Photodestruction spectroscopy of carbon disulfide cluster anions (CS2)-n n = 1-4: Evidence for the dimer core structure and competitive reactions of the dimer anion

Journal of Chemical Physics

Volumn 108, Issue 4, 1998, Pages 1368-1376

  Maeyama, Toshihiko ^a   Oikawa, Takanobu ^a   Tsumura, Tohru ^a   Mikami, Naohiko ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

BAND STRUCTURE; CALCULATIONS; CARBON INORGANIC COMPOUNDS; CHEMICAL BONDS; DISSOCIATION; ELECTRON ENERGY LEVELS; LIGHT ABSORPTION; MASS SPECTROMETRY; MOLECULAR VIBRATIONS; PHOTOCHEMICAL REACTIONS;

ABSORPTION BAND; ELECTRON DETACHMENT; HARTREE-FOCK CALCULATIONS; PHOTODESTRUCTION SPECTROSCOPY; PHOTON ENERGY DEPENDENCE;

ELECTRON SPECTROSCOPY;

EID: 0031648464     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.475510     Document Type: Article

References (29)

1. S. T. Arnold, J. G. Eaton, D. Patel-Misra, H. W. Sarkas, and K. H. Bowen, in Ion and Cluster Ion Spectroscopy and Structure, edited by J. P. Maier (Elsevier, Amsterdam, 1989), p. 417, and references therein.
2. Y. Hatano, in Dynamics of Excited Molecules, edited by K. Kuchitsu (Elsevier, Amsterdam, 1994), p. 151.
3. J. Tsukamoto and A. Takahashi, Jpn. J. Appl. Phys., Part 2 25, L338 (1989).
4. Y. Asano, Jpn. J. Appl. Phys., Part 1 22, 1618 (1983).
5. Y. Ono, S. H. Linn, H. F. Prest, M. E. Gress, and C. Y. Ng, J. Chem. Phys. 73, 2523 (1980).
6. Y. Ono, S. H. Linn, H. F. Prest, M. E. Gress, and C. Y. Ng, J. Chem. Phys. 74, 1125 (1981).
7. T. Kondow and K. Mitsuke, J. Chem. Phys. 83, 2612 (1985).
8. K. Hiraoka, S. Fujimaki, K. Aruga, and S. Yamabe, J. Phys. Chem. 98, 1801 (1994).
9. T. Tsukada, T. Hirose, and T. Nagata, Chem. Phys. Lett. (in press).
10. S. H. Fleischman and K. D. Jordan, J. Phys. Chem. 91, 1300 (1987).
11. M. J. DeLuca, B. Niu, and M. A. Johnson, J. Chem. Phys. 88, 5857 (1988).
12. M. L. Alexander, M. A. Johnson, N. E. Levinger, and W. C. Lineberger, Phys. Rev. Lett. 57, 976 (1986).
13. T. Maeyama, T. Tsumura, A. Fujii, and N. Mikami, Chem. Phys. Lett. 264, 292 (1997).
14. A. Nakajima, T. Taguwa, K. Hoshino, T. Sugioka, T. Naganuma, F. Ono, K. Watanabe, K. Nakao, Y. Konishi, R. Kishi, and K. Kaya Chem. Phys. Lett. 214, 22 (1993).
15. P. C. Cosby, R. A. Bennett, J. R. Peterson, and J. T. Moseley, J. Chem. Phys. 63, 1612 (1975).
16. J. M. Oakes and G. B. Ellison, Tetrahedron 42, 6263 (1986).
17. K. Ohashi and N. Nishi, J. Phys. Chem. 96, 2931 (1992).
18. K. Ohashi and N. Nishi, J. Chem. Phys. 98, 390 (1993).
19. R. V. Hodges and J. A. Vanderhoff, J. Chem. Phys. 72, 3517 (1980).
20. T. Dresch, H. Kramer, Y. Thurner, and R. Weber, Z. Phys. D 18, 391 (1991).
21. G. P. Smith and L. C. Lee, J. Chem. Phys. 69, 5393 (1978).
22. C. B. Freidhoff, Ph.D. thesis, 1987, Johns Hopkins University; private communication from Professor K. H. Bowen.
23. T. Dresch, H. Kramer, Y. Thurner, and R. Weber, Chem. Phys. Lett. 177, 383 (1991).
24. M. J. Frisch, G. W. Trucks, H. B. Schlegel, P. M. W. Gill, B. G. Johnson, M. W. Wong, J. B. Foresman, M. A. Robb, M. Head-Gordon, E. S. Replogle, R. Gomperts, J. L. Andres, K. Raghavachari, J. S. Blinkley, C. Gonzalez, R. L. Martin, D. J. Fox, D. J. Defrees, J. Baker, J. J. P. Stewart, and J. A. Pople, GAUSSIAN 92/DFT, Rev. G.2, Gaussian Inc., Pittsburgh, PA, 1993.
25. We also calculated at the BLYP level of theory, where the optimized geometries and energies are remarkably different from those obtained at the HF level. However, application of density functional methods for negative ions is not well established at present; see Ref. 26.
26. J. M. Galbraith and H. F. Schaefer III, J. Chem. Phys. 105, 862 (1996).
27. G. Herzberg, Molecular Spectra and Molecular Structure (Krieger, Malabar, 1989), Vol. 1, p. 566.
28. G. Herzberg, Molecular Spectra and Molecular Structure (Van Nostrand Reinhold, New York, 1966), Vol. 3, p. 600.
29. See, for example, Y. Ohshima and Y. Endo, J. Mol. Spectrosc. 153, 627 (1992).