gupta, A. D., L. W. Lake, G. A. Pope, K. Sephernoori, and M. J. King, High-resolution monotonic schemes for reservoir fluid flow simulation, In Situ, 15(3), 289-317, 1991.
20. Harten, A., High resolution schemes for hyperbolic conservation laws, J. Comput. Phys., 49, 357-393, 1983.
21. Hering, J., and F. Morel, Kinetics of trace metal complexation: Role of alkaline-Earth metals, Environ. Sci. Technol., 22, 1469-1478, 1988.
22. Hindmarsh, A. C., A systemized collection of ODE solvers, in Scientific Computing, edited by R. S. Stepleman, pp. 55-64, North-Holland, New York, 1983.
23. Hinz, C., L. Gaston, and H. Selium, Effect of sorption isotherm type on predictions of solute mobility in soil, Water Resour. Res., 30(11), 3013-3021, 1994.
24. Huang, K., N. Toride, and M. van Genuchten, Experimental investigation of solute transport in large, homogeneous and heterogeneous, saturated soil columns, Transp. Porous Media, 18, 283-302, 1995.
25. Jones, T. L., G. W. Gee, J. L. Swanson, and R. R. Kirkham, A laboratory and field evaluation of the mobility of cobalt-60/EDTA, in Proceedings of the Symposium on Waste Management, edited by R. G. Post, pp. 331-333, Univ. of Ariz. Press, Tuscon, 1983.
26. Kari, F., S. Hilger, and S. Cononica, Determination of reaction quantum yield for the photochemical degradation of Fe(III)-EDTA: Implications for the environmental fate of EDTA in surface waters, Environ. Sci. Technol., 29(4), 1008-1017, 1995.
27. Kent, D., J. Davis, C. Anderson, B. Rea, and T. Waite, Transport of chromium and selenium in the suboxic zone of a shallow aquifer: Influence of redox and adsorption reactions, Water Resour. Res., 30(6), 1099-1114, 1994.
28. Koltermann, C. E., and S. M. Gorelick, Heterogeneity in sedimentary deposits: A review of structure-imating, process-imating, and descriptive approaches, Water Resour. Res., 32(9), 2617-2658, 1996.
29. Leonard, B. P., Third-order upwinding as a rational basis for computational fluid dynamics, in Computational Techniques and Applications, pp. 106-122, North Holland, New York, 1984.
30. Lin, C., and M. Benjamin, Dissolution kinetics of minerals in the presence of sorbing and complexing ligands, Environ. Sci. Technol., 24, 126-134, 1990.
31. Ma, L., and H. Selim, Predicting the transport of atrazine in soils: Second-order and multireaction approaches, Water Resour. Res., 30(12), 3489-3498, 1994.
32. Means, J. L., and C. A. Alexander, Environmental biogeochemistry of chelating agents and recommendations for the disposal of chelated radioactive wastes, Nucl. Chem. Waste Manage., 2, 183-196, 1981.
33. Murphy, E. M., T. R. Ginn, A. Chilakapati, C. T. Resch, J. L. Phillips, T. W. Wietsma, and C. M. Spadoni, The influence of physical heterogeneity on microbial degradation and distribution in porous media, Water Resour. Res., 33(5), 1087-1103, 1997.
34. Nowack, B., J. Lutzenkirchen, P. Behra, and L. Sigg, Modeling the adsorption of metal-EDTA complexes onto oxides, Environ. Sci. Technol., 30, 2397-2405, 1996.
35. Pedit, J., and C. T. Miller, Heterogeneous sorption processes in sub-surface systems, 1, Model formulations and applications, Environ. Sci. Technol., 28(12), 2094-2104, 1994.
36. Reichle, R., W. Kinzelbach, and H. Kinzelbach, Effective parameters in heterogeneous and homogeneous transport models with kinetic sorption, Water Resour. Res., 34(4), 583-594, 1998.
37. Reidel, S. P., N. P. Campbell, K. R. Fecht, and K. A. Lindsey, Late Cenozoic structure and stratigraphy of south-central Washington, in Regional Geology of Washington State, pp. 159-180, Wash. Div. of Geol. and Earth Resour., Olympia, 1994.
38. Riley, R. G., and J. M. Zachara, Chemical contaminants on DOE lands and election of contaminant mixtures for subsurface science research, DOE/ER-0547T, Off. of Energy Res., U.S. Dep. of Energy, Washington, D. C., 1992.
39. Rubin, Y., Flow and transport bimodal heterogeneous formations, Water Resour. Res., 31(10), 2461-2468, 1995.
40. Schwertmann, U., and R. M. Cornell, Iron Oxides in the Laboratory: Preparation and Characterization, VCH, New York, 1991.
41. Simmons, C. S., T. R. Ginn, and B. D. Wood, Stochastic-convective transport with nonlinear reaction: Mathematical framework, Water Resour. Res., 31(11), 2675-2688, 1995.
42. Spurlock, G., K. Huang, and M. T. van Genuchten, Isotherm nonlinearity and nonequilibrium sorption effects on transport of Fenuron and Monuron in soil columns, Environ. Sci. Technol., 29, 1000-1007, 1995.
43. Szecsody, J. E., F. J. Brockman, G. P. Streile, and M. J. Truex, Transport and biodegradation of quinoline in horizontally stratified porous media, J. Contam. Hydrol., 15, 277-304, 1994a.
44. Szecsody, J. E., J. M. Zachara, and P. L. Bruckhart, Adsorption-dissolution reactions affecting the distribution and stability of Co(II)EDTA in iron oxide-coated sand, Environ. Sci. Technol., 28(9), 1706-1716, 1994b.
45. Szecsody, J. E., J. M. Zachara, A. Chilakapati, P. M. Jardine, and A. S. Ferrency, Importance of flow and particle-scale heterogeneity on Co(II/III)EDTA reactive transport, J. Hydrol., in press, 1998.
46. Tompson, A. F. B., Numerical simulation of chemical migration in physically and chemically heterogeneous porous media, Water Resour. Res., 29(11), 3709-3726, 1993.
47. Tompson, A. F. B., A. L. Schafer, and R. W. Smith, Impacts of physical and chemical heterogeneity on cocontaminant transport in a sandy porous medium, Water Resour. Res., 32(4), 801-818, 1996.
48. Westall, J., J. Jones, G. Turner, and J. Zachara, Models for association of metal ions with heterogeneous environmental sorbents, 1, Complexation of Co(II) by Leonardite humoc acid as a function of pH and NaClO4 concentration, Environ. Sci. Technol., 29(4), 951-959, 1995.
49. Wise, W. R., Effects of laboratory-scale variability upon batch and column determinations of nonlinearity sorptive behavior in porous media, Water Resour. Res., 29(9), 2983-2992, 1993.
50. Yeh, G. T., and V. S. Tripathi, A model for simulating transport of reactive multispecies components: Model development and demonstration, Water Resour. Res., 27(12), 3075-3094, 1991.
51. Zachara, J. M., P. L. Gassman, S. C. Smith, and D. Taylor, Oxidation and adsorption of Co(II)EDTA complexes in subsurface materials with Fe and Mn oxide grain coatings, Geochim. Cosmochim. Acta, 59, 4449-4463, 1995a.
52. Zachara, J. M., S. C. Smith, and L. S. Kuzel, Adsorption and dissociation of Co-EDTA complexes in Fe-oxide containing subsurface sands, Geochim. Cosmochim. Acta, 59, 4825-4844, 1995b.