Synthesis of enantioenriched methyl vic-dihydroxystearates

Synthesis

Volumn , Issue 9, 1998, Pages 1255-1258

  Plate, Mark ^a   Overs, Michael ^a   Schäfer, Hans J ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

Enantioselective dihydroxylation; Kolbe electrolysis; Methyl octadecenoates; Methyl vic dihydroxystearates; Separation of diastereoisomers

Indexed keywords

FATTY ACID DERIVATIVE; STEARIC ACID DERIVATIVE;

ARTICLE; DRUG STRUCTURE; DRUG SYNTHESIS; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; IN VITRO STUDY; INFRARED SPECTROPHOTOMETRY; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0031683890     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1998-6084     Document Type: Article

References (16)

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14. 4 and separated. In the higher melting diastereoisomer the 10- and 12-hydroxy groups are anti to each other. The trihydroxystearates were related to the optical pure methyl 9,10-dihydroxystearates after selective removal of the 12-hydroxy group.
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