Mass transport in gas-diffusion electrodes: A diagnostic tool for fuel-cell cathodes

Journal of the Electrochemical Society

Volumn 145, Issue 1, 1998, Pages 5-15

  Perry, Mike L ^a,b   Newman, John ^a   Cairns, Elton J ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b DuPont   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATHODES; CURRENT DENSITY; DIFFUSION; ELECTROLYTES; FUEL CELLS; IONIC CONDUCTION; MASS TRANSFER; MATHEMATICAL MODELS; REACTION KINETICS;

FUEL CELL CATHODES; GAS DIFFUSION ELECTRODES; IONIC MASS TRANSPORT; TAFEL KINETICS;

ELECTROCHEMICAL ELECTRODES;

EID: 0031674885     PISSN: 00134651     EISSN: None     Source Type: Journal    
DOI: 10.1149/1.1838202     Document Type: Article

References (39)

1. R. A. Lemons, J. Power Sources, 29, 251 (1990).
2. A. J. Appleby, in Modern Aspects of Electrochemistry, Vol. 9, B. E. Conway and J. O'M. Bockris, Editors, p. 369, Plenum Press, New York (1974).
3. J. Newman and W. Tiedemann, AIChE J., 21, 25 (1975).
4. J. Giner and C. Hunter, This Journal, 116, 1124 (1969).
5. R. P. Iczkowski and M. B. Cutlip, ibid., 127, 1433 (1980).
6. K. A. Striebel, Ph.D. Thesis, University of California, Berkeley (1987); K. A. Striebel, F. R. McLarnon, and E. J. Cairns, Ind. Eng. Chem. Res., 34, 3632 (1995).
7. K. A. Striebel, Ph.D. Thesis, University of California, Berkeley (1987); K. A. Striebel, F. R. McLarnon, and E. J. Cairns, Ind. Eng. Chem. Res., 34, 3632 (1995).
8. P. N. Ross, Jr., Anomalous Current Ratios in Phosphoric Acid Fuel Cell Cathodes, Lawrence Berkeley Laboratory (LBL) Report 13955 (1986).
9. L. G. Austin, Trans. Faraday Soc., 60, 1319 (1964).
10. P. N. Ross, Jr., This Journal, 127, 2655 (1980).
11. R. B. Bird, W. E. Stewart, and E. N. Lightfoot, Transport Phenomena, p. 542, John Wiley & Sons, Inc., New York (1960).
12. E. W. Thiele, Ind. Eng. Chem., 31, 916 (1939).
13. J. S. Newman, Electrochemical Systems, 2nd ed., p. 249, Prentice-Hall, Inc., Englewood Cliffs, NJ (1991).
14. K. Kinoshita, Carbon: Electrochemical and Physiochemical Properties, pp. 262-267, John Wiley & Sons, Inc., New York (1988).
15. A. Pebler, This Journal, 133, 9 (1986).
16. A. J. Appelby, J. Power Sources, 49, 15 (1994).
17. L. S. Darken and H. F. Meier, J. Am. Chem. Soc., 64, 621 (1942).
18. N. F. Shevchenko, V. V. Aleksanddrov, N. I. Gancharova, and T. N. Seredenko, Sov. Electrochem., 15, 306 (1979).
19. B. R. Scharifker, P. Zelany, and J. O'M. Bockris, This Journal, 134, 2714 (1987).
20. R. E. Davis, G. L. Horvath, and C. W. Tobias, Electrochim. Acta, 12, 287 (1967).
21. D. B. Sepa, M. V. Vojnovic, and A. Damjanovic, ibid, 26, 781 (1981).
22. J. S. Newman, Electrochemical Systems, 2nd ed., pp. 539-555, Prentice-Hall, Inc., Englewood Cliffs, NJ (1991).
23. M. L. Perry, M.S. Thesis, University of California, Berkeley (1996).
24. M. S. Wilson and S. Gottesfeld, J. Appl. Electrochem., 22, 1 (1992).
25. R. S. Yeo, in Transport Processes in Electrochemical Systems, R. S. Yeo, T. Katan, and D. T. Chin, Editors, PV 82-10, p.178, The Electrochemical Society Proceedings Series, Pennington, NJ (1982).
26. T. E. Springer, T. A. Zawodzinski, and S. Gottesfeld, This Journal, 138, 2334 (1991).
27. T. F. Fuller and J. Newman, ibid., 140, 1218 (1993).
28. D. M. Bernardi and M. W. Verbrugge, ibid., 139, 2477 (1992).
29. Z. Ogumi, Z. Takehara, and S. Yoshizawa, ibid., 131, 769 (1984).
30. T. E. Springer, M. S. Wilson, and S. Gottesfeld, ibid., 140, 3513 (1993).
31. T. E. Springer, T. A. Zawodzinski, M. S. Wilson, and S. Gottesfeld, ibid., 143, 587 (1996).
32. T. A. Zawodzinski, C. Derouin, S. Radzinski, R. J. Sherman, V. T. Smith, T. E. Springer, and S. Gottesfeld, ibid., 140, 1041 (1993).
33. P. Schroeder, Z. Phys. Chem., 45, 75 (1903).
34. A. Parthasarathy, S. Srinivasan, A. J. Appelby, and C. R. Martin, This Journal, 139, 2530 (1992).
35. J. S. Newman and C. W. Tobias, ibid., 109, 1183 (1962).
36. A. Winsel, Z. Elektrochem., 66, 287 (1962).
37. H. R. Kunz and G. A. Gruver, This Journal, 122, 1279 (1975).
38. T. Maoka, Electrochim. Acta, 33, 371 (1988).
39. O. J. Murphy, G. D. Hitchens, and D. J. Manko, J. Power Sources, 47, 353 (1994).