Study on radical chemistry of monoperoxycarbonates by α-methylstyrene dimer trapping technique

Polymer Journal

Volumn 30, Issue 3, 1998, Pages 192-196

  Watanabe, Yasumasa ^a   Ishigaki, Hideyo ^a   Okada, Hiroshi ^a   Suyama, Shuji ^a  

^a NOF Corporation   (Japan)

Author keywords

Decarboxylalion; Hydrogen Abstraction; Initiation Mechanism; Initiator Efficiency; Monoperoxycarbonates; Radical Trapping

Indexed keywords

CARBONATES; CHEMICAL BONDS; HIGH TEMPERATURE EFFECTS; INITIATORS (CHEMICAL); POLYSTYRENES; REACTION KINETICS;

DECARBOXYLATION; HYDROGEN ABSTRACTION; METHYLSTYRENE DIMER TRAPPING; MONOPEROXYCARBONATES;

FREE RADICAL POLYMERIZATION;

EID: 0031681136     PISSN: 00323896     EISSN: None     Source Type: Journal    
DOI: 10.1295/polymj.30.192     Document Type: Article

References (19)

1. J. K. Kochi, in "Free Radicals," Vol. II, J. K. Kochi, Ed., John Wiley & Sons, New York, N.Y., 1973, pp 677-695.
2. J. A. Howard and J. C. Scaiano, in "Landolt-Börnstein, New Series. Radical Reaction Rates in Liquids," Vol. 13d, H. Fischer, Ed., Springer-Verlag, Berlin, 1984.
3. S. G. Cohen and D. B. Sparrow, J. Am. Chem. Soc., 72, 611 (1950).
4. D. E. Van Sickle, J. Org. Chem., 34, 3446 (1969).
5. J. Chateauneuf, J. Lusztyk, B. Maillard, and K. U. Ingold, J. Am. Chem. Soc., 110, 6727 (1988).
6. Y. Watanabe, H. Ishigaki, H. Okada, and S. Suyama, Polym. J., 29, 366 (1997).
7. Y. Watanabe, H. Ishigaki, H. Okada, and S. Suyama, Chem. Lett., 1089 (1993); S. Suyama, H. Ishigaki, Y. Watanabe, and T. Nakamura, Polym. J., 27, 371 (1995); S. Suyama, H. Ishigaki, Y. Watanabe, and T. Nakamura, Polym. J., 27, 503 (1995).
8. Y. Watanabe, H. Ishigaki, H. Okada, and S. Suyama, Chem. Lett., 1089 (1993); S. Suyama, H. Ishigaki, Y. Watanabe, and T. Nakamura, Polym. J., 27, 371 (1995); S. Suyama, H. Ishigaki, Y. Watanabe, and T. Nakamura, Polym. J., 27, 503 (1995).
9. Y. Watanabe, H. Ishigaki, H. Okada, and S. Suyama, Chem. Lett., 1089 (1993); S. Suyama, H. Ishigaki, Y. Watanabe, and T. Nakamura, Polym. J., 27, 371 (1995); S. Suyama, H. Ishigaki, Y. Watanabe, and T. Nakamura, Polym. J., 27, 503 (1995).
10. Y. Watanabe, H. Ishigaki, H. Okada, and S. Suyama, Polym. J., 29, 940 (1997).
11. K. U. Ingold, in "Free Radicals," Vol.I, J. K. Kochi, Ed., John Wiley & Sons, New York, N.Y., 1973, p 74.
12. R. D. Grant, E. Rizzardo, and D. H. Solomon, Makromol. Chem., 185, 1809 (1984).
13. Y. Watanabe, H. Ishigaki, H. Okada, and S. Suyama, Polym. J., 29, 603 (1997).
14. J. Chateauneuf, J. Lusztyk, and K. U. Ingold, J. Am, Chem. Soc., 110, 2886 (1988); K. Fujimori, in "Organic Peroxides," W. Ando, Ed., John Wiley & Sons, New York, N.Y., 1992, pp 361-367.
15. J. Chateauneuf, J. Lusztyk, and K. U. Ingold, J. Am, Chem. Soc., 110, 2886 (1988); K. Fujimori, in "Organic Peroxides," W. Ando, Ed., John Wiley & Sons, New York, N.Y., 1992, pp 361-367.
16. W. A. Cramer, J. Phys. Chem., 71, 1171 (1967); K. U. Ingold, in "Free Radicals," Vol. I, J. K. Kochi, Ed., John Wiley & Sons, New York, N.Y., 1973, p 51.
17. W. A. Cramer, J. Phys. Chem., 71, 1171 (1967); K. U. Ingold, in "Free Radicals," Vol. I, J. K. Kochi, Ed., John Wiley & Sons, New York, N.Y., 1973, p 51.
18. R. A. Sheldon and J. K. Kochi, J. Am. Chem. Soc., 92, 5175 (1970); T. Koenig, in "Free Radicals," Vol. I, J. K. Kochi, Ed., John Wiley & Sons, New York, N.Y., 1973, Chapter 3.
19. R. A. Sheldon and J. K. Kochi, J. Am. Chem. Soc., 92, 5175 (1970); T. Koenig, in "Free Radicals," Vol. I, J. K. Kochi, Ed., John Wiley & Sons, New York, N.Y., 1973, Chapter 3.